The application discloses
anthraquinone-based polysulfate and a preparation method and photocatalytic application thereof, and belongs to the field of
polymer material synthesis and photocatalytic technology. The polysulfate takes 2,6-
dihydroxyanthraquinone derivative as a core
monomer, is connected through a
sulfate bond to form a conjugated
polymer, and has excellent visible light
absorption capacity and
electron transport performance. The preparation method takes 2,6-
dihydroxyanthraquinone as a starting material, synthesizes a double
silyl ether protected
anthraquinone intermediate and a thiofluoride activated
anthraquinone intermediate respectively, and finally performs polycondensation on the two intermediates under a
potassium hydrogen fluoride /
crown ether catalytic
system. The material can catalyze
hydrogen peroxide to be generated from water and
oxygen under
visible light irradiation, and the yield reaches 2667 μmol·h ‑1 ·g ‑1 , is a new type of efficient photocatalytic material, and has wide application prospects in the fields of green synthesis and environmental
catalysis.