71 results about "Sodium tetrafluoroborate" patented technology

The present invention discloses a sodium ion battery negative electrode sheet, the negative electrode sheet is a porous graphite film structure, the diameter of the pores is from 2 to 30 microns, the distance between the centers of the circles of the pores is 5 to 50 microns, mass ratio of carbon atoms in the porous graphite film is greater than 99%, the negative electrode sheet may be used directly as the sodium ion battery negative electrode sheet, can avoid the use of a conductive agent, a binder and a metal collector, and has high capacity, corrosion resistance and good conductivity. The present invention also discloses a sodium ion battery using the negative electrode sheet, the sodium ion battery comprises a positive electrode sheet, a negative electrode sheet, a separator and an electrolyte, the sodium ion battery electrolyte solvent is one or more than one of diethanol dimethyl ether, dimethyl ether tetraethanol, and tetrahydrofuran, the electrolyte is one of sodium perchlorate, sodium hexafluorophosphate, sodium tetrafluoroborate and sodium trifluoromethanesulfonate, and the sodium ion battery is simple in production process and good in charging and discharging cycle stability, and has good prospects in the new energy field.

The invention relates to a polymer-ionic liquid composite clay stabilizer used for restraining clay hydration expansion in petroleum industry and a synthesis method of the polymer-ionic liquid composite clay stabilizer. The synthesis method comprises the steps of: reacting single 6-allyl amino beta-cyclodextrin, acrylamide and acrylic acid under initiation of ammonium persulfate and sodium hydrogen sulfite in an aqueous solution under the condition of pH of 7 and the temperature of 35 DEG C, purifying by aqueous solution after 8 hours of reaction and drying to obtain a polymer; refluxing quinoline and n-butyl bromide for 48 hours at 60 DEG C to obtain brominated 1-normal-butyl-quinoline salt, stirring for 3 days with sodium fluoborate in acetonitrile, filtering, carrying out rotary evaporation and drying to obtain tetrafluoroborate 1-normal-butyl-quinoline salt ([bquin]BF4); refluxing the polymer and the [bquin]BF4 for 4 hours at 50 DEG C to obtain a polymer-ionic liquid compound. The polymer-ionic liquid compound has good water solubility, stability and clay expansion restraining power and the antiswelling rate to bentonite can reach 90.3%.

The invention provides an organic promoting phosphating solution, a preparation method thereof and the application thereof; wherein, the phosphating solution comprises basic solution and an accelerant which have the weight ratio of 1.5-2.5:1; the basic solution is the mixture of iron powders, phosphoric acid, zinc oxide, hydrofluoric acid, carbonate, fluosilicic acid and water; the accelerant is the mixture of sodium fluoborate, tartaric acid, sodium chlorate, caustic soda, trinitrobenzene sulfonic acid and water. The phosphating solution has wide phosphating process, can be used within the temperature of 5-65 DEG C, is suitable for the treatment before coating of automobiles, electric apparatuses, furniture and mechanical equipment, has simple production and use methods and meets the requirement of environmental protection.

The invention provides a method for synthesizing a hyperbranched ionic liquid fire retardant based on HCCP. According to the method, HCCP reacts with trialkylamin, trialkyl phosphorus, and N-alkyl imidazole to realize ionization, salts such as sodium tetrafluoroborate, potassium hexafluorophosphate and bistrifluoromethanesulfonimide lithium, which contain different anions, are used for ion exchange, so that a hyperbranched ionic liquid fire retardant containing different anions is obtained, and synergistic flame retardance of HCCP and the ionic liquid is realized. The synthesized hyperbranched ionic liquid based on HCCP can be used as the fire retardant in various polymers.

The preparation process of Ru(II)-polypyridine complex includes the following steps: preparing 1,10-phenanthroline-5,6-diquinone, pyridine [3, 2-a:2', 3'-c] phenazine as ligand I, and 7,8-dimethyl pyridine [3, 2-a: 2', 3'-c] phenazine as ligand II, Ru(bipy)2Cl2.2H2O (bipy=2, 2'-dipyridyl) as precursor I and Ru(phen)2Cl2.2H2O as precursor II; adding certain amount of Ru(bipy)2Cl2.2H2O/Ru(phen)2Cl2.2H2O, ligand I/ligand II, and mixture liquid of methanol and water, heating reflux for certain time, heating to concentrate, adding water and boiling, freezing, adding sodium tetrafluoborate, filtering and separating out precipitate, re-crystallization in alcohol, and stoving under infrared lamp to obtain the Ru(II)-polypyridine complex. The Ru(II)-polypyridine complex is used as nucleic acid recognizing probe for the analysis and detection of nucleic acid, and has high stability, high sensitivity, high selectivity and other advantages.

The invention discloses an electrochemical catalytic synthesis method of aromaticnitrile. Aromatic aldehyde is used as a raw material, HMDS (hexamethyldisilazane) is used as a nitrogen source, a three-electrode system is adopted, a negative electrode and a positive electrode adopt platinum electrodes, and a 0.1mol/l silver nitrate acetonitrile solution is used as a reference electrode; aromatic aldehyde, HMDS, TEMPO (2,2,6,6-tetramethyl-1-piperidine-N-oxyl free radicals) and acetic acid are added to an electrolyte acetonitrile solution with certain concentration, the mixture is stirred for an electrolytic reaction at the temperature of 5-40 DEG C and under the constant voltage of 0.5-8.0 V for 5-30 h, a reaction liquid is subjected to aftertreatment, and a product, namely, aromaticnitrile, is obtained; an electrolyte refers to sodium perchlorate, sodium periodate or sodium tetrafluoroborate. The method is simple and safe to operate and easy to implement.

The invention provides an extreme-pressure anti-wear lubricating agent, and relates to the technical field of high-temperature lubricating agents. The extreme-pressure anti-wear lubricating agent comprises components in weight ratio as follows: 0.1%-3% of a component A, 8%-35% of a component B, 2%-6% of a component C, 0.5%-5% of a component D, 0.5%-4% of a component E, 0.5%-4% of a component F, 0.8%-4% of a component G, 0.2%-1% of a component H and the balance of water, wherein the component A is one of or a mixture of sodium carboxymethylcellulose and xanthan gum; the component B is one of or a mixture of talc powder and bentonite; the component C adopts sodium silicate; the component D adopts one of or a mixture of two or three of sodium fluoborate, borax decahydrate and calcium metaborate; the component E adopts one of zinc stearate and lithium stearate; the component F adopts one of nano fullerene and alkaline sulfonate; the component G adopts sodium polyacrylate; and the component H adopts a water-based defoaming agent. The high-temperature friction coefficient value is very low, the lubricating property is excellent, and the lubricating requirement of current equipment under the high-temperature and high-load conditions can be well met.

The invention relates to a method for preparing metal titanium by electro-deoxidization and specifically relates to the method for preparing the metal titanium by taking ionic liquid as an electrolyte and performing the electro-deoxidization at room temperature. The method comprises the following steps: performing electrolysis at the room temperature by taking the ionic liquid as the electrolyte, taking graphite as an anode and taking a prepared cathode as a cathode, wherein the ionic liquid is prepared by firstly preparing an intermediate of the ionic liquid from N-methylimidazole and halogenated alkane by adopting a light wave-ultrasonic wave synthesis method and further reacting the intermediate of the ionic liquid with sodium tetrafluoroborate for preparation. The method disclosed by the invention has the advantages of convenience in operation, high reaction speed, high efficiency and high yield, as well as high product purity and capability of reducing production period, so that the method is an environment-friendly, green and low-energy-consumption new method for preparing metal titanium by electro-deoxidization.

The invention discloses a one alkyl triphenyl substituted group based phosphonium salt preparation method and application. The preparation method includes that a one alkyl triphenyl phosphonium salt halide I is obtained through reaction of several alkyl halides and triphenylphosphine in a DMF (dimethyl formamide) solvent through nucleophilic substitution, and an aqueous solution of a compound I and a sodium tetrafluoroborate aqueous solution are subjected to ion exchange to prepare the phosphonium salt through high yield of recrystallization. The phosphonium salt preparation method and application has the advantages of low cost and easy obtaining of raw materials and low cost, one alkyl triphenyl substituted group containing phosphonium salt II serving as a phase transfer catalyst has the advantages of high catalytic activity, less required dose, long activity time, high thermal stability and low toxicity, high reaction recovery and the like in catalytic fluorine chlorine exchange reaction, and wide commercial application prospect is achieved.

The invention discloses an electrolyte with a high solvent-sodium salt ratio and a sodium ion battery. The electrolyte comprises sodium salt, a solvent and an additive, wherein the molar ratio of the solvent to the sodium salt is (20: 1)-(70: 1), and the addition amount of the additive accounts for 0.5%-5% of the mass of the electrolyte; the sodium salt comprises one or more of sodium perchlorate (NaClO4), sodium tetrafluoroborate (NaBF4), sodium hexafluorophosphate (NaPF6), sodium hexafluoroarsenate (NaAsF6), sodium trifluoroacetate (CF3COONa), sodium tetraphenylborate (NaB(C6H5)4), sodium trifluoromethanesulfonate (NaSO3CF3), sodium bis (fluorosulfonyl) imide (Na[(FSO2)2N]) or sodium bis (trifluoromethanesulfonyl) imide (Na[(CF3SO2)2N]).

The invention provides a room-temperature zinc slag-free phosphating agent and a production method. The phosphating agent comprises the components including, by weight, 15-25 parts of zinc oxide, 45-65 parts of nitric acid, 15-30 parts of phosphoric acid, 0.1-0.4 part of fluorochemical, 0.1-1.5 parts of an accelerant, 5-10 parts of a complexing agent, 0.1-0.5 part of a surfactant, 0.05-0.12 part of an additive and 70-120 parts of water, wherein the fluorochemical is preferably sodium fluoborite, the accelerant is preferably copper nitrate, the complexing agent is preferably ethylene diamine tetraacetic acid, and the surfactant is preferably a compound of a nonionic surfactant and an ampholytic surfactant. The phosphating agent provided by the invention does not use harmful substances suchas nickel-containing compounds, the product stability is uniform, and a generated phosphating film is uniform and compact.

The invention relates to a high-purity enriched 11B boron trifluoride gas and a preparation method thereof. The preparation method comprises the step of enriching the 11B in a double-tower in-series high-efficiency rectifying tower by a chemical exchange method by using a mass of 11B boron trifluoride methyl ether generated during producing the enriched 11B and taking the part of a byproduct as a raw material. The abundance of the 11B is higher than 95% (at.), and the purity is higher than 99wt%. Therefore, the 11B boron trifluoride methyl ether coordination compound is directly reacted with the sodium fluoride to obtain the 11B sodium fluoborate, so that the technical process is simple, the product purity is high, and the yield of the 11B sodium fluoborate is greatly improved. The 11B sodium fluoborate is directly heated at 600-700DEG C to be thermally decomposed so as to obtain the 11B boron trifluoride gas. The abundance of the prepared boron trifluoride gas 11B is higher than 95% (at.), and the purity is higher than 99.99vol%.

The invention discloses a preparation method of an oil injection pump plunger surface phosphating liquid. The preparation method of the phosphating liquid comprises the steps: (1) taking an appropriate amount of water to blend zinc oxide into a paste; (2) taking an appropriate amount of water again, adding phosphoric acid and nitric acid to obtain a mixed solution, adding the pasty zinc oxide of the step (1), and then putting into a reaction kettle; and (3) successively adding nickel nitrate, ferric nitrate, copper nitrate, sodium citrate, tartaric acid, sodium fluoroborate, sodium chlorate, hydrogen peroxide and sodium carbonate into the reaction kettle by a way of adding the next component after the former component is dissolved, and after all the components are dissolved, adjusting the pH to 2-3.

The invention relates to a preparation method of a graphene conductive paper with controllable conductivity. The preparation method comprises the following steps of: (1) a pretreatment process; (2) an oxidation process; (3) a reduction process: diluting oxidized graphene dispersion liquid by using distilled water, then regulating a pH value by using ammonia, and adding hydrazine hydrate to prepare graphene dispersion liquid; (4) a modifying process: dissolving phenylamine into a solution prepared from concentrated hydrochloric acid and distilled water, dropping a sodium nitrite solution, filtering to obtain filter liquor, adding sodium tetrafluoroborate to the filter liquor, successively flushing obtained diazonium salt by using ice water and cold ether, and mixing the graphene dispersion liquid and the diazonium salt for reaction; (5) a film preparation measuring process: carrying out suction filtration on a reacted mixed solution through a water-phase film, drying to obtain a graphene film, measuring the sheet resistance of the film by using a four-probe system, and converting conductivity. The preparation method disclosed by the invention achieves the purpose of controlling the graphene conductivity by quantificationally destroying the conjugated structure of graphene by utilizing the diazonium salt and has wide application prospect in the fields of electric devices, electrodes, and the like.

A method for synthesizing an N-aryl formamide compound comprises the following steps: putting an N, N-dimethylaniline compound, cuprous chloride, sodium tetrafluoroborate and salicylic acid in an organic solvent in an oxygen atmosphere, reacting for 0.5-48 hours at 30-60 DEG C, and separating and purifying a product to obtain the N-aryl formamide compound, wherein the using amount of the organic solvent is as follows: the amount-of-substance concentration of the N, N-dimethylaniline compound, the cuprous chloride, the sodium tetrafluoroborate and the salicylic acid is 0.5-1mol/L. The method has the advantages as follows: the operation is simple, a used catalyst is cheap, a reaction condition is mild, the product yield is high, the defects of expensive raw material reagents, a harsh condition, cumbersome synthesis steps, not high total yield and the like in the prior art are overcome, and a good application prospect is achieved.

The invention relates to a preparation method of a grafted quaternary phosphonate ionic liquid. The preparation method comprises the following steps of: using 3-(chloropropyl)triethoxysilane and trioctylphosphine to react and generate a chlorinated quaternary phosphonate ionic liquid intermediate, then using the chlorinated ionic liquid intermediate and sodium fluoroborate to synthesize a tetrafluoroborate quaternary phosphonate ionic liquid intermediate, and finally using the tetrafluoroborate ionic liquid intermediate and silica to react and generate the grafted quaternary phosphonate ionic liquid. The grafted quaternary phosphonate ionic liquid provided by the preparation method of the grafted quaternary phosphonate ionic liquid can be used as the CO2 adsorbent alone and can also be used along with other adsorption materials; and compared with the silica gel supported 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid which is synthesized by the traditional immersion method and the silica gel supported 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid which is synthesized by the sol-gel method, the grafted quaternary phosphonate ionic liquid has larger cumulative specific surface area and better CO2 adsorption property.

The invention discloses non-aqueous electrolyte for inhibiting sodium-ion battery swelling as well as a preparation method and application thereof. The non-aqueous electrolyte comprises a sodium salt,an organic solvent and a first functional additive, wherein the molecular formula of the first functional additive is R1R2R3C3H3O3S; the content of the first functional additive in the non-aqueous electrolyte is 0.001-30wt%; the sodium salt refers to one or more of sodium hexafluorophosphate, sodium tetrafluoroborate, sodium hexafluoroarsenate, sodium borate dioxalate, sodium ditrifluoromethyl sulfonamide, sodium trifluoromethanesulfonate, sodium difluorosulfonimide or sodium perchlorate; the organic solvent refers to one or more of cyclic carbonate, chain linear carbonate, carboxylic ester or cyclic lactone.

The invention belongs to the field of deep-processing of biomass energy liquid fuels and discloses an extracting desulfurizing agent, a preparation method thereof and a desulfurizing refining method for biodiesel oil. The extracting desulfurizing agent is liquid state ionic inorganic salt and is synthesized by carrying out a reaction on a precursor A and sodium tetrafluoroborate in a mass ratio of(40-50):(50-70), wherein the precursor A is 1-butyl-3-methylimidazole bromide or 1-propyl-3-methylimidazole bromide. The desulfurizing refining method for biodiesel oil comprises the following steps:adding the extracting desulfurizing agent and an accelerant of the extracting reaction into the biodiesel oil; and leaving the biodiesel oil to stand and layer after the reaction to separate the biodiesel oil. The liquid state ionic organic salt can remove sulfur in the biodiesel oil effectively, and the two phases are extremely easily separated, so that an emulsion phenomenon can be avoided effectively. The sulfur content of the biodiesel oil is reduced by extraction by means of the liquid state ionic organic salt. The sulfur content in the biodiesel oil can be reduced by 90% or above. The extracting desulfurizing agent has the advantages of low energy consumption, low refining consumption and no pollution.

The invention relates to a preparation method of CaF2 hollow nanospheres. F127 is taken as surfactant, calcium nitrate tetrahydrate is taken as calcium source, sodium citrate dihydrate is taken as complexing agent, and sodium tetrafluoroborate is taken as fluorine source, and the CaF2 hollow nanospheres are synthesized by hydrothermal method. The synthesis method is simple, rapid and easy to repeat. The hollow spheres obtained are uniform in shape and size.

The invention belongs to the technical field of wastewater treatment, and particularly relates to a method and device for recovering boron trifluoride in wastewater containing boron trifluoride. The recovery method provided by the invention comprises the following steps: mixing wastewater containing boron trifluoride with strong base to carry out acid-base neutralization reaction to obtain a neutralization reaction product, wherein the boron trifluoride contained in the wastewater is hydrolyzed into fluoboric acid and boric acid; and mixing the neutralization reaction product with fuming sulfuric acid, and carrying out a replacement reaction to obtain boron trifluoride gas. According to the method, by adding the strong base into the boron trifluoride-containing wastewater and carrying out acid-base neutralization reaction on the strong base and fluoboric acid in the wastewater, sodium fluoborate is obtained; and sodium fluoborate, boric acid and fuming sulfuric acid react to obtain the boron trifluoride gas. According to the method, boron trifluoride in the wastewater is recycled by utilizing a simple chemical reaction. The recovery method provided by the invention is simple and easy to implement; the influence of boron trifluoride on the environment and an existing wastewater treatment system is reduced; and the waste of resources is reduced.

The invention relates to a synthesis method of a low-toxicity low-harm environment-friendly solvent green 3, which comprises the following steps: (a) adding N-butylimidazole and acetone into a reaction vessel, slowly dropwise adding bromoethane for reaction, adding sodium tetrafluoroborate for anion exchange, and continuing stirring the reactants to obtain an ionic liquid; (b) adding 1,4-dihydroxyanthraquinone, a 1,4-dihydroxy anthraquinone leuco body and p-toluidine into the ionic liquid, and carrying out condensation reaction to obtain a first mixed solution; and (c) cooling the first mixedsolution, carrying out suction filtration to obtain a filter cake and a filtrate, and carrying out washing post-treatment on the filter cake to obtain the solvent green 3. According to the method, the synthesized ionic liquid is used as a solvent, the condensation reaction is double condensation through model selection of organic cations and anions in the ionic liquid, the product purity is obviously improved to 98% or above, the yield reaches 95% or above, in addition, the ionic liquid can be recycled, the cost is greatly reduced, and the pollutant discharge amount is reduced; the performances of the solvent green 3 dye as shown as follows: the [delta]E is less than 0.5, [delta]C is brilliant, and the pressure value is less than 0.2.

The invention discloses fluorinated gadolinium carbonate as well as a preparation method and application thereof and belongs to rare earth gadolinium materials. The fluorinated gadolinium carbonate is a novel fluorine and carbonate coordinated rare earth gadolinium material, and the structural composition formula of the fluorinated gadolinium carbonate is [GdCO3F] n (1), the maximum magnetic entropy change value of the material is 69.9 J kg <-1 > K <-1 > at 2K and 7T. The preparation method comprises the following steps of: adding hydrated gadolinium carbonate as a raw material into water; adding sodium tetrafluoroborate; fully stirring an obtained mixed solution, and transferring the solution into a hydrothermal kettle for hydrothermal reaction; and performing washing and drying to obtain a target product. A synthesis device of the fluorinated gadolinium carbonate is simple, preparation is convenient and fast, operation is easy, and the fluorinated gadolinium carbonate can be applied to preparation of magnetic refrigeration materials. Rare earth Gd < 3 + > with a high spinning ground state and small magnetic anisotropy is selected as cations, CO3 < 2-> with small molecular weight is selected as a ligand, the mass ratio of the rare earth to the ligand is increased to improve the magnetic density, and meanwhile, a fluorine ligand is doped into the material, so that the magnetic refrigeration effect of the material is greatly improved.

The invention relates to the field of adsorption separation, in particular to a CaF2 nano material with high specific surface area and high thermal stability as well as a preparation method and application thereof. The CaF2 nano material is a multilayer nanosheet flower-shaped CaF2 material synthesized by taking disodium ethylene diamine tetraacetate as a complexing agent, calcium acetate as a calcium source and sodium tetrafluoroborate as a fluorine source and adopting a hydrothermal method. According to the CaF2 nano-material provided by the invention, the pH value and crystallization time of the synthetic liquid are optimized, so that the morphology and size of the CaF2 nano-material are effectively controlled, and the highest thermal stability, the maximum specific surface area and theoptimal water absorption performance of the CaF2 nano-material are obtained. In addition, the CaF2 material prepared by the technical scheme of the invention can be used as a water absorbent to efficiently adsorb trace moisture in HF gas to prepare HF high-purity electronic special gas, and can be recycled after regeneration.

The invention discloses a surface carbonitriding treatment method for a planet shaft for a tractor axle. The surface carbonitriding treatment method comprises the steps of infiltration-assisted pretreatment, carbonitriding treatment and quenching and tempering treatment. The infiltration-assisted pretreatment comprises steps of surface treatment, infiltration-assisted coating liquid preparation, drying and sintering; a carbonitriding agent used in carbonitriding is composed of sodium carbonate, barium carbonate, Mo3N2, sodium tetrafluoroborate, sodium chloride and potassium chloride according to the mass ratio of (30-46): (23-36): (28-33): (1-4): (5-9): (1-3). According to the planet shaft for the tractor axle obtained through the carbonitriding treatment method, the quenching hardness of the surface ranges from 59 HRC to 63 HRC, the quenching hardness of the R/2 position ranges from 48 HRC to 51 HRC, and the quenching hardness of the core ranges from 28 HRC to 30 HRC; the surface of the tempered structure is S(back) 1-2 grade, R/2 is S(back)1-2 grade, and the core part is 2-3 grade; and the fatigue life (under 90% of survival rate) is 60-65 million times.

A cyclic preparation method for producing titanium boride from intermediate feedstock sodium-based titanium-boron-fluorine salt mixture and producing sodium cryolite as byproduct, which comprises the steps: a) boric acid or boric anhydride is added with hydrofluoric acid and then with sodium carbonate solution for concentration and crystallization to generate sodium fluoborate; titanium-iron concentrate is added with hydrofluoric acid and then with sodium carbonate and sodium hydroxide to obtain sodium fluotitanate; B) the sodium fluoborate is mixed with the sodium fluotitanate, and the mixture reacts with aluminum to generate titanium boride and sodium cryolite; C) the sodium cryolite is sucked out and then fed into a rotary reaction kettle together with concentrated sulfuric acid, hydrogen fluoride gas as well as sodium sulfate and sodium aluminum sulfate are generated by reaction in the rotary reaction kettle, and the hydrogen fluoride gas is collected and then dissolved in water to obtain hydrofluoric acid aqueous solution; and D) the obtained hydrofluoric acid aqueous solution is recycled.