71 results about "M-Cresol" patented technology

The invention discloses a crude phenol continuous refining device and method, the device comprises a crude phenol storage tank, a dehydrating tower, a primary tower, a phenol fraction tower, an o-cresol fraction tower, a m-cresol and p-cresol tower, an extractive distillation tower and a p-cresol fraction tower which are connected in sequence, and the top of each tower is independently connected with a cooler; the method specifically comprises the following steps: (1) discharging phenol water; (2) discharging a heavy fraction; (3) discharging phenol; (4) discharging o-cresol; (5) discharging residual oil at the bottom of the tower; (6) carrying out extractive distillation, and discharging m-cresol; and (7) discharging p-cresol, and recycling the extraction agent. Compared with a traditional continuous rectification process, the method has the advantages that all components are separated by adopting vacuum rectification, the separation degree of the obtained product is higher, the number of theoretical plates and energy consumption are lower, high-purity phenol products are produced with low energy consumption, low cost and high efficiency, and economic benefits and environmental benefits are greatly improved.

The invention provides a refining method of medicinal chlorocresol, and relates to the field of pharmacy. The method comprises the following steps: mixing an industrial-grade chlorocresol crude product with a mixed solvent, heating, adding a decolorizing agent, stirring and refining to obtain a crude product refined solution; the mixed solvent comprises an alcohol organic solvent and an alkane organic solvent; and carrying out sterilization and first solid-liquid separation on the crude product refined liquid, continuously cooling to a first temperature and a second temperature in a stirring state, crystallizing, carrying out second solid-liquid separation, and drying to obtain the medicinal chlorocresol. According to the refining method of the medicinal chlorocresol, provided by the invention, specific impurities such as phenol and m-cresol in the crude chlorocresol product are refined, so that the crude chlorocresol product is almost free of residues after being refined, the purity of the product is effectively improved, the medicinal requirement is met, and the problem that commercially available industrial chlorocresol related substances such as m-cresol and the like do not meet the medicinal requirement is solved.

The invention relates to the technical field of chemical product separation equipment, and particularly discloses a reaction crystallizer for separating and refining m-cresol and p-cresol and a crystallization method. A sealing box; a filter screen; a tapered tube; and a discharge pipe. The mother liquor drives p-cresol crystals to be sprayed out from the spraying pipe, the sprayed p-cresol crystals impact the filter screen, so that the p-cresol crystals are scattered and broken, an m-cresol solution wrapped in the crystals is splashed out at the moment to be separated from the crystals, and the splashed m-cresol solution is discharged through the filter screen. Therefore, the m-cresol solution can be effectively prevented from being wrapped in the p-cresol crystal, so that the purity of the m-cresol and the p-cresol after separation is effectively prevented from being reduced.

The invention discloses a preparation method of 6-nitro-m-cresol, and belongs to the technical field of organic synthesis.The method comprises the steps that raw materials are subjected to esterification, water washing, sulfonation, nitration, desulfonation and refining in sequence, and the 6-nitro-m-cresol is obtained. According to the method, it can be guaranteed that the intermediate product is the 6-nitro derivative, generation of isomer impurities such as 2-site and 4-site is greatly reduced from the source, the reaction path is clear, and atom economy is good. The method does not need to depend on complicated means such as time-consuming column chromatography or precise fractionation, the requirement for high purity can be met only through conventional extraction and crystallization operation, the technological process is simple, the method is very suitable for large-scale production, and the product purity (measured through HPLC (High Performance Liquid Chromatography)) can stably reach 98% or above.

The invention discloses application of m-cresol to prevention and treatment of pepper southern blight, and belongs to the field of plant disease prevention and treatment. According to the invention, it is found for the first time that m-cresol has an inhibition effect on sclerotium rolfsii, wherein EC50 of m-cresol is 0.1560 [mu] L / mL; the m-cresol with the concentration of 2 * EC50 can completely inhibit sclerotium germination, sclerotium generation and hypha growth of the sclerotium rolfsii. Furthermore, m-cresol can be used for preventing and treating pepper southern blight caused by sclerotium rolfsii, the morbidity and disease index of pepper southern blight can be effectively reduced by using a m-cresol solution with the concentration of 0.125% to perform root irrigation treatment on pepper planted in pathogenic bacteria soil, the relative prevention and treatment effect reaches 100%, and adverse reaction of pepper plants cannot be caused. The invention provides a new method for controlling the pepper southern blight by using a medicament, and the method has the advantages of high efficiency, low cost, low environmental harm and the like.

The present invention relates to a molding composition comprising by weight: a) from 50 to 99% of a semi-crystalline aliphatic polyamide having an inherent viscosity of less than or equal to 1.10, in particular less than or equal to 1.00, in particular less than or equal to 0.95, in particular less than or equal to 0.9, as determined according to ISO 307:2007 but using m-cresol instead of sulfuric acid, a temperature of 20°C and a concentration of 0.5% by mass, b) from 1 to 50% of recycled carbon fibers having an average length of less than or equal to 6 mm before compounding, said recycled carbon fibers being surface-coated (sized) with a polyamide, in particular an aliphatic polyamide, c) from 0 to 5% of at least one additive, the sum of components a), b) and c) being equal to 100%.

The present invention discloses a continuous refining device and method for crude phenol, the device comprises a crude phenol storage tank, a dehydration tower, a primary distillation tower, a phenol fraction tower, an o-cresol fraction tower, a m-cresol tower, an extractive distillation tower and a p-cresol fraction tower connected in sequence, and the top of each tower is individually connected to a cooler; the method specifically comprises the following steps: (1) discharging phenol water; (2) discharging heavy fractions; (3) discharging phenol; (4) discharging o-cresol; (5) discharging residual oil at the bottom of the tower; (6) extractive distillation, discharging m-cresol; (7) discharging p-cresol, and recycling the extractant. Compared with the traditional continuous distillation process, the present invention uses vacuum distillation to separate the components, and the obtained product separation degree is higher, and the theoretical plate number and energy consumption are less, so that high-purity phenol products can be produced with low energy consumption, low cost and high efficiency, which greatly improves the economic and environmental benefits.

The invention discloses a production process method of an antioxidant BHT (butylated hydroxytoluene). The core of the method is to treat the recrystallization mother liquor: after the mother liquor is rectified to remove the solvent alcohol, the traditional high-temperature rectification is not adopted, and primary cooling crystallization, alkylation reaction and secondary cooling crystallization are sequentially carried out. Finally, the secondary mother liquor is produced as a liquid antioxidant LK51, and comprises 7-9% of 2-tert-butyl-p-cresol, about 35% of 4 (6)-tert-butyl-m-cresol, about 35% of 2, 6-di-tert-butyl-p-cresol, 4, 6-di-tert-butyl-m-cresol and other alkylphenols, and the total content of the alkylphenols is greater than 98%. The component is a mixture of various alkylphenols, has excellent oxidation resistance in lubricating oil, gasoline and other oil products, and can replace an antioxidant T501 and the like. According to the method disclosed by the invention, through process innovation and replacement of two-fraction alkylation of original rectification 2 by direct alkylation of the primary crystallization mother liquor, the yield of a BHT main product is increased, meanwhile, the high-added-value liquid antioxidant is co-produced, low-value heavy alkylphenol waste is eliminated, and dual improvement of energy conservation, consumption reduction and economic benefits is realized.

The invention discloses a positive photoresist composition suitable for an electroplating process as well as a preparation method and application of the positive photoresist composition, and belongs to the technical field of photoresist. The positive photoresist composition suitable for the electroplating process comprises the following components in parts by mass: 20-25 parts of high-molecular-weight high-sensitivity phenolic resin; 2 to 7 parts of plasticizing resin; 4-6 parts of a photosensitizer; 0.5-1 part of an additive; 61 to 73.5 parts of a solvent; wherein the molecular weight of the high-molecular-weight and high-sensitivity phenolic resin is 10000-20000, and the high-molecular-weight and high-sensitivity phenolic resin is low-ortho-position and high-branched phenolic resin in which the ratio of m-cresol to p-cresol is 8 / 2; the plasticizing resin is poly (p-hydroxystyrene) resin. The positive photoresist composition is suitable for an electroplating process, is used for solving the problem that a common photoresist is easy to break down in the electroplating process, and keeps good sensitivity characteristics at the same time.

The invention discloses a method for separating m-cresol and p-cresol, which is characterized in that a bis (dipropoxy) pillar [5] arene crystal material and / or an adsorption material loaded with bis (dipropoxy) pillar [5] arene are / is used as an adsorbent to selectively adsorb m-cresol in a mixture of the m-cresol and the p-cresol so as to realize the separation of the m-cresol and the p-cresol; the chemical structural formula of the bis (dipropoxy) pillar [5] arene is as follows: # imgabs0 #. The separation process of the invention is simple to operate and low in equipment requirement; rectification operation is not needed in the separation process, energy consumption is low, energy is saved, and the production cost is reduced; the used crystal material is high in stability and can be recycled, and the separation effect cannot be reduced; a lot of organic solvents, strong acids and strong alkalis are not used, and the green chemistry concept is met.

The invention discloses a method for preparing m-cresol, p-cresol and m-cresol phenolic resin by using crude phenol refining residues. According to the method, an acidic silicon-aluminum oxide solid catalyst and a zirconium phosphate system are adopted, long alkyl groups such as ethyl groups on aromatic rings in a 3, 4-methyl ethyl phenol mixture are removed, methyl groups are reserved, phenol containing the long alkyl groups is converted into simple cresol, phenol and the like, and then vacuum distillation treatment is performed to obtain phenol, m-p-cresol and 2, 3, 5-tricresol; further reacting the mixed phenol obtained by rectification with aldehydes to obtain modified m-cresol-formaldehyde resin products such as p-cresol, 2, 3, 5-tricresol and the like; complex raw materials are converted into simple products with clear targets through the cracking reaction, sulfur and nitrogen impurities in most of the raw materials are removed by utilizing an acid environment in the cracking process, an additional refining step is omitted, and the grades of all subsequent products are improved. According to the method, the limitation of traditional rectification is broken through, the difficulty of physical separation is simplified through a chemical means, the phenol and the phenolic resin are co-produced, and the added value of the product is improved.

The invention relates to the field of copper clad laminates and specifically discloses a low-dielectric epoxy resin for copper clad laminates and a processing technology thereof. The low-dielectric epoxy resin for copper clad laminates comprises a component A and a component B. Component A comprises the following raw materials, calculated in parts by mass: 100-150 parts of acetone, 250-300 parts of bisphenol A epoxy resin, and 50-100 parts of low-dielectric fillers; component B comprises the following raw materials, calculated in parts by mass: 150-250 parts of a low-dielectric curing agent, 20-30 parts of a curing agent, and 10-20 parts of a curing accelerator. The preparation of the low-dielectric curing agent comprises the following steps: taking a diamine modifier, 4,4'-diaminodiphenyl ether, 4,4'-oxydiphthalic anhydride, and meta-cresol, stirring under nitrogen protection, adding isoquinoline, stirring, cooling, adding meta-cresol, discharging the material while hot into ethanol, washing, filtering, extracting to remove the meta-cresol, and vacuum drying to obtain the low-dielectric curing agent.

The invention discloses a method for separating a cresol mixture and synthesizing 2, 3, 6-tricresol by adopting an alkylation method, and relates to the technical field of separation of cresol mixtures. The technical problems that in the prior art, during alkylation separation of 2, 4, 2, 5-xylenol, the obtained 2, 5-xylenol is narrow in application and small in dosage, and the synthesis cost of 2, 3, 6-tricresol is relatively high are solved. According to the method, the isobutene reacts with the mixture of the 2, 4-xylenol and the 2, 5-xylenol to generate the 6-tert-butyl-2, 4-xylenol and the 4-tert-butyl-2, 5-xylenol, so that the partial separation of the 2, 4-xylenol and the 2, 5-xylenol is realized; and carrying out methylation reaction on the separated intermediate and methanol to generate 2, 3, 6-trimethylphenol. According to the method disclosed by the invention, the application range of the 2, 5-xylenol is remarkably widened, the use amount of the mixture of the 2, 4-xylenol and the 2, 5-xylenol is increased, and the dependency degree on m-cresol in the synthesis of the vitamin E is reduced.

The invention relates to the field of copper-clad plates, and particularly discloses low-dielectric epoxy resin for a copper-clad plate and a processing technology of the low-dielectric epoxy resin. The low-dielectric epoxy resin for the copper-clad plate comprises a component A and a component B, the component A is prepared from the following raw materials in parts by mass: 100 to 150 parts of acetone, 250 to 300 parts of bisphenol A epoxy resin and 50 to 100 parts of low dielectric filler; the component B comprises the following raw materials in parts by mass: 150-250 parts of a low dielectric curing agent, 20-30 parts of a curing agent and 10-20 parts of a curing accelerator; the preparation method of the low-dielectric curing agent comprises the following steps: stirring a diamine modifier, 4, 4 '-diaminodiphenyl ether, 4, 4'-oxybisphphthalic anhydride and m-cresol under the protection of nitrogen, adding isoquinoline, stirring, cooling, adding m-cresol, discharging in ethanol while hot, washing, filtering, extracting to remove m-cresol, and drying in vacuum to obtain the low-dielectric curing agent.

The invention relates to the technical field of wastewater treatment, in particular to a salt-containing wastewater treatment device in m-cresol production, which comprises an evaporation hopper, a magnet frame is welded on the inner wall of the top of the evaporation hopper, a first bearing plate is slidably inserted in the evaporation hopper, a first sliding rod is welded on the outer wall of the first bearing plate, and a second sliding rod is welded on the outer wall of the first sliding rod. The first sliding rod is inserted into the outer wall of the magnet frame in a sliding mode. Through arrangement of a first bearing plate and stirring blades, when waste water enters an evaporation hopper, the elastic force of a first spring is overcome through the weight of the waste water, the first bearing plate moves downwards, the first bearing plate drives a discharging plate and the stirring blades to move downwards, and along with the fact that the stirring blades slide out of a containing groove, a first rope is gradually tensioned; and after the stirring blades slide out of the storage groove, the rope starts to pull the winch to rotate, and the winch drives the stirring blades to rotate and compresses the rotating coil spring, so that the stirring effect is realized by taking the gravity of the wastewater as driving force, and the device is more energy-saving and environment-friendly.

The invention belongs to the technical field of organic synthesis, and particularly discloses a thymol preparation method which comprises the following steps: filling a reaction tube of a fixed bed reactor with a catalyst, and heating m-cresol and isopropanol as raw materials in a fixed bed for gas-solid heterogeneous reaction to obtain thymol, the catalyst is an H-M1-ZSM-5 molecular sieve catalyst, the metal M1 is selected from Sn, Fe or Zn, and the ratio of n (Si) / n (Al + M1) of the molecular sieve is 25-30. According to the H-M1-ZSM-5 molecular sieve catalyst adopted by the invention, Sn, Fe or Zn is introduced into an existing H-type ZSM-5 molecular sieve, and the catalyst prepared by the invention has the advantages of long catalysis life, mild reaction, capability of being carried out under normal pressure, few byproducts, good selectivity, easiness in realization of reaction conditions and good industrial application prospect.

The application discloses a method and system for preparing thymol from m-p-isopropyl phenol / m-p-propyl phenol, wherein the m-p-isopropyl phenol / m-p-propyl phenol mixture is added into a reactor with a catalyst, and a reaction is carried out at a certain temperature; in the reaction, the m-p-isopropyl phenol and the like are subjected to a depropylation reaction to obtain a mixture of phenol and propylene; the reaction is completed under the control of a special online automatic analyzer; the mixture is cooled to a certain temperature; the propylene generated in the reaction is pressurized and stored in a spherical tank; an alkylation catalyst, a mixture of low-grade phenol and m-cresol are added into another reactor to carry out an alkylation reaction of phenol and propylene; and the reaction liquid is subjected to rectification to obtain high-purity phenol, high-purity m-cresol, o-isopropyl phenol, p-isopropyl phenol, 2-isopropyl-5-methyl phenol and 4-isopropyl phenol-3-methyl phenol; and the application can convert the mixed m-p-isopropyl phenol / m-p-propyl phenol with low value and small market demand into the marketable o-isopropyl phenol and p-isopropyl phenol and the like.

The invention provides a positive photosensitive resin composition, a resist film, a resist underlayer film, and a resist permanent film. The invention provides a positive photosensitive resin composition which is capable of obtaining a resist film with excellent developability, chemical resistance and heat resistance, and has good storage stability and thick film forming property. A positive photosensitive resin composition containing the following components (A) to (D): (A) a novolac phenolic resin having an acetal group-based protecting group, containing a phenol structural unit (a1) derived from m-cresol and / or o-cresol and an aldehyde structural unit (a2) derived from salicylaldehyde / (B) a polyhydroxystyrene having an acid-dissociable protecting group / (C) a photoacid generator / (D) a solvent.

The invention provides a continuous flow preparation method of m-cresol and a continuous flow preparation device of m-cresol. A continuous flow preparation method of m-cresol comprises the following steps: (1) pumping dilute sulphuric acid and m-toluidine into a first-stage microchannel reactor at the reaction temperature of 25-35 DEG C to obtain an m-toluidine sulfate solution; (2) cooling the m-toluidine sulfate solution to 5 DEG C, and dispersing the m-toluidine sulfate solution into 0.5-5 [mu] m liquid drops by a high-speed disperser; pumping the liquid drops and a diazotization reagent into a secondary microchannel reactor, and reacting at the temperature of-5 DEG C to 5 DEG C to obtain diazonium liquid; wherein the content of intermediate toluidine in the liquid phase of the diazo liquid is less than 0.5%; (3) pumping the diazonium liquid and methylbenzene into a three-stage microchannel reactor, and reacting at 75-90 DEG C to obtain hydrolysate; and (4) cooling the hydrolysate to normal temperature, carrying out phase separation to obtain an organic layer and an acid water layer, washing and rectifying the organic layer to obtain a m-cresol finished product, extracting the acid water layer, and discharging the extracted acid water layer. The yield of the m-cresol obtained by the method is obviously improved, and the environmental pollution is reduced.

The invention discloses a process for preparing phenol products from 2, 4-xylenol / 2, 5-xylenol, which comprises the following steps: adding a 2, 4-xylenol / 2, 5-xylenol mixture into a reactor added with silicon-aluminum-chromium oxide and an acidic catalyst, carrying out dealkylation reaction at 280-400 DEG C, removing propylene, ethylene and the like from o-isopropyl phenol, 2-methyl-6-ethyl phenol and the like in the reaction, and then carrying out dealkylation reaction to obtain the phenol products. The mixed phenol and olefin mixture contains phenol, cresol and 2, 4-xylenol / 2, 5-xylenol; the mixture is rapidly cooled and liquefied, olefin is discharged, rectification is carried out, and high-purity 2, 5-xylenol / 2, 4-xylenol without o-isopropyl phenol, 2-ethyl-6-cresol and the like is obtained; the preparation method comprises the following steps: reacting propylene with m-cresol by controlling the reaction temperature to obtain thymol, 4-isopropyl-3-cresol and the like, and reacting ethylene with phenol to obtain o-ethyl phenol and p-ethyl phenol; according to the method, ethyl in 2-ethyl-6-cresol and isopropyl / propyl in o-isopropyl phenol in alkylphenol are removed at high temperature, a purified 2, 5 / 2, 4-xylenol product is obtained, and a high-purity product is produced.

The present invention provides a chemically amplified positive photoresist composition, comprising: an alkali-soluble resin comprising an acrylic resin and a phenolic resin, in which the phenolic resin comprises a monomer derived from m-cresol and a monomer derived from trimethylphenol, and the weight ratio of the acrylic resin to the phenolic resin is between 1: 4 and 4: 1; and a photoacid generator. The invention also provides an application of the chemical amplification type positive photoresist composition.

The present invention is primarily directed to a polyamide powder composition useful for powder bed additive manufacturing, comprising: (a) 10% by weight to 90% by weight of a polyamide powder A having an intrinsic viscosity calculated according to equation (1) from the flow rate of a solution of the polymer and the solvent, measured in an Ubbelohde viscometer in accordance with ISO Standard 307:2019, apart from the use of m-cresol as the solvent and at a temperature of 20°C, of ​​0.8 to 2.8 with a span between 0.4 and 1.40; (b) 90% to 10% by weight of a polyamide powder B different from the polyamide powder A, having an intrinsic viscosity calculated as above of 0.8 to 2.8 with a span between 0.4 and 1.40; (c) 0 to 40 wt. % of additives selected from flow agents, stabilizers, optical brighteners, and energy absorbing additives and / or fillers; The present invention relates to a polyamide powder composition comprising: It is understood that polyamide powder B is derived from polyamide powder A, and the difference in intrinsic viscosity between powders A and B does not exceed 0.6 in absolute value.

The invention discloses a salt-tolerant strain for degrading m-cresol, the classification name of the salt-tolerant strain is Rhodococcus tectodiphilus, the strain number is GXGD-YZ-2510, and the preservation number is GDMCC No: 67304. The strain has the capability of stably growing and efficiently degrading the m-cresol in an environment with the salinity of 1-5 wt%, and the removal rate of the strain to the m-cresol is as high as 91.5% under the conditions that the salinity is 1 wt% and the initial m-cresol concentration is 100 mg / L. The method for treating the m-cresol-containing wastewater by using the strain has the characteristics of high efficiency, environmental protection and low cost, is suitable for treating the m-cresol-containing high-salt wastewater in the industries of petrifaction, chemical engineering, metallurgy and the like, has a wide application prospect, and provides novel microbial resources and technical support for biological treatment of refractory phenolic pollutants.

To provide a positive photosensitive resin composition giving a resist film excellent in developability and heat resistance and having good storage stability and thick film-forming property.SOLUTION: A positive photosensitive resin composition comprising the following components (A) to (C): (A) a molar ratio of a structural unit derived from m-cresol (a1), a structural unit derived from benzaldehyde (a2), a structural unit derived from salicylaldehyde (a3), and a structural unit derived from formaldehyde (a4) [(a1): (a2): (a3): (a4)] is 1.0:0.3 to 0.8:0.3 to 0.8:0.01 to 0.2, Novolac phenolic resin having acetal protective group / (B) photoacid generator / (C) solvent SELECTED DRAWING: None

The present application provides a kind of solid acid catalyst and the method for preparing 4,4'- butylidene bis (6-tert-butyl-m-cresol) antioxidant using the catalyst.The solid acid catalyst of the present application includes active component containing Lewis acid and catalyst carrier, the Lewis acid includes one or more of AlCl3, ZnCl2, SbCl3, the carrier includes pillared montmorillonite, the pillared montmorillonite is selected from one or more of titanium pillared montmorillonite, silicon pillared montmorillonite, aluminum pillared montmorillonite, zirconium pillared montmorillonite.The catalyst of the present application has high catalytic activity, good repeatability, simple separation and recovery process, high yield of antioxidant preparation method, green, economical and environmental preparation process.

The present invention discloses a method for selectively adsorbing p-cresol and m-cresol. Using a mixture containing p-cresol and m-cresol as the adsorption liquid, an adsorbent is used to selectively adsorb the adsorption liquid. The adsorbent is a flaky ZSM-5 zeolite molecular sieve, and the mass of p-cresol adsorbed by the adsorbent accounts for more than 97% of the total mass of m-cresol and p-cresol adsorbed by it. The flaky ZSM-5 zeolite molecular sieve can also be modified with organic bases, inorganic bases, inorganic salts, or a silica layer can be coated on its surface for modification. By using this method, p-cresol and m-cresol can be efficiently adsorbed and separated in a single time, and the adsorption selectivity of p-cresol can reach more than 97%. The best selective adsorption effect can achieve only the adsorption of p-cresol without the adsorption of m-cresol.

The invention discloses preparation of an adsorbent for preferentially adsorbing m-cresol by a liquid phase and a continuous separation and purification process method, and belongs to the technical field of chemical separation application. The process comprises the following steps: stirring and mixing a lithium-type ZSM-20 molecular sieve obtained by exchanging a LiOH solution with an ammonium-type ZSM-20 molecular sieve, organic bentonite and a pore-forming aid, molding in a ball forming mill to obtain spherical adsorbent particles with the particle size of 0.2-2.5 mm, drying, roasting, dehydrating and activating to obtain the m-cresol adsorbent for producing high-purity m-cresol. The method not only overcomes the defects of more byproducts, long process flow, large production energy consumption, limited production scale and the like in the existing industrial common alkylation method for separating the m-cresol and the p-cresol, but also changes the process route of preferentially adsorbing the p-cresol to separate the cresol mixture reported in the existing patent literature. According to the process method disclosed by the invention, the m-cresol is adsorbed preferentially, the high-purity m-cresol is produced with high selectivity, and the process method is an environment-friendly green process.

The present invention provides a biphenyl diphenol-based aluminum catalyst for preparing thymol, a preparation method thereof, and a preparation method of thymol and an application method thereof. The present invention prepares a catalyst by using a biphenyl diphenol compound and an aluminum-containing compound (such as alkyl aluminum or aluminum hydride), and then uses the catalyst to catalyze an alkylation reaction of m-cresol and propylene to prepare thymol. The catalytic effect can be further improved by adding isopropyl ether or isopropyl ester. The method of the present invention has the advantages of mild reaction conditions, high product selectivity, etc., and is particularly suitable for industrial production.

Provided is an electrical connection member in which a sealing material is disposed between a terminal and a housing, and in which high sealing performance can be maintained even when the sealing material is in contact with lubricating oil. An electrical connection member (1) is provided with: a terminal (2); a housing (3) that holds the terminal (2); and a sealing material (4) disposed between the terminal (2) and the housing (3), the housing (3) containing a polyester-based resin and / or a polyamide-based resin, the sealing material (4) containing a thermoplastic polymer and being capable of dissolving or swelling with respect to both hexafluoroisopropanol and m-cresol. And the mass change rate is less than 20% when the product is immersed in lubricating oil at 100 DEG C for 8 hours.

The present invention provides an extruded composition comprising, by weight: a) 35 to 100%, in particular 35 to 96.9%, of at least one semi-crystalline aliphatic polyamide PA1, wherein the at least one semi-crystalline aliphatic polyamide PA1 comprises at least 30%, in particular at least 50%, of recycled semi-crystalline aliphatic polyamide PA2 recovered from pipes used or at the end of their life for the exploitation of offshore or onshore oil or gas deposits, in particular from offshore oil or gas deposits, and wherein the recycled semi-crystalline aliphatic polyamide PA2 has undergone a washing and / or compounding step after removal of the pipes and crushing to form granules, b) 0 to 65%, in particular 0 to 10%, of at least one reinforcing fiber; c) 0 to 40%, in particular 3 to 30%, of at least one impact modifier, d) 0 to 30%, in particular 0 to 15%, of fillers; e) 0 to 10%, in particular 0.1 to 5%, of at least one additive, Including, The sum of components a+b+c+d+e is 100% the intrinsic viscosity of the composition, measured in m-cresol at 20°C according to ISO307:2007, is 1.2 dL / g or more, particularly in the range of 1.2 dL / g to 1.7 dL / g; It relates to extruded compositions.