66 results about "Complexometric titration" patented technology

The invention relates to a method for testing nickel and cobalt contents in a nickel compound by a titration, which comprises the following steps of: 1) dissolving the nickel compound to obtain nickel solution; 2) taking the partial nickel solution obtained in step 1), and carrying out complexometric titration on the nickel solution to test the nickel and cobalt metal total content; 3) taking the partial nickel solution obtained in step 1), adding ammonium persulfate, and testing the nickel metal content by using the complexometric titration again; and 4) subtracting the nickel metal content in step 3) from the nickel and cobalt metal total content tested in step 2), and obtaining the cobalt metal content. The nickel and cobalt contents in samples tested by the testing method have the advantages of small relative error and high accuracy. The testing method has the advantages of good repeatability and lower requirements of test conditions at the same time, and is suitable for work and production.

The invention relates to a method for joint measurement of calcium-barium content of a silicon-barium alloy by using compleximetry. The method is characterized by comprising the following steps: dissolving a sample by using nitric acid and hydrofluoric acid; adding perchloric acid until smoke is generated; steaming until the sample is dried; dissolving salts by using hydrochloric acid, fixing volume by using water, then taking two samples, and adding a masking agent into the two samples respectively to eliminate interference elements; then mixing calcein with an indicator; performing titration by using EDTA (ethylene diamine tetraacetic acid) as a standard solution to measure the calcium-barium content and the calcium content respectively; and performing subtractive calculation to obtain the barium content. The method has the following advantages: by virtue of joint measurement, simultaneous measurements by one time of sample dissolving are realized, and successive measurements by two times of sample dissolving are not needed, so that the operation time is greatly shortened, and the operation is quick and accurate; by one time of sample dissolving, the labor capacity of workers is reduced, the added types and added amount of chemicals are greatly reduced, the cost is saved, the use frequency of a electric hot plate is reduced, and the energy consumption is reduced.

The invention belongs to a measuring method of divalent cobalt content in lithium cobalt oxide in the metallic ion quantitative detection field; the measuring method is characterized in that: total cobalt content and trivalent cobalt ion content in the lithium cobalt oxide are respectively measured, and then the total cobalt content subtracts the trivalent cobalt ion content for obtaining the divalent cobalt content in lithium cobalt oxide; wherein, the measuring method of the total cobalt content in the lithium cobalt oxide adopts ethylenediamine tetraacetic acid (EDTA) chelatometrie volumetric method, an iodometry method or a potassium ferricyanide oxidimetry method, and the measuring method of the trivalent cobalt ion content in the lithium cobalt oxide adopts an ammonium ferrous sulfate oxidimetry method. The measuring method in the invention makes up the disadvantage that the prior art has no measuring method of divalent cobalt content in lithium cobalt oxide and provides a measuring method of divalent cobalt content in lithium cobalt oxide in the metallic, wherein the method has simple operation, easy judgment of a finishing point and accurate measuring result, thereby providing powerful reference for judging the purity of the lithium cobalt oxide products and ensuring the lithium cobalt oxide products to have good electro-chemical performance.

The invention discloses a complexometry joint measurement method for calcium, barium and magnesium contents in a silico-calcium barium magnesium alloy. The method comprises the steps of preparing a sample solution of the alloy and a blank solution as a contrast, preparing a titration solution and a blank titration solution respectively with the sample solution and the blank solution, titrating the titration solution and the blank titration solution respectively with an EDTA (Ethylene Diamine Tetraacetic Acid) standard solution, and calculating the calcium, barium and magnesium contents in the alloy respectively according to the consumption of the EDTA standard solution, wherein the titration solution comprises a calcium blank titration solution, a calcium and barium titration solution and a calcium and magnesium titration solution, and the blank titration solution comprises a calcium blank titration solution, a calcium and barium blank titration solution and a calcium and magnesium blank titration solution. With the adoption of the method, the calcium, barium and magnesium contents can be simultaneously measured in the same solution only by once sample dissolving, and the method is easy and simple to operate.

A composite desiliconization agent is added in sodium aluminosilicate solution with medium and high concentration for deep desiliconization, the invention relates to a chemical process method for carrying out the desiliconization of the sodium aluminosilicate solution with medium and high concentration by adopting the composite desiliconization agent under atmospheric pressure, the silicon content index of the solution after the desiliconization can be more than 7000, and the desiliconization method comprises the following steps: composition containing the sodium aluminosilicate solution is prepared, 80-90ml of the solution is taken and put in a reaction kettle, a calcium oxide and calcium sulfate composite desiliconization agent is added, the reaction kettle is put in a heat collection type constant temperature heating magnetic stirrer, supernatant liquor is taken after the solution is cooled, the concentration of Al2O3 is measured by using the complexometric titration, and the content of SiO2 is measured by using a spectrophotometer. The chemical process method is applicable to the secondary desiliconization of the sodium aluminosilicate solution with medium and high concentration. The economic benefits of using the sodium aluminosilicate solution with medium and high concentration are much higher than those of using the sodium aluminosilicate solution with low concentration under the situation of the same energy consumption, thereby being beneficial to reducing the energy consumption and promoting the sustainable development of the production of aluminum oxide.

The invention discloses a method for measuring the metallic magnesium content of a briquette nodulizing agent by using complexometry. The method comprises the steps of dissolving metallic magnesium in a test sample in dilute acetic acid, removing other Insoluble matters through filtering and washing, and fixing the volume of the filtrate in a volumetric flask; and weighing a certain volume of filtrate, regulating the pH value to 6-7 with ammonia water, separating interference elements with a copper reagent, complexing calcium with EGTA (ethylene glycol tetraacetic acid) when the pH is 10, and performing complexometry on magnesium by using EDTA (ethylene diamine tetraacetic acid), wherein eriochrome black T is an indicator. The method can detect that the metallic magnesium content in a briquette nodulizing agent sample is 5-15%, which nearly covers the metallic magnesium distribution gradients of all nodulizing agents in the production process, and can be applied to quantitative detection of the metallic magnesium in the laboratory briquette nodulizing agent for a long term. The method has the advantages of simplicity, fastness, high accuracy and precision and the like.

The determining process of lime content in long term lime stabilized soil includes the following steps: weighing lime soil sample, adding hydrochloric acid solution in the concentration of 50 vol% in 50 ml to dissolve the lime soil via stirring, transferring the supernatant into conical flask, complex titrating with standard 0.05 mol/L concentration EDTA solution and determining the volume of consumed standard 0.05 mol/L concentration EDTA solution Vlime soil; determining the Vpure soil and Vlime in similar process; and calculating the percentage content of lime in the lime soil based on corresponding formula. The method is simple, accurate and widely applicable.

The invention relates to a method for determining the content of nickel in a nickel-titanium shape memory alloy. The method comprises the following steps of: dissolving a sample with ammonium fluoride and nitric acid, and fluorating the sample; adding excessive EDTA (Ethylene Diamine Tetraacetic Acid) to make the EDTA completely complexed with nickel; regulating the acidity through an indicator; adding a buffer solution to control the acidity; titrating excessive EDTA by using a zinc scale; and determining the content of nickel by calculating. According to the method, the influence of titanium on the nickel during analysis is eliminated by masking the titanium, the end point mutation is obvious when the solution is titrated by regulating the acidity, and the more accurate content of nickel elements can be acquired by analyzing iron elements. The method for determining the content of the nickel in the nickel-titanium alloy has the advantages of simple process, obvious titration end point mutation, high recovery rate and high precision; the influence of Fe3<+> on the determination of the nickel can be eliminated; and the defects that methyl orange is used as an indicator to regulate the acidity, and xylenol orange is used as an indicator of complexometric titration end points in the conventional method to cause that the acidity control deviation is larger, and the titration end points are not obvious are overcome.

The invention provides a method for measuring magnesium content in a fluxing agent II. The method comprise the following steps of: putting a fluxing agent II sample to water, heating up and filtering the mixture to obtain filter residue; mixing and dissolving the filter residue with hydrochloric acid and nitric acid to obtain a solution; adjusting the pH value of the solution, adding a copper reagent to the solution, and filtering the solution to obtain filtrate; carrying out calcium-magnesium titration and calcium titration, and obtaining the content of the magnesium oxide through conversion of volume of a sodium ethylene diamine tetracetate standard titration solution which is consumed by the twice titration. Compared with an atomic absorption spectrometry or an ICP (Inductively Coupled Plasma) spectrometry in the prior art, soluble impurities such as un-reacted magnesium chloride, un-reacted potassium chloride and the like are firstly dissolved and removed by water; the magnesium oxide is dissolved by the mixture of hydrochloric acid and nitric acid; the interfering ions such as iron, manganese, aluminum, nickel, copper and the like in the solution are precipitated and separated by the copper reagent; and the content of the magnesium oxide is obtained through the conversion utilizing EDTA (Ethylene Diamine Tetraacetic Acid) complexometric titration. Therefore, the content of the magnesium oxide can be measured by only using simple glass wares and conventional chemical reagents without much investment, and the cost is low.

The invention provides a method for testing constant cadmium and zinc in cadmium zinc telluride crystal. The method provided by the invention comprises the following steps: taking a solution obtained by dissolving a proper amount of a sample solution of the cadmium zinc telluride crystal to be tested or a proper amount of a solid sample of the cadmium zinc telluride crystal to be tested, adjusting pH value of the solution to neutral by adding ammoniacal liquor (1+1) to and adjusting pH value of the solution to 10 by adding a proper amount of an ammonia-ammonium chloride buffer solution and remaining stable; adding a proper amount of a surfactant into the solution, adding a proper amount of an eriochrome black T indicator, and carrying out complexometric titration by the use of a complexing agent EDTA to turn the solution from purple to pure blue so as to obtain total amount nCd+Zn of cadmium and zinc, wherein molar concentration of the complexing agent EDTA is C1 and the use amount is V1; adding a proper amount of DDTC sodium salt to fully dissolve, selectively precipitate cadmium by DDTC sodium salt and releasing the same amount of EDTA, carrying out titration on EDTA by the use of a magnesium nitrate solution until the solution turns light red so as to obtain cadmium with the amount of nCd and mass of mCd, wherein molar concentration of the magnesium nitrate solution is C2 and use amount is V2; and obtaining zinc with amount of nZn and mass of mZn according to a difference method.

The invention discloses a calcium content determination method for low-calcium aluminum ferromanganese. The calcium content determination method comprises the following steps: utilizing hydrochloric acid-hydrogen peroxide to dissolve a sample; utilizing ammonia water to separate out aluminum, iron and other elements; using ammonium persulfate to oxidize and remove manganese to form colloidal precipitate; after filtering and separating out the precipitate, repeating the manganese removing process; adding hydrochloric acid to a manganese-removing solution; boiling the solution to remove superfluous ammonium persulfate; using ammonia water to regulate the pH value to be 7; splitting a part of solution; adding a masking agent to eliminate other ion interference; carrying out complexometric titration to determine the calcium element content. With application of the determination method disclosed by the invention, the calcium content in low-calcium aluminum ferromanganese can be accurately, stably, simply and efficiently determined, and the determination for the calcium content in the low-calcium aluminum ferromanganese can be faster and more convenient, so that the determination cost can be reduced.

The invention provides a method for testing content of titanium dioxide by a complexometric titration-back titration method. The method comprises the following steps of: (1) treating a sample; (2) optimizing an operation process, and reasonably adjusting the concentration of solution pH alkali; and (3) adding a buffer solution; and then calculating out the content of the titanium dioxide in the sample. By adopting the method provided by the invention, the acidity of the solution at the end point of titration can be controlled well, an indicator is ensured to change the color obviously, the precision of sample test is improved, and the relative deviation of the sample test result is less than 0.3%.

This invention discloses a handheld minim titrator including a sample pin protection jacket, a titrator wrap, a core locking plug of the titrator, a sample cavity of the sample pin and the titrator, a titrator pull rod and a core characterizing that said titrator pull rod is set in the sample cavity of the sample pin and the sample titrator to make up of a core, which is set in the wrap to be locked by the plug of the core and the protection jacket of the sample pin coveres one end of the pin to form a handheld minim titrator, which can replace acid-alkali buret in the lab and is suitable for oxidation-reduction titration method.

The invention discloses a method for quick quantitative analysis of metal cations in oil field water. By complexometric titration, synchronous titration of calcium, magnesium, strontium, barium and iron in an oil field water sample is realized through solution acidity control and precipitation masking without special pretreatment. Due to reduction of steps of iron removal, heating, aging, filtering and diluting, operation steps are greatly reduced, operation time is greatly shortened, measurement result accuracy is improved, and operation efficiency is improved as well. The method is hopefully popularized and applied in oil field water quality analysis.

The invention provides a chemical analysis determination method of zinc content of molecular sieve. The chemical analysis determination method comprises following steps: titer T of EDTA standard solution on zinc is obtained via calibration; a sample is dissolved in a strong base, and the pH value of an obtained mixture is adjusted to be lower than 7; a masking agent is added; and EDTA complexometric titration is adopted to determining the content of zinc in molecular sieve. In the chemical analysis determination method, the strong base is adopted to dissolve the sample; and ammonium fluoride and tartaric acid are taken as the masking agent; so that influences of interfering ions on determination results are avoided; the operation steps of the chemical analysis determination method are simple; and accuracy is high.

The invention discloses a method for detecting metal ion contents in zinc stearate and calcium stearate composite salt. The method comprises the following steps: accurately weighing composite stearate, adopting a complexometric titration method, utilizing the different capacities of complexing metal ions of an EDTA sodium solution under different acid and alkaline conditions, recording the volume of the consumed EDTA sodium solution, and calculating the content of each metal ion. The method provided by the invention is simple and easy to operate, and the detected stearate metal contents are accurate and reliable.

The invention provides a method for measuring the content of free boron oxide in boron nitride. The method specifically comprises the following steps: boron nitride is subjected to acid pickling in an acid solution, filtering and acid-base neutralization titration, a neutral mixed solution is prepared and subjected to complexometric titration and acid-base neutralization titration by adopting an alcohol complexing agent and a strong base standard solution respectively, the volume difference of the consumed strong base standard solution is obtained through a blank test, and an established unary linear quantitative detection model for free boron oxide in boron nitride is used for calculation, so that the content of free boron oxide in boron nitride is obtained. The method has simple steps and high detection result accuracy.

The invention relates to a method for analyzing and measuring hexafluorophosphoric acid ions, in particular to a method for measuring hexafluorophosphoric acid ions through the amperometric titration. The method comprises the following steps: (1), preparing a standard tetraphenylarsonium chloride solution, and calibrating the concentration of the tetraphenylarsonium chloride solution; (2), preparing a hexafluorophosphoric acid ion solution to be tested; (3), setting conditions for polarographic analysis: the initial potential ranges from minus 1.25 to minus 1.78; the sensitivity I is 8; the differentiation is 2.0; the scanning is carried out once; the step length is 5; the hexafluorophosphoric acid ions are subjected to the amperometric titration, with tetraphenylarsinium chloride taken as a titrant; and (4), reducing excess tetraphenylarsonium ions on mercury drops after (C6H5)4AsPF6 is produced, and calculating the concentration of a lithium-ion battery electrolyte sample to be tested on the basis of the concentration of lithium salt in a diluted sample and the dilution multiple. The invention provides the quick, accurate and economical method for measuring the hexafluorophosphoric acid ions. Tetraphenylarsonium chloride can remain in a stable state in a solution, tetraphenylarsonium chloride and hexafluorophosphoric acid salt form complex compound sediment, and the hexafluorophosphoric acid ions are unlikely to be oxidized or reduced by the mercury drops, so that the reducibility of the tetraphenylarsonium ions facilitates the analysis of the hexafluorophosphoric acid ions.

The invention discloses a method of detecting periclase content in cement clinker and belongs to the technical field of detection of building materials. The method comprises the steps of S01, crushingcement clinker, crushing, and screening to obtain a clinker sample; S02, mixing castor oil and anhydrous ethyl alcohol in a mass ratio of (10-15):1 to obtain a shielding agent; S03, adding 1 part bymass of the clinker sample into 40-80 parts by mass of the shielding agent, and holding the temperature of 50-70 DEG C for 10-20 min; S04, adding 40-60 parts by mass of ammonium nitrate and 150-200 parts by mass of anhydrous ethyl alcohol to the obtained material of step S03, heating at 85-95% to allow refluxing for 1-4 h, performing suction filtering while the temperature is high, washing the precipitate with hot anhydrous ethyl alcohol, and combining the washed precipitate with the filtrate; S05, cooling the filtrate of the step S04 to room temperature, and detecting periclase content by means of complexometric titration difference process. The method herein is suitable for more efficiently separating solid-solution magnesia and periclase, detection results for periclase are more real and accurate, and stability of the cement clinker can be correctly estimated.

The invention discloses a method for testing the content of alkyl chloride aluminum for ethylene-propylene polymerization. The method comprises the following steps: performing dehydration treatment onalkyl chloride aluminum in a vessel, performing titration to test the content of aluminum by using a complexing titration method, and further performing titration to test the content of chloride by using a Volhard method. By adopting the method, a conventional alkyl chloride aluminum content testing method is changed, the method does not need to be carried out in a nitrogen tank, and only reactions and hydration treatment are carried out in a ventilation cabinet. The method is simple, convenient and feasible. The hydration treatment steps are carried out in relatively special vessels, an alkyl chloride aluminum sample is added in a completely sealed environment in the testing process, the sample and a hydrogen chloride gas generated from reactions are not lost, and precise testing resultscan be achieved.

The invention provides a measurement method for zirconium oxide in drainage sand. The measurement method is characterized by comprising the following steps of preparing a reagent, preparing a test sample in a molten state, performing titration, and calculating zirconium oxide content. The measurement method for the zirconium oxide in the drainage sand has the beneficial effects that flux by whichthe zirconium oxide sample can be completely dissolved is used, accuracy detection data of the measurement method shows that the experiment recycling rate is 99-102%, and precision detection data shows that the RSD of the method is 0.68% and is remarkably higher than that of normal standard of which the RSD is 3%. By the method, the problem that the sample is difficult to dissolve during the measurement process of the zirconium oxide in the drainage sand is solved, so that the accuracy and the precision of a zirconium oxide element in the drainage sand measured by an EDTA complexometric titration method are remarkably improved, and the measurement method can be applicable to production and verification.

The invention provides a method for detecting free bismuth in colloidal bismuth pectin or a preparation containing colloidal bismuth pectin. The method includes the following steps of: placing colloidal bismuth pectin or the preparation containing colloidal bismuth pectin in a plastic centrifuge tube, adding water to shake for no more than 1min, obtaining a colloidal solution with uniform dissolution, centrifuging the colloidal solution immediately, separating the supernatant, measuring the content of bismuth in the supernatant by complexometric titration or ultraviolet spectrophotometry, andcalculating the content of free bismuth in colloidal bismuth pectin or the preparation containing colloidal bismuth pectin. The method for detecting free bismuth in colloidal bismuth pectin or the preparation containing colloidal bismuth pectin, established by the invention, has the advantages of strong specificity, high accuracy, good repeatability, good linear relationship and high sensitivity,and can be used as a mass control method for free bismuth in colloidal bismuth pectin or the preparation containing colloidal bismuth pectin to effectively control the quality of products of colloidalbismuth pectin or the preparation thereof.