56 results about "Methyl phenyl polysiloxane" patented technology

The invention provides a single-component addition-type silicone rubber which is prepared by vulcanizing the following raw materials in parts by mass: 20-50 parts of vinyl polysiloxane, 3-18 parts of vinyl methyl phenyl polysiloxane, 4-20 parts of hydrogen-containing polysiloxane, 0.01-0.1 part of platinum catalyst, 0.3-2.5 parts of inhibitor, 40-60 parts of filler, 2.0-10 parts of additive and 0.5-3 parts of tackifier. The single-component addition-type silicone rubber comprises the heat-resistant additive and the filler, so that the single-component addition-type silicone rubber prepared by vulcanizing has good high temperature resistance and low temperature aging resistance. The single-component addition-type silicone rubber comprises the catalytic inhibitor, so that the single-component addition-type silicone rubber has a higher inhibitory effect, and the storage life of the single-component addition-type silicone rubber is prolonged. When the addition-type silicone rubber is vulcanized, small molecular substances are not produced, and packaging components are not corroded.

The invention discloses a method for synthesizing organic silicon, in particular provides a method for preparing methyl phenyl silicone resin which has low curing temperature by self and is not sticky repeatedly. The invention uses the monomers of methyl trichlorosilane, dimethyldichlorosilance, phenyl trichlorosilane, dichloromethylphenylsilane, diphenyl dichlorosilane and the like to obtain a methyl phenyl silicone resin with low curing temperature and a paint film which is not sticky repeatedly after being cured by the processes of adjusting the proportion of raw materials, controlling proper reaction temperature and polymerization time, carrying out hydrolysis reaction and polycondensation reaction, etc. The invention has the advantages that the methyl phenyl silicone resin prepared by the method has the characteristics of low curing temperature, being not sticky repeatedly, being clear and transparent, high and low temperature resistance, weather resistance, being insulating and the like; the methyl phenyl silicone resin is in particular fit for dip varnish higher than grade H; and the methyl phenyl silicone resin is used for confecting insulated paint, weather-resistant paint and heat resistant paint higher than grade H, is used for heat resistant parting agent and also can be used in the fields with rigorous using requirements, such as heat resistant water blocking and sand prevention for oil drilling, etc.

The invention discloses a photocured organosilicone elastomer and a preparation method thereof. The photocured organosilicone elastomer is prepared from, by weight, 50-80 parts of vinyl methyl phenyl polysiloxane, 10-30 parts of mercaptopropyl methyl phenyl polysiloxane, 5-20 parts of mercaptopropyl silicon resin, 0-3 parts of photoinitiator and 0.1-1 part of auxiliary. Vinyl methyl phenyl polysiloxane, mercaptopropyl methyl phenyl polysiloxane, mercaptopropyl silicon resin and the photoinitiator are used as raw materials and mixed and stirred to be uniform, and the photocured organosilicone elastomer is prepared. By adjusting the quantity ratio of methyl segmers and phenyl segmers in polysiloxane and introducing mercaptopropyl silicon resin to serve as a macromolecular cross-linking agent, photocured organosilicone elastomers different in toughness, mechanical strength and refractive index can be prepared, and rapid curing molding is realized within 5-20 s under ultraviolet illumination; the process is simple, efficient and environmentally friendly and saves energy; the photocured organosilicone elastomer can be applied to the fields of electronic packaging materials, optical materials, 3D printing materials and the like.

The invention relates to a chemical method for preparing organic silicon modified epoxy resin, aiming to solve the technical problems that the compatibility is not good and the efficiency is low in a modification process of organic silicon epoxy resin. The chemical method comprises the following steps of: adding epoxy resin (one of bisphenol A epoxy resin and bisphenol F epoxy resin), hydroxyl-terminated methyl phenyl polysiloxane (with the use amount of 20-50% of the mass of the epoxy resin) and a catalyst (which is 1-5% of the total mass of two components including the epoxy resin and the hydroxyl-terminated methyl phenyl polysiloxane) into a reactor; uniformly agitating and gradually raising the temperature to 60-140 DEG C, and reacting for 4-6 hours; after the reaction, lasting under the condition of 120-130 DEG C / 5-10 mmHg for 0.5 hours; and desorbing low-boiling-point compounds, which are generated in the reaction, in vacuum to obtain the organic silicon modified epoxy resin.

The invention discloses a phenyl organic silicon modified polyurethane resin, a preparation method and application thereof, and belongs to the field of polyurethane resin. The structural formula of the phenyl organic silicon modified polyurethane resin is as shown in the description; the preparation method of the phenyl organic silicon modified polyurethane resin comprises the following steps: dissolving phenylsilanediol into an organic solvent, taking a reaction with chlorosilane (R<2>SiCH3Cl2) to prepare hydroxyl-terminated methyphenyl polysiloxane, under the action of a catalyst, mixing the hydroxyl-terminated methyphenyl polysiloxane with a silane compound to obtain amino or imino terminated methyphenyl polysiloxane, then in the atmosphere of argon, mixing diisocyanate, amino or imino terminated methyphenyl polysiloxane, polyethylene glycol or polyol with a mixed solvent, and taking a reaction to obtain the phenyl organic silicon modified polyurethane resin. The phenyl organic silicon modified polyurethane resin has the advantages of being capable of reducing the water absorption, improving the hydrophobicity, and improving the compatibility of organic silicon and polyurethane, and can be prepared to thin film with good properties; the preparation method is simple and feasible.

The invention relates to an organic silicon potting adhesive containing a POSS (polysilsesquioxane) group and a preparation method of the organic silicon potting adhesive. The organic silicon potting adhesive comprises a component A and a component B and is characterized in that the component A is formed by a POSS-phenyl organosilicon polymer and excessive hydrogen-terminated methyl phenyl polysiloxane which is not involved in the reaction, wherein the POSS-phenyl organosilicon polymer is formed by hydrosilylation to graft hydrogen-terminated methyl phenyl polysiloxane by taking polysiloxane cage octavinyl polysilsesquioxane as a main chain; the component B is methyl phenyl vinyl polysiloxane. By virtue of the phenyl of phenyl vinyl polysiloxane in the component A of the potting adhesive, the high refractive index of the material is ensured; by virtue of an introduced organic polysiloxane system, the heat resistance of the material is improved, the number of cross-linking points is increased and the refractive index of the material is increased; meanwhile, by virtue of phenyl polysiloxane matrix, the high refractive index of the material is ensured; the transparent organic silicon material with high heat resistance and high refractive index can be applied to encapsulation of HB-LED.

The invention relates to an organic silicon rubber for LED packaging. In order to solve the problems that during direct physical blending of POSS (polyhedral oligomeric silsesquioxane) with vinyl silicone oil and hydrogen containing silicone oil, POSS has poor compatibility with vinyl silicone oil and hydrogen containing silicone oil and is very easy to precipitate, so that the light transmittance and mechanical properties of the product can be affected, the invention provides a preparation method of a POSS skeleton containing vinyl silicone oil. The method includes: mixing POSS with one or two of dimethyl polysiloxane and methylphenyl polysiloxane at any proportion to obtain a mixture, in the presence of a catalyst, carrying out end-capping with a vinyl end-capping reagent, and performing a polymerization reaction to obtain the POSS skeleton containing vinyl silicone oil. The preparation method is simple. The invention also provides application of the POSS skeleton containing vinyl silicone oil in LED packaging materials.

The invention relates to high-temperature resisting bonding sealed silicone resin and a preparation method thereof. The high-temperature resisting bonding sealed silicone resin is prepared from the following raw materials: methyl phenyl polysiloxane-b-polyphenylsilsesquioxane block copolymer resin, methyl phenyl hydroxy silicone oil, functional POSS (Polyhedral Oligomeric Silsesquioxane), heat-resisting filler, an adhesive, a cross-linking agent and a catalyst. The preparation method comprises the following steps: firstly, mixing the methyl phenyl polysiloxane-b-polyphenylsilsesquioxane block copolymer resin, the methyl phenyl hydroxy silicone oil and the functional POSS, and then carrying out vacuum stirring and dehydrating at the temperature of 100 to 120 DEG C for 1 to 2 hours; secondly, adding the heat-resisting filler and the cross-linking agent for carrying out vacuum stirring for 30 to 60 minutes, then adding the adhesive and the catalyst for carrying out vacuum stirring for 30 to 60 minutes, discharging and sealing to obtain the high-temperature resisting bonding sealed silicone resin. The resin has the advantages of better heat-resisting property and mechanical property, and no need of white carbon black for reinforcing and priming; in addition, the retention rate of shear strength is more than 90 percent after the resin is subjected to 400 DEG C*1 hour high-temperature treatment, and tensile strength, shear strength and peel strength are still more than 80 percent after the resin is subjected to 330 DEG C*24 hour treatment.

The invention relates to a preparation method of methyl phyenyl cyclosiloxane, aiming at solving the technical problem that the invention provides the preparation method of the methyl phenyl polysiloxane containing SiPhO1.5, namely TP under catalysis of alkali through thermal cracking. The particular steps are that: 1) polymethylphenyl sioxane containing TP is mixed evenly with catalysts (lithium hydroxide, potassium carbonate or sodium carbonate), and catalyst dosage is 0.1 to 10 percent of the polymethylphenyl sioxane dosage; 2) a low-boiling material condensed by the polymethylphenyl sioxane containing TP is removed under the vacuum and heating-up temperature of 200 to 250 DEG C; 3) the polymethylphenyl sioxane containing TP is cracked under high vacuum and highly heating-up temperature of 300 to 350 DEG C, thereby obtaining the product by collecting 250 to 290 DEG C / 2mmHg distillations.

A non-skid coating described herein attempts to overcome the deficiencies of the conventional coatings with improved external durability and color retention, a reduced level of VOCs, and direct-to-metal (DTM) adhesion using organo-siloxane chemistry. The non-skid coating has a first component having an amino-functional siloxane resin; a second component having a non-aromatic epoxy resin; a spherical filler for lowering viscosity; a pigment; a coarse aggregate; and a thixotropic agent. The amino-functional siloxane resin can be an amino-functional methyl phenyl polysiloxane, diphenyl polysiloxane or silsesquioxane-based resin. The non-aromatic epoxy resin can be cycloaliphatic or aliphatic. The first component is about 5% to 20% weight of the coating, and the second component is about 80% to 95% weight of the coating.

The invention discloses leather cleaning, nourishing and care cream, which comprises the following components in percentage by weight: 1 to 5 percent of molecular distilled monoglyceride, 1 to 5 percent of stearic acid, 8 to 15 percent of medical white vaseline, 1 to 5 percent of methyl phenyl polysiloxane, 2 to 6 percent of alcohol 16-18, 1 to 5 percent of coconut water oil-fatty acid-diethanol amide, 0.5 to 2.5 percent of lanolin, 0.2 to 1 percent of diazolidinyl urea, 0.2 to 1 percent of plant essence, 0.2 to 1 percent of aloe liquid, 0.5 to 3 percent of vegetable wax, 0.1 to 0.5 percent of natural zeolite, and 50 to 85 percent of deionized water. The invention also provides a production method for the cream. The cream integrates maintenance and care into a whole, is environment-friendly, has the properties of cleaning and polishing leather and resisting water, cracking, mildew and bacteria, is safe, healthy and natural, does not contain paraffin, is not greasy or sticky, keeps the natural color of the leather, is anti-fouling and clean, and is applied widely.

The invention discloses a method for synthesizing organic silicon, in particular provides a method for preparing methyl phenyl silicone resin which has low curing temperature by self and is not sticky repeatedly. The invention uses the monomers of methyl trichlorosilane, dimethyldichlorosilance, phenyl trichlorosilane, dichloromethylphenylsilane, diphenyl dichlorosilane and the like to obtain a methyl phenyl silicone resin with low curing temperature and a paint film which is not sticky repeatedly after being cured by the processes of adjusting the proportion of raw materials, controlling proper reaction temperature and polymerization time, carrying out hydrolysis reaction and polycondensation reaction, etc. The invention has the advantages that the methyl phenyl silicone resin prepared by the method has the characteristics of low curing temperature, being not sticky repeatedly, being clear and transparent, high and low temperature resistance, weather resistance, being insulating and the like; the methyl phenyl silicone resin is in particular fit for dip varnish higher than grade H; and the methyl phenyl silicone resin is used for confecting insulated paint, weather-resistant paint and heat resistant paint higher than grade H, is used for heat resistant parting agent and also can be used in the fields with rigorous using requirements, such as heat resistant water blocking and sand prevention for oil drilling, etc.

The invention relates to an isocyanate-terminated polysiloxane material that can preferably be used as a curing agent, hardener or co-reactant in coatings. The invention further relates to a method of manufacturing the isocyanate-terminated polysiloxane material by partially hydrolyzing a methoxy-functional polysiloxane such as a methyl phenyl polysiloxane, and reacting it with a polyisocyanate to yield the isocyanate-terminated polysiloxane hardener. The hardener can preferably be used with any isocyanate-reactive functional group of another component to form coating systems, including acrylics, polyesters, epoxies and urethanes.

The invention discloses an organosilicone modified isocyanate prepolymer for solvent-free type synthetic leather and a preparation method thereof. The prepolymer contains a compound in the structure shown in the description, wherein R is aryl or fatty group; a and b are natural numbers. The preparation method comprises the following steps that (1) octamethylcyclotetrasiloxane, 2,4,6,8-tetramethyl-2,4,6,8-tetraphenylcyclotetrasiloxane and acid catalysts are added into a reactor; then, tetramethyl dihydrodisiloxane is added; ring-opening polymerization reaction is performed for 4 to 6h at 60 to80 DEG C; temperature reduction, neutralization, water washing, filtering and micromolecule by-product removal are performed to obtain hydrogen-terminated blocking methyl phenyl polysiloxane; (2) thehydrogen-terminated methyl phenyl polysiloxane obtained in the step (1) and allyl amine react under H2PtCl6 catalysts to prepare hydrogen-terminated blocking methyl phenyl polysiloxane; (3) the product in the step (2) is dehydrated and then reacts with isocyanate monomers to generate the prepolymer with the terminal group being NCO.

The invention relates to an isocyanate-terminated polysiloxane material that can preferably be used as a curing agent, hardener or co-reactant in coatings. The invention further relates to a method of manufacturing the isocyanate-terminated polysiloxane material by partially hydrolyzing a methoxy-functional polysiloxane such as a methyl phenyl polysiloxane, and reacting it with a polyisocyanate to yield the isocyanate-terminated polysiloxane hardener. The hardener can preferably be used with any isocyanate-reactive functional group of another component to form coating systems, including acrylics, polyesters, epoxies and urethanes.

The invention aims to provide a curable silicon rubber composition which is high in refractive index, is good in rubber-like performance and strength characteristics and hardly has surface viscosity after curing. A coating agent is developed based on the composition. The curable silicon rubber composition comprises a component A, a component B and a component C, wherein the component A contains methyl phenyl polysiloxane with unsaturated bonds in aliphatic series, and the viscosity of the component A at 25 DEG C is 2000-20000 mPa.s; the component B is methyl phenyl polysiloxane of which each molecule contains a plurality of silicon-hydrogen bonds, and the viscosity of the component B at 25 DEG C is 2000-20000 mPa.s; the component C is a platinum family metal catalyst; and the mass of the component B occupies 10-90% of the total mass of the component A and the component B.

A non-skid coating described herein attempts to overcome the deficiencies of the conventional coatings with improved external durability and color retention, a reduced level of VOCs, and direct-to-metal (DTM) adhesion using organo-siloxane chemistry. The non-skid coating has a first component having an amino-functional siloxane resin; a second component having a non-aromatic epoxy resin; a spherical filler for lowering viscosity; a pigment; a coarse aggregate; and a thixotropic agent. The amino-functional siloxane resin can be an amino-functional methyl phenyl polysiloxane, diphenyl polysiloxane or silsesquioxane-based resin. The non-aromatic epoxy resin can be cycloaliphatic or aliphatic. The first component is about 5% to 20% weight of the coating, and the second component is about 80% to 95% weight of the coating.

The invention discloses a high-temperature resistance methyl phenyl polysiloxane resin powder coating and a preparation method thereof. The coating comprises following components, in parts by weight: 47 to 53 parts of methyl phenyl polysiloxane resin, 0.3 to 0.8 part of tert-butyl peroxide, 8 to 12 parts of methyltris(methylethylketoxime)silane, 1.1 to 1.3 parts of organic silicon levelling agent, 2.5 to 3.0 parts of polysiloxanes, 3.3 to 3.8 parts of triglycidyl isocyanurate, 9 to 10 parts of aluminium nitride powder, 5.5 to 7.5 parts of nano brick slag powder, 1.3 to 1.8 parts of 1-methyl amyl alcohol and 2 to 3 parts of propylene glycol methyl ether acetate. The methyl phenyl polysiloxane resin has the advantages of excellent damp-resistance, waterproofness, stainlessness, cold-resistance, ozone-resistance and weatherability. The methyl phenyl polysiloxane resin has a good high-temperature resistance performance, and the heat-resistance temperature arrives at 550 DEG C or more.

An inelastic collision and rolling viscous resistance particle coupling energy dissipation cutter rod relates to a cutting tool. The cutter rod comprises a cutter rod body, a cutter rod connection piece, a cutting head and coupling energy dissipation plates. A groove array is formed in each coupling energy dissipation plate. A surface low recovery coefficient particle and at least two high surface viscous resistance macromolecule particles are arranged in each groove, a high polymer film wraps the surface of each high surface viscous resistance macromolecule particle, and a fixed groove for installing the coupling energy dissipation plate is formed in each coupling energy dissipation plate. After multiple layers of coupling energy dissipation plates are installed in the cutter rod, vibration energy generated by cutting force can be dissipated quickly and gradually, energy dissipation factors are high, the vibration restraining effect is obvious, and boring stability and accuracy of parts with deep holes are effectively improved. The cutter rod is low in cost and easy to implement. The surface low recovery coefficient particles utilize a metal material as the base material, methyl phenyl polysiloxane and acrylate interpenetration polymer wraps the base material, and the surface low recovery coefficient particles are high in strength, not prone to corrosion, long in service life and capable of being used in a long term.

The invention discloses a water-borne polyurethane not containing organic tin. The water-borne polyurethane is prepared from the following components in parts by weight: 25 to 80 parts of aromatic polyester polyol, 10 to 20 parts of diisocyanate, 10 to 40 parts of hydroxyalkyl-terminated methyl phenyl polysiloxane, 0.015 to 0.06 part of catalyst, 2 to 10 parts of hydrophilic chain-extending agent, 2 to 10 parts of amine chain-extending agent, 5 to 10 parts of solvent and 2 to 5 parts of salt forming agent, wherein the catalyst is selected from one or two of organic bismuth, organic zinc or organic zirconium. The water-borne polyurethane has the advantages that the hydrophilic chain-extending agent and the hydroxyalkyl-terminated methyl phenyl polysiloxane are used as main polymerizing monomers, so that the hydrolysis-resistant property and heat-resistant property are better; the water-borne polyurethane is more suitable for application environments with complicated water system; the water-borne polyurethane does not contain the organic tin catalyst, so that the more environment-friendly property is realized.

The invention relates to phenyl polysiloxane containing hydrogen and a preparation method thereof, the phenyl polysiloxane containing hydrogen is prepared by using 60 to 80 parts of methyl phenyl polysiloxane, 20 to 35 parts of methylhydracyclosiloxane, 5 to 8 parts of end-capping reagent tetramethyl dihydro disiloxane, and taking cation exchange resin as a catalyst. The process route is simple and convenient, economic and environment friendly and raw materials are easy to obtain. The prepared phenyl polysiloxane containing hydrogen by utilizing the technology has the usability of high phenyl content, good transparency, high refraction coefficient and excellent usability.

The invention relates to the technical field of coatings, and discloses a high-temperature-resistant paint composition, a high-temperature-resistant paint, a preparation method and application of the high-temperature-resistant paint, and a high-temperature-resistant coating. The paint composition is obtained by compounding methyl phenyl polysiloxane resin, polysilazane, alkylsilane, a silane coupling agent and a solvent with specific content; the coating prepared from the paint composition has the advantages of being easy to clean, resistant to high temperature and good in adhesiveness; and meanwhile, when the coating is applied to kitchen appliances, the electric appliances can be endowed with hydrophobic and oleophobic effects.

The present invention provides a RTV monocomponent hydrophobic long-acting antifouling flashing paint for porcelain insulator for high-voltage transmission line of power system and its production method. It is formed from the following components (by weight %): 20-40% of terminal hydroxy polysiloxane, 2-10% of basic fire-resisting agent, 3-20% of reinforcing agent, 1-5% of additive, 0.2-0.4% of catalyst, 1-5% of cross-linking agent and 30-60% of diluting agent.

The invention discloses a hot-melt OCA optical adhesive film and a preparation method thereof. The hot-melt OCA optical adhesive film is a novel optical-grade material taking hot-melt resin and organic silicon resin as the main body, wherein the hot-melt resin comprises thermosetting resin and thermoplastic resin, and the organic silicon resin comprises: reactive methyl phenyl polysiloxane, methylphenyl T resin, methyl phenyl silicon resin, a phenyl cross-linking agent, a phenyl chain extender and an additive. Compared with the traditional OCA, the OCA provided by the invention has the advantages of excellent light transmission, bonding strength, cold and hot impact resistance and weather resistance.

The invention relates to a methoxy-terminated methylphenyl polysiloxane resin, a silicone coating glue, a preparation method and an application thereof, and the silicone material for preparing the methoxy-terminated methylphenyl polysiloxane resin is Oxygen monomers include: 19-30 parts of diphenyldimethoxysilane, 20-30 parts of dimethyldimethoxysilane and 40-60 parts of methyltrimethoxysilane; The mass content of phenyl groups in the group-terminated methylphenyl polysiloxane resin is 23% to 25%. The above-mentioned methoxy-terminated methylphenyl polysiloxane resin is terminated with methoxy groups and has a suitable content of phenyl groups, so that its refractive index is very close to that of fumed silica and has a suitable viscosity . Using this polysiloxane resin to replace the base material in the traditional organic coating adhesive, and adding fumed silica as a reinforcing agent can significantly improve the mechanical properties such as hardness and tensile strength on the basis of ensuring high transparency , Adhesive performance and air tightness.

The invention relates to the technical field of high polymer materials, in particular to an organic silicone adhesive containing a nano-silver material and a preparation method thereof. The organic silicone adhesive is prepared from the following components: vinyl-terminated methyl phenyl polysiloxane, an amine compound, terminal group hydrogen-containing polysiloxane, o-hydroxybenzophenone, nano-silver, a toughening agent, heat-resistant filler, a curing agent and a platinum catalyst, and has an antibacterial function, and is better in durability and long in service life. The preparation method comprises the following steps of weighing vinyl-terminated methyl phenyl polysiloxane, the amine compound, the terminal group hydrogen-containing polysiloxane, the toughening agent and the platinumcatalyst, and adding the materials into a sealed reaction device for heating under the protection of inert gas, adding the nano-silver and the heat-resistant filler, and stirring, then adding o-hydroxybenzophenone and the curing agent, and continuously stirring, decompressing to remove bubbles, and heating and curing to obtain an organic silicone adhesive. The preparation process is simple, the obtained organic silicone adhesive is good in antibacterial effect, and the durability of the organic silicone adhesive is improved.