17 results about "Methyl phenyl polysiloxane" patented technology

The invention discloses a polysiloxane multifunctional anticorrosive coating and a preparation method thereof. The polysiloxane multifunctional anticorrosive coating is prepared from the following raw materials in parts by weight: 40 to 60 parts of vinyl-terminated methyl phenyl polysiloxane, 5 to 15 parts of epoxy resin, 1 to 3 parts of compound modified boron nitride, 10 to 15 parts of Na-montmorillonite, 4 to 8 parts of filler, 1 to 3 parts of flatting agent, 1 to 3 parts of curing agent, 1 to 2 parts of dispersing agent, 1 to 2 parts of coalescing agent, 1 to 2 parts of defoaming agent and 5 to 12 parts of absolute ethyl alcohol; the raw materials are reasonably proportioned, mixed, stirred and ball-milled to prepare the multifunctional anticorrosive polysiloxane coating, and the multifunctional anticorrosive polysiloxane coating is obtained after the coating is dried. The polysiloxane multifunctional anticorrosive coating provided by the invention has excellent corrosion resistance, bacteriostasis, wear resistance and water resistance, and can be widely applied to corrosion prevention of metal materials.

The invention relates to the technical field of coatings, in particular to a photo-thermal super-hydrophobic coating as well as a preparation method and application thereof. The invention provides a photo-thermal super-hydrophobic coating. The photo-thermal super-hydrophobic coating is prepared from the following raw materials in parts by weight: 3 to 5 parts of organic silicon polysilazane, 5 to 7 parts of methyl phenyl polysiloxane, 3 to 5 parts of vinyl chloride and vinyl acetate copolymer, 4 to 6 parts of modified ferroferric oxide, 5 to 7 parts of fluorinated multi-walled carbon nanotube, 4 to 6 parts of fluorinated black titanium dioxide, 59 to 82 parts of organic solvent and 0.02 to 0.2 part of defoaming agent. Wherein the modified ferroferric oxide is ferroferric oxide coated with copper chloride. The photo-thermal super-hydrophobic coating provided by the invention has ultrahigh hydrophobic performance and good photo-thermal conversion performance, the water contact angle can reach 155 degrees or above, the rolling angle is less than 10 degrees, the surface hardness of the coating is 4H or above, the adhesive force is grade 0, and the comprehensive performance is excellent.

The invention discloses a blended neutron / gamma discrimination polysiloxane scintillator and a preparation method thereof. The polysiloxane scintillator is composed of a matrix, a primary fluorescent dye, a secondary fluorescent dye and a cross-linking agent. A matrix of the scintillator is a copolymer of methyl phenyl polysiloxane and phenyl methyl siloxane, a main fluorescent dye is 2, 5-diphenyl oxazole (PPO), a secondary fluorescent dye is selected from 7-diethylamino-4-methylcoumarin (MDAC), and a cross-linking agent is 1, 3-divinyl-1, 3-diphenyl-1, 3-dimethyl siloxane. The obtained polysiloxane scintillator has good stability and can be used for neutron detection and neutron / gamma discrimination in a strong irradiation field environment.

The invention relates to the technical field of adhesives, and discloses a functional organic silicon adhesive and a preparation method thereof.The functional organic silicon adhesive is formed by mixing vinyl-terminated methyl phenyl polysiloxane serving as a base material and a tackifying component, a fiber anti-cracking component and the like serving as auxiliary materials. The fiber anti-cracking component contains a large number of branched macromolecular chains connected through silicon-oxygen bonds, and rich silicon-hydrogen bonds exist in the macromolecular chains at the same time, so that the vinyl-terminated methyl phenyl polysiloxane matrix and the tackifying component can be connected in the subsequent adhesive curing process in which a platinum catalyst participates, and the viscosity of the adhesive is improved. According to the present invention, the palm fiber exists in the adhesive in the form of the chemical connection point through the connection mode, the anti-cracking performance of the adhesive is enhanced, the tackifying component can enter the adhesive matrix, and the ether bond and the active group in the glucose can form the hydrogen bond with the bonded matrix so as to further enhance the bonding performance of the organic silica gel adhesive;

The invention provides a long-acting bionic antimicrobial functional coating as well as a preparation method and application thereof, and relates to the technical field of marine coatings, the long-acting bionic antimicrobial functional coating comprises a component A and a component B, the component A is prepared from the following raw materials: silanol-terminated polydimethylsiloxane, methyl phenyl polysiloxane, a methylhydrosiloxane-dimethyl siloxane copolymer, an auxiliary agent and an organic solvent a; and the component B comprises the following raw materials: ethyl silicate and an organic solvent b. According to the long-acting bionic antimicrobial functional coating provided by the invention, marine organisms cannot be attached to the surface of a ship body or easily fall off, so that the antifouling effect is achieved, and the pollution path of antifouling paint to the marine environment is fundamentally cut off.

The present invention is a methylphenylpolysiloxane mixture characterized by containing (A) a methylphenylpolysiloxane represented by formula (1), and (B) a methylphenylpolysiloxane represented by formula (2), the content of the component (B) being 0.1-5 mol% based on 100 mol% of the total amount of the components (A) and (B). Thus, provided is a methylphenylpolysiloxane having an increased phenyl group introduction amount, and having a base-sensitive functional group such as an acrylic group, a methacrylic group or a mercapto group introduced in the methylphenylpolysiloxane. (In formula (1), A is a group selected from a (meth)acryloxymethyl group, a 3-(meth)acryloxypropyl group, and a 3-mercaptopropyl group; a is an integer of 2 or more; b is an integer of 3 or more; and c is an integer of 0 or more, where a<b and 5≤a+b+c≤100). (In formula (2), a, b, and c are the same as the aforementioned).

The invention discloses a photo-thermal dual-curing organic silicon composition as well as a preparation method and application thereof. Relates to the technical field of LED packaging. Raw materials of the photo-thermal dual-curing organic silicon composition comprise the following components: vinyl-terminated MT type hydroxyphenyl polysiloxane; linear vinyl terminated methyl phenyl polysiloxane; a linear hydrogen group terminated phenyl polysiloxane; a catalyst; the vinyl terminated MT type hydroxyl phenyl polysiloxane is phenyl polysiloxane containing silicon hydroxyl and silicon vinyl. The photo-thermal dual-curing organic silicon composition disclosed by the invention is an organic silicon composition which is good in mechanical strength, good in thixotropy, high in interface bonding force and resistant to high temperature.

The present invention discloses a polysiloxane multifunctional anti-corrosion coating and a preparation method thereof, wherein the polysiloxane multifunctional anti-corrosion coating comprises the following raw materials in parts by weight: 40-60 parts of vinyl-terminated methylphenyl polysiloxane, 5-15 parts of epoxy resin, 1-3 parts of composite modified boron nitride, 10-15 parts of sodium montmorillonite, 4-8 parts of filler, 1-3 parts of leveling agent, 1-3 parts of curing agent, 1-2 parts of dispersant, 1-2 parts of film-forming aid, 1-2 parts of defoaming agent, and 5-12 parts of anhydrous ethanol; the polysiloxane multifunctional anti-corrosion coating is prepared by mixing and stirring the raw materials in a reasonable proportion and ball milling, and the polysiloxane multifunctional anti-corrosion coating is obtained after the coating is dried. The polysiloxane multifunctional anti-corrosion coating provided by the present invention has excellent anti-corrosion, antibacterial, wear-resistant and waterproof properties, and can be widely used in the anti-corrosion of metal materials.

The invention discloses an underfill adhesive for packaging a large-size chip, a preparation method of the underfill adhesive and a packaging structure, and the underfill adhesive comprises the following raw materials in parts by mass: 53-65 parts of an inorganic filler, 22-28 parts of epoxy resin, 11-15 parts of a curing agent, 1-3 parts of an epoxy reactive diluent, 0.2-0.4 part of a dispersant, 0.1-0.3 part of a silane coupling agent and 0.2-0.4 part of an accelerant. Wherein the epoxy resin comprises nano silicon dioxide filled bisphenol A epoxy resin and methyl phenyl polysiloxane resin. The underfill adhesive provided by the invention has excellent fluidity and flexibility, low thermal shrinkage and water absorption, and high adhesive force and reliability, and is suitable for underfill of chips, especially large-size chips; in addition, the packaging structure using the underfill adhesive for underfilling also solves the problem that different material interfaces of the packaging structure are easy to layer.

The present invention relates to the technical field of coatings, and specifically relates to a photothermal superhydrophobic coating, a preparation method thereof, and an application thereof. The present invention provides a photothermal superhydrophobic coating, which comprises the following raw materials in parts by weight: 3-5 parts of organosilicon polysilazane, 5-7 parts of methylphenyl polysiloxane, 3-5 parts of vinyl chloride-vinyl acetate copolymer, 4-6 parts of modified iron oxide, 5-7 parts of fluorinated multi-walled carbon nanotubes, 4-6 parts of fluorinated black titanium dioxide, 59-82 parts of organic solvent, and 0.02-0.2 parts of defoamer; wherein the modified iron oxide is iron oxide coated with copper chloride. The photothermal superhydrophobic coating provided by the present invention has ultra-high hydrophobic performance and good photothermal conversion performance, the water contact angle can reach more than 155°, the rolling angle is less than 10°, and the surface hardness of the coating is 4H or above, and the adhesion is grade 0, with excellent comprehensive performance.

This invention discloses a low-cost, rapidly prepared neutron / gamma-discriminating polysiloxane scintillator and its preparation method. The polysiloxane scintillator comprises a matrix, a primary fluorescent dye, a secondary fluorescent dye, and a crosslinking agent. The scintillator matrix is ​​a copolymer of methylphenyl polysiloxane and polyphenyl-(dimethylsiloxane), the primary fluorescent dye is 2,5-diphenyloxazole (PPO), the secondary fluorescent dye is 7-diethylamino-4-methylcoumarin (MDAC), and the crosslinking agent is 1,3-divinyl,1,3-diphenyl,1,3-dimethylsiloxane. The resulting polysiloxane scintillator possesses neutron and gamma discrimination capabilities, good radiation resistance, stability, and low cost, making it suitable for use in neutron detectors.

The invention discloses a neutron / gamma discrimination polysiloxane scintillator which is low in cost and can be rapidly prepared and a preparation method of the neutron / gamma discrimination polysiloxane scintillator. The polysiloxane scintillator is composed of a matrix, a primary fluorescent dye, a secondary fluorescent dye and a cross-linking agent. A matrix of the scintillator is a copolymer of methyl phenyl polysiloxane and polyphenyl-(dimethyl siloxane), a main fluorescent dye is 2, 5-diphenyl oxazole (PPO), a secondary fluorescent dye is selected from 7-diethylamino-4-methylcoumarin (MDAC), and a cross-linking agent is selected from 1, 3-divinyl, 1, 3-diphenyl and 1, 3-dimethyl siloxane. The obtained polysiloxane scintillator has the capability of discriminating neutrons and gamma rays, has good anti-irradiation performance and stability, is low in cost, and can be used for neutron detectors.

The application discloses a preparation method of an organic / inorganic composite coating with transparency, ultraviolet resistance and antifouling property, and comprises the following steps: step one, preparing SiO2 by adopting an acid catalysis sol-gel method; and step two, preparing the organic / inorganic hybrid antifouling coating with high hardness, transparency and ultraviolet resistance by graft polymerization. The method prepares SiO2 by the sol-gel method, constructs a continuous silicone resin network by using methylphenyl polysiloxane resin, simultaneously adds SiO2 of the inorganic phase and MT-PDMS and octocrylene of the organic phase as polymerization reactants, and prepares the organic / inorganic hybrid coating through grafting and polymerization. The unique design makes the coating have excellent transparency, antifouling property and ultraviolet resistance. In addition, the coating also has good hardness and friction resistance, and still maintains excellent transparency and ultraviolet resistance in low-temperature and high-temperature environments.

The invention relates to the technical field of anti-skid sprays, and particularly discloses a sole anti-skid agent and a preparation method thereof. The sole anti-slip agent comprises the following raw materials in percentage by mass: 15-25% of polydimethylsiloxane, 2-5% of methyl phenyl polysiloxane, 4-5% of modified silicon dioxide, 3-5% of butyl rubber, 5-6% of an auxiliary agent and the balance of a solvent, and the modified silicon dioxide is sea urchin-shaped silicon dioxide coated with an amphiphilic polymer. The anti-skid agent for the shoe sole can increase the friction force between the shoe sole and the ground through the microstructure of the film layer and the interaction of water molecules and oil stains in the dry and wet scene (for example, the tile ground encounters water) and even the scene with slight oil stains, and has the advantages of excellent anti-skid and wear-resistant performance, high film forming speed and convenience in use.

The invention discloses a preparation method of an organic / inorganic composite coating with transparency, ultraviolet resistance and antifouling property. The method comprises the following steps: step 1, preparing SiO2 by adopting an acid catalysis sol-gel method; and 2, preparing the organic / inorganic hybrid antifouling coating with high hardness, transparency and ultraviolet resistance through graft polymerization. According to the method, SiO2 is prepared through a sol-gel method, a continuous organic silicon resin network is constructed through methyl phenyl polysiloxane resin, meanwhile, inorganic-phase SiO2 and organic MT-PDMS and octocrylene are added to serve as polymerization reactants, and the organic / inorganic hybrid coating is prepared through grafting, polymerization and the like. Due to the unique design, the coating has excellent transparency, antifouling property and ultraviolet resistance. In addition, the coating also has good hardness and friction resistance, and still keeps excellent transparency and ultraviolet resistance in low-temperature and high-temperature environments.

The application relates to the technical field of defoaming agent preparation, in particular to a high-content organic silicon defoaming agent composition for a high-temperature and high-shear system. The high-content organic silicon defoaming agent composition is prepared by the following steps: firstly, octamethylcyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane and hydrogen-containing polymethylsiloxane are copolymerized to construct a methylphenyl polysiloxane skeleton; secondly, acetyl-terminated allyl epoxy oxirane / epoxy propane copolyether and allyl glycidyl ether are introduced step by step; then, the obtained product is sequentially reacted with N,N-diethyl-1,3-propanediamine, phenyl isocyanate, diisopropylamine and maleic anhydride to obtain a urea-based / esterified modified polysiloxane; finally, the urea-based / esterified modified polysiloxane is compounded with methylphenyl silicone oil, dimethyl silicone oil, hydrophobic fumed silica and precipitated silica to obtain the high-content organic silicon defoaming agent composition. The obtained defoaming agent has the advantages of instant defoaming, excellent sustained defoaming, strong shear resistance, storage stability and no floating oil in a high-temperature circulating cleaning liquid system, a high-speed sand mill slurry system and the like.

The invention discloses a heat-resistant insulating coating and a preparation method of the heat-resistant insulating coating, and belongs to the technical field of coatings. The coating is prepared from the following raw materials in parts by weight: 30 to 40 parts of methyl phenyl polysiloxane resin, 10 to 20 parts of polysiloxane modified bismaleimide resin, 40 to 60 parts of filler, 5 to 10 parts of a curing agent, 0.01 to 0.07 part of a defoaming agent and 0.01 to 0.3 part of a flatting agent. The heat resistance of the insulating paint is effectively improved.