The invention relates to a heavy size TRIP amorphous composite material and preparation method thereof, the composite material comprises the following alloy components: CuaZrbMcNdXe(atom mol ratio), wherein M is at least one of Al, Be, Ag, Au, Pd, Pt or rare earth element, N is at least one of Ti, Fe, Co, Ni, Cr, V, Zn, Nb, Ta, Mo, Hf, W, WC, SiC, and TiC, X is at least one of Si, C, B, Sn, Ga, Ge and In, wherein a is greater than or equal to 0 and less than or equal to 70, b is greater than or equal to 0 and less than or equal to 70, c is greater than or equal to 2 and less than or equal to 15, c is greater than or equal to 0 and less than or equal to 5, e is greater than or equal to 0.05 and less than or equal to 2, and sum of a, b, c, d and e is 100. According to the invention, amorphous formation capability of a matrix can be increased by alloying and technical adjusting, and a dispersed crystalline state second phase having phase transition induction plasticity effect can be generated in-situ, deformation induction generated during a deformation process of the second phase is used for obtaining large stretching plasticity and strong processing hardening capability. The prepared composite material can realize good combination of intensity and plasticity, and has wide engineering application prospect.