The invention discloses a preparation method of an environment-friendly special modified 
polyester chip for iron 
coating. The preparation method comprises the following steps of adding 
ethylene glycol into a pulping kettle and then sequentially adding 
terephthalic acid, 
isophthalic acid, 1,4-
cyclohexanedimethanol and 
neopentyl glycol into the pulping kettle to prepare 
slurry; adding 
ethylene glycol into a catalyst preparation kettle, then adding a 
titanium catalyst and uniformly stirring to prepare catalyst liquid; adding 
ethylene glycol into an additive preparation kettle, then adding 
silicon dioxide and uniformly stirring to prepare additive liquid; leading the 
slurry and the catalyst liquid into a first esterification kettle, heating to perform the 
esterification reaction, then leading the obtained product into a second esterification kettle, adding 
trimethyl phosphate and the additive liquid and uniformly mixing; leading ester into a condensation 
polymerization kettle to carry out condensation 
polymerization, and vacuumizing to the 
degree of polymerization of 70 to 110 in the reaction process so as to obtain high-molecular 
polymer melt; and preparing the high-molecular 
polymer melt into the 
chip in the cooling process. The 
polyester chip can be widely used for iron canned products such as foods, beverages, drugs, 
chemical products and the like; moreover, the 
polyester chip also can be used for packaging of 
powder or 
emulsion pesticides and the like; 
discharge of an 
organic solvent is greatly reduced; and the environment-friendly special modified polyester chip for iron 
coating can replace foreign products.