The application discloses a high-activity Pt / GaCe-Al2O3 catalyst and a preparation method and application thereof. Firstly, an Al2O3 carrier doped with Ga and Ce is synthesized through a
hydrothermal synthesis method; then,
metal Pt is loaded on the synthesized GaCe-Al2O3 carrier through an impregnation method, so as to obtain the Pt / GaCe-Al2O3 catalyst with high
dehydrogenation activity. The catalyst has a
nanosheet structure and has strong adsorption performance on
methylcyclohexane, and under the condition of 300 DEG C and normal pressure, the catalyst has excellent catalytic
dehydrogenation activity and stability in a
methylcyclohexane dehydrogenation reaction, and can realize an ultrahigh
hydrogen release rate.