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138 results about "Porous microstructure" patented technology

Gold-containing catalyst for preparing vinyl chloride by using acetylene method as well as preparation method and application of catalyst

The invention discloses a gold-containing catalyst for preparing vinyl chloride by using an acetylene method as well as a preparation method and application of the catalyst. The catalyst contains a gold element, a lanthanum element, a cobalt element, a co-catalytic metal element and a carrier with a porous micro-structure. The gold accounts for 0.3%-2% by mass of the catalyst; the gold element in the catalyst comes from gold chlorides or gold nitrates; the cobalt element comes from chlorides of the cobalt or cobalt nitrates; and the lanthanum element comes from lanthanum chlorides or lanthanum nitrates. The catalyst disclosed by the invention in use is free from inactivation phenomenon caused by sublimation of industrial catalyst mercury chloride, has no pollution to the environment, overcomes defects of high toxicity and high pollution of the conventional industrial catalyst mercury chloride, has the characteristics of simple preparation method, high conversion rate of the acetylene and selectivity of the vinyl chloride, long service life up to 1000 hours or more, high temperature resistance, and high intensity and is renewable, and the conversion rate of the acetylene and selectivity of the vinyl chloride approximate to or exceed the technical indexes of the mercury chloride catalyst.
Owner:TIANJIN UNIV +1

Electrospun polyvinyl alcohol-based tannic acid anti-oxidation nanofiber membrane

The invention relates to an electrospun polyvinyl alcohol-based tannic acid anti-oxidation nanofiber membrane. A prepration method includes the steps of tannic acid-metal ion self-assembly complex solution preparation, polyvinyl alcohol fiber-forming matrix preparation, polyvinyl alcohol-based tannic acid-metal ion complex electrospinning solution preparation and anti-oxidation nanofiber membrane preparation through electrospinning. By the utilization of the dual effects of polyphenol efficient anti-oxidation activity of tannic acid molecular structures and self-assembly chelation crosslinking between the tannic acid molecular structures and metal ions, with polyvinyl alcohol being a membrane-forming matrix, a chelated net structure of tannic acid and the metal ions is constructed by the utilization of the electrospinning technology to enhance fiber mechanical properties, a nanfiber porous microstructure is used for efficiently exerting anti-oxidation activity of tannic acid, a high mechanical property and anti-oxidation function integrated forming technology for preparing the nanofiber membrane in a one-step mode is created, and the polymer nanofiber membrane is endowed with the dual functional characteristics of anti-oxidation and mechanical property enhancement.
Owner:TIANJIN JIESHENG DONGHUI FRESH PRESERVATION TECH

Dimension-adjustable porous micro-structured surface antifouling material

The invention belongs to the technical field of marine life fouling prevention, and relates to a dimension-adjustable porous micro-structured surface antifouling material prepared from mixed materials of organosilicon acrylic acid copolymer resin, an amine nucleation promoter, and a curing agent according to a certain volume ratio. First, organosilicon acrylic acid copolymer resin, the amine nucleation promoter, and the curing agent are well mixed, and the mixture is used for coating, such that a dimension-adjustable porous micro-structured surface is formed under room temperature. The volumeof the amine nucleation promoter takes 0.5% to 2.0% of the volume of organosilicon acrylic acid copolymer resin, and the volume of the curing agent takes 1%-3% of the volume of organosilicon acrylic acid copolymer resin. A mass ratio of a prepolymer containing double-bond organosilicon to propylene monomers is 2:1-1:2. The content of acrylonitrile monomers takes 0-25% of a total mass of the propylene monomers. The adjusting method is advantaged in simple technology, reliable principle, convenient adjustment, and flexible operation. The material is advantaged in good antifouling effect, and issuitable to be used in equipment fouling preventing occasions in various marine environments.
Owner:725TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Inorganic-organic hybrid three-dimensional interpenetrating network hydrogel materials and preparation method and application thereof

The invention belongs to the field of the hydrogel material application and the technical field of novel medical materials and particularly relates to inorganic-organic hybrid three-dimensional interpenetrating network hydrogel materials and a preparation method and an application thereof. The inorganic-organic hybrid three-dimensional interpenetrating network hydrogel materials comprise inorganic material enhanced first supermolecular hydrogel and room temperature in-situ polymerized second polymer hydrogel. Polymer monomers form a second polymer hydrogel network in a first network formed by inorganic materials and dendritic polymers through in-situ polymerization to form the inorganic-organic hybrid three-dimensional interpenetrating network hydrogel and accordingly the mechanical performance of the inorganic-organic hybrid three-dimensional interpenetrating network hydrogel is high. The sol state is transformed into the gel state in the polymerization process due to the in-situ polymerization of the second polymer hydrogel network and accordingly the injection performance of the inorganic-organic hybrid three-dimensional interpenetrating network hydrogel is good. The inorganic-organic hybrid three-dimensional interpenetrating network hydrogel is of a porous microstructure and accordingly the adsorption capability or the load capacity of the inorganic-organic hybrid three-dimensional interpenetrating network hydrogel are high and X-ray developer or small molecule drugs can be loaded.
Owner:FUDAN UNIV +1

An air pressure control method and device used for photonic band gap optical fiber drawing

ActiveCN106495464AStable air pressureSolve the problem of independent and precise control of regional air pressureGlass making apparatusEngineeringIntermediate Fiber
The invention discloses an air pressure control method and device used for photonic band gap optical fiber drawing, and belongs to the technical field of optical fiber manufacturing. The method includes firstly inserting an intermediate into an intermediate fixing table, sealing the intermediate and the intermediate fixing table with sealing glue, connecting a single-cavity body and a double-cavity body in a threaded manner, with a fiber core duct being inserted into an intermediate fiber core during connection, and after assembling is finished, communicating a fiber-core-cavity gas pipe port, a cladding-cavity gas pipe port and an outer-cavity gas pipe port to a gas chamber of an air pressure control electric part through gas guiding pipes separately to achieve independent air pressure control of three regions which are a fiber core cavity, a cladding cavity and an outer cavity. The method and the device overcome a problem of independent precise air pressure control of the three regions during a photonic band gap optical fiber drawing process. The method and the device have universality and are suitable for porous micro-structured optical fiber drawing requiring independent air pressure control for separated regions. A pressure difference is adopted to determine on-off control time of an electromagnetic valve, thus controlling a gas flux through the pressure difference and increasing air pressure control precision.
Owner:BEIHANG UNIV

Preparation method of porous Al2O3 ceramic

The invention relates to a preparation method of porous Al2O3 ceramic. The preparation method comprises the steps: adopting sintered-plate shaped alundum powder as raw material, adopting water glass solution as a binding agent, mixing the sintered-plate shaped alundum powder and the water glass solution into suspending liquid, fully stirring, injecting the obtained suspending liquid into a mold, freezing the suspending liquid in a vacuum freeze dryer, carrying out continuous drying thoroughly under vacuum state on the frozen suspending liquid, then demolding the sample, placing the demolded sample into a high-temperature box-type electric furnace, rising the temperature to 1500-1600 DEG C, keeping the temperature for 2 hours, and cooling naturally along the furnace to obtain the porous Al2O3 ceramic. As a vacuum freeze drying technique is adopted, the invention does not add any organic or inorganic chemical harmful substances, does not need special templates, and adopts ice as a hole-making template; and after the ice crystal is sublimated and removed, the ceramic particles obtain a porous microstructure of negative duplicates for growth of the ice crystal. The preparation method better inherits the ice crystal appearance, also does not need the processes of removing the templates, such as calcining, chemical etching and the like, not only has simple technique, but also has unique hole structure, and is easy to obtain a special hole structure.
Owner:SHAANXI UNIV OF TECH
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