The application discloses a near-
infrared film and a preparation method thereof. The near-
infrared film is prepared by the following method: mixing
cadmium bromide,
antimony bromide and propyl
triphenyl phosphonium bromide, wherein the ratio of the sum of the
molar amounts of the
cadmium bromide and the
antimony bromide to the
molar amount of the propyl
triphenyl phosphonium bromide is 1:2.001; the
molar amount of the
antimony bromide is 0.1% to 50% of the molar amount of the
cadmium bromide; then adding a polar
solvent to dissolve and filter to obtain a precursor solution, and finally using the precursor solution to prepare the near-
infrared film. The application introduces the antimony element into the organic-inorganic
hybrid cadmium
halide, combines ligand regulation
engineering and
halogen regulation
engineering, and prepares a novel near-infrared film. The near-infrared film realizes near-infrared
light emission with a peak position of 760 nm for the first time by using the antimony element, the
light emission is not affected by a matrix, the
light emission efficiency is high, the stability is high, the film forming performance of the film is good, the preparation method is simple and easy to implement, and the near-infrared film has low cost and large-scale production potential.