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223 results about "Active surface area" patented technology

Active surface sites only represent a fraction of the total surface area, called active surface area (ASA). Knowledge of the nature and concentration of the active sites is of paramount importance for a better understanding of the kinetics involved in heterogeneous gas-solid reactions [1].

Cobaltosic oxide hierarchical structure nano array materials and preparation method thereof, and application of cobaltosic oxide hierarchical structure nano array materials

The present invention provides cobaltosic oxide hierarchical structure nano array materials and a preparation method thereof, and an application of cobaltosic oxide hierarchical structure nano array materials. In a closed high temperature and high pressure reactor, redistilled water is taken as reaction solvent, cobalt salt, ammonium fluoride and urea are added into the reaction solvent for uniform mixing, and a reaction system is heated to generate a high-pressure environment to prepare cobaltous hydroxide precursor nanowire materials; then redistilled water is taken as reaction solvent, 2-methylimidazole is added into the reaction solvent, the cobaltous hydroxide precursor loaded on carbon cloth is immersed in the solution, the cobaltous hydroxide is taken as a cobalt source, the reaction system is heated and the reaction time is controlled to control a ZIF67 nucleation rate so as to prepare a cobalt-based metal organic framework (ZIF67) array; and finally, calcining decomposition ofthe cobalt-based metal organic framework (ZIF67) array is performed to obtain a cobaltosic oxide hierarchical structure. The product purity is high, the dispersibility is good, the controllability isgood, the production cost is low, the reproducibility is good, the cobaltosic oxide hierarchical structure nano array materials have cycling stability and large active surface area, and have a potential application value at the aspect of supercapacitors.
Owner:ANHUI NORMAL UNIV

Composite nanostructure based on three-dimensional porous transition metal carbide Ti3C2MXene and general preparation method thereof

The invention discloses a composite nanostructure based on a three-dimensional porous transition metal carbide Ti3C2MXene and a general preparation method thereof, and belongs to the field of nanomaterials. The three-dimensional composite structure is composed of a three-dimensional porous Mxene-supported inorganic nanostructure, and has a honeycomb hierarchical porous structure. A precursor of atwo-dimensional transition metal carbide and a metal-organic framework compound is subjected to high-temperature pyrolysis or a chemical reaction in an inert or reactive atmosphere to prepare the composite nanostructure with a controllable size. According to the composite nanostructure, stacking of MXene itself is inhibited, an active surface area, porosity, and ion permeability of MXene are increased, and thereby a surface interface of MXene is efficiently used. At the same time, introduction of the metal-organic framework compound realizes uniform and stable compounding of the three-dimensional porous MXene and an inorganic nanomaterial, the fundamental difficult problem that plagues exerting and application of inorganic nanomaterial performance is solved, and the composite nanostructurehas wide application prospects in the fields such as catalysis, energy, photo-electricity, space technology, and military industry.
Owner:DALIAN UNIV OF TECH
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