The invention relates to the technical field of catalytic
material synthesis, and discloses a preparation method of a modified
tin-
titanium-
silicon molecular sieve catalyst, which comprises the following steps: S1, mixing a
silicon source, a
titanium source, a
tin source, an alkali source, a template agent, a surfactant and water to obtain a first mixture; s2, performing
hydrothermal reaction on the first mixture in the step S1, and washing,
drying and
roasting an obtained second mixture to obtain
tin-
titanium-
silicon molecular sieve powder; and S3, mixing and contacting the tin-titanium-silicon
molecular sieve powder obtained in the step S2 with an organic solution of organosiloxane, and then
drying to obtain the modified tin-titanium-silicon molecular
sieve catalyst. According to the modified tin-titanium-silicon molecular
sieve catalyst provided by the invention, a catalytic activity center is mainly positioned in a molecular
sieve pore channel, and when the catalyst is used for catalyzing a reaction for preparing
cresol through
toluene hydroxylation, effective shape-selective
catalysis can be realized, so that the selectivity of o-
cresol and p-
cresol can be improved, and particularly the selectivity of the o-cresol can be improved.