The invention discloses a preparation method of a core-shell-surface ternary heterostructure nano material with enhanced thermoelectric catalytic activity, and belongs to the technical field of nano functional materials and preparation thereof. The problems that in an existing
metal /
semiconductor composite material, the interface structure level is single, the carrier migration behavior is difficult to effectively regulate and control under the thermoelectric or photo-thermal-thermoelectric driving condition, and the
precious metal modification stability is insufficient are solved. The technical defects that a traditional
semiconductor material is low in energy utilization efficiency and limited in interface reaction regulation and control capacity under the thermal excitation condition are overcome. The method comprises the following steps: 1, preparing
CZTS nanocrystals; 2, preparation of the Au-coated
CZTS NPs core-shell nano structure material; (3) preparation of the Au-coated
CZTS-Pt heterostructure nano material; and 4, modifying the nano material. The method is used for preparing the core-shell-surface ternary heterostructure nanometer material with the enhanced thermoelectric catalytic activity.