The invention relates to an ultralow-attenuation and large-effective-area single-mode 
fiber comprising a core layer and wrapping 
layers. The ultralow-attenuation and large-effective-area single-mode 
fiber is characterized in that the 
radius r1 of the core layer is 5-8 microns, the 
relative refractive index deltan1 of the core layer is 0-0.20%, and the core layer wraps an internal wrapping layer, a recessed internal wrapping layer and an external wrapping layer from inside to outside in turn. The 
radius r2 of the internal wrapping layer is 8.5-12 microns, and the 
relative refractive index deltan2 is -0.20--0.45%. The 
radius r3 of the recessed internal wrapping layer is 12.5-30 microns, and the 
relative refractive index deltan3 is -0.40--0.65%. The external wrapping layer is a fully fluoridated 
silicon dioxide glass layer, and the relative 
refractive index deltan4 is -0.22--0.53%. The ultralow-attenuation and large-effective-area single-mode 
fiber has the specific 
viscosity matching design: the core layer is not the pure 
silicon core and has the characteristics of co-
doping of 
germanium and 
fluorine, and the 
chlorine doping technology is also performed so that the fiber 
viscosity can be reduced and the structural relaxation of glass can be accelerated; and the core layer 
viscosity matching is optimized by controlling the 
doping concentration, and the viscosity of each part of the fiber and the 
fiber strain are optimized so that ultralow-attenuation performance of the single-mode fiber can be realized.