The invention relates to a method for oxidatively degrading
chlorophenol substances by using an EDTA (
ethylene diamine tetraacetic acid)-reinforced
bimetal aluminum-iron
system. Machined
metal iron and
metal aluminum used as raw materials are filled in a reactor. Before treatment, a certain amount of EDTA is previously added into the reactor, and
aeration and stirring are simultaneously carried out after starting introducing water. In the water, the
metal aluminum can easily generate
hydrogen peroxide after
aeration, the EDTA after
aeration can promote the metal iron to activate
molecular oxygen to generate oxydol and can eliminate the
passivation layer on the iron surface to reinforce the leaching of
ferrous ions, the
ferrous ions immediately produce Fenton advanced oxidation reaction immediately after contacting the
hydrogen peroxide, and the generated.OH is subjected to advanced oxidation reaction. Meanwhile, the generated iron and aluminum hydroxides have the capacity for adsorbing and removing pollutants, and thus, are beneficial to further enhancing the quality of
effluent water. The invention has the advantages of low
operating cost and simplified technical process, implements quick
decomposition of the EDTA, and can not bring about combined
pollution of the EDTA. The treatment cost is low. The FeO used by the technique is
machining waste of metal workpieces, the AlO is the most abundant metal element on the
earth crust, and both the FeO and AlO are cheap and accessible and can be used for a long time.