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1283 results about "Fiber spinning" patented technology

Liquid crystalline thermosets from ester, ester-imide, and ester-amide oligomers

Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. These properties make the end-capped liquid crystal oligomers highly processable by a variety of melt process shape forming and blending techniques including film extrusion, fiber spinning, reactive injection molding (RIM), resin transfer molding (RTM), resin film injection (RFI), powder molding, pultrusion, injection molding, blow molding, plasma spraying and thermo-forming. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures. The resulting thermosets display many properties that are superior to their non-end-capped high molecular weight analogs.
Owner:NASA

Modified Polylactic Acid Fibers

A method for forming biodegradable fibers is provided. The method includes blending polylactic acid with a polyepoxide modifier to form a thermoplastic composition, extruding the thermoplastic composition through a die, and thereafter passing the extruded composition through a die to form a fiber. Without intending to be limited by theory, it is believed that the polyepoxide modifier reacts with the polylactic acid and results in branching of its polymer backbone, thereby improving its melt strength and stability during fiber spinning without significantly reducing glass transition temperature. The reaction-induced branching can also increase molecular weight, which may lead to improved fiber ductility and the ability to better dissipate energy when subjected to an elongation force. To minimize premature reaction, the polylactic acid and polyepoxide modifier are first blended together at a relatively low temperature(s). Nevertheless, a relatively high shear rate may be employed during blending to induce chain scission of the polylactic acid backbone, thereby making more hydroxyl and/or carboxyl groups available for subsequent reaction with the polyepoxide modifier. Once blended, the temperature(s) employed during extrusion of the blended composition can be selected to both melt the composition and initiate a reaction of the polyepoxide modifier with hydroxyl and/or carboxyl groups of the polylactic acid. Through selective control over this method, the present inventors have discovered that the resulting fibers may exhibit good mechanical properties, both during and after melt spinning.
Owner:KIMBERLY-CLARK WORLDWIDE INC

Orientation electro-spinning nanometer fiber spinning method and device thereof

InactiveCN103132194AHigh degree of axial orientationSuppress spinning instabilityDrafting machinesFilament/thread formingBobbinEngineering
The invention discloses an orientation electro-spinning nanometer fiber spinning method and a device thereof. A metal shower nozzle which exerts positive and negative high pressure is adopted to spin two strands of nanometer fibers with opposite charges, an electric field line of a spinning electric field, relative to a common spinning electric field, is straight, stability of spinning is effectively restrained, and the spinning nanometer fibers are straight. Two strands of the fibers surround the yarn tail and form a cone-shaped twisting trigonum on the upper portion of a metal twisting machine, and enable the nanometer fibers to be further oriented and twisted to form yarn through electric field force, tractive force of the yarn and acting force of the metal twisting force. The spinning nanometer fiber yarn is conducted heat shaping through a heat processing device under certain tensile force, degree of orientation of the nanometer fibers along the axial direction of the yarn, breaking force and yarn levelness are further improved, and the yarn after shaped is collected by a winding bobbin. The device can achieve the aim that orientation nanometer fiber yarn can be continuously prepared, is simple in device, convenient to operate, and good in resultant yarn continuity, yarn breaking strength and yarn levelness, and not only can spin pure nanometer fiber yarn, but also can spin nanometer fibers / filament core composite yarn. The orientation nanometer fiber spinning method and the device thereof have important application value in the fields, such as a biomedical field and a sensor field.
Owner:杨恩龙 +1

Method for producing terylene fibre with pearly lustre

The invention relates to a method for preparing polyester fibers with pearly luster. The method comprises the following steps: (1) pearlescent pigment agglomerate and full-dull PET fiber forming resin slice are blended according to the weight ratio of 5-20 to 80-95; and after drying, the water content is less than 100PPM, and the slice is delivered to a feeding port of an extruder and enters an screw extruder for heat fusing and compression; (2) the temperature is controlled to between 290 and 305 DEG C, fusant extruded out by the rotary screw rod enters a metering pump through a distributing pipe and a static mixer, delivered to a spinning component, filtered by a sea sand layer and pressed into a spinning plate to form fusant current which is cooed to form in a spinning cabinet, and the surface of a filament bundle is covered by a spinning finish; and 3. the spinning speed pre-extension is between 2, 500 and 3, 500m/min, the winding carry rate is between 5 and 15 percent for wind-forming, and the full-dull pearlescent polyester fiber POY is obtained. The manufacturing process is easily realized, and is convenient to improve the pearlescent fiber spinning effect and simultaneously provides the fibers with light extinction performance, and the pearlescent pigment has excellent performance and little feed rate.
Owner:DONGHUA UNIV

Dynamic demonomerization and defoaming method and device for carbon fiber spinning solution

ActiveCN101856570AContinuous quantitative feedingSingle and degassing continuous dynamicFoam dispersion/preventionCarbon fibersSolvent
The invention discloses a dynamic demonomerization and defoaming method and a dynamic demonomerization and defoaming device for carbon fiber spinning solution. An ultrasonic generator is arranged in the centre of a defoaming kettle; an air guide cylinder and a flow guide disk are arranged on a flow diversion and air guide cover; and the defoaming effect is improved to realize low-temperature high-vacuum demonomerization and defoaming of the spinning solution with different relative molecular masses and different charging rates by the processes of heating a demonomerization and defoaming device, continuous feeding, gravity demonomerization and defoaming, film stretch defoaming and ultrasound-assisted defoaming and controlling the defoaming temperature, the vacuum degree and the rotation speed of a demonomerization tower. The spinning solution obtained by the method has the residual monomer content of less than 0.1 percent, less than 5 small bubbles with diameter of less than 0.03mm and solvent loss of less than 5 percent during the demonomerization and defoaming. The method and the device can realize continuous dynamic demonomerization and defoaming at a low temperature under vacuum condition and has the characteristics of simple and practical process and good defoaming effect.
Owner:XIAN KANGBEN MATERIAL

Polyamide and polyester sheath-core functional fiber and manufacturing method

A polyamide and polyester sheath-core functional fiber and manufacturing method are provided. Section of the polyamide and polyester sheath-core functional fiber is an abnormal sheath-core compound structure. Common PET (terylene) polyester forms abnormal sheath-core of fiber and functional PA (polyamide) with negative oxygen ion and far infrared ray forms abnormal sheath layer of fiber. The manufacturing method is as follows: using a complex fiber-spinning machine, using an abnormal central orifice of same plate bi-component sheath-core distributing plate and corresponding an abnormal spinneret orifice of spinneret plate as complex fiber-spinning assembly; material quality proportion of two components sheath and core is 1.5:8.5 to 5:5. Fiber abnormal sheath layer PA uses melt spinning temperature which is 3 to 10 DEG. C higher than conventional spinning temperature so that melt viscosity is reduced, which leads to high compatibility penetrating each other in larger area edge between the PET melt and the PA. It is hard to peel off two components of polyamide and polyester. The filament has larger specific surface and is easy to release negative oxygen ions constantly and effectively above 5500/cu.cm. Far infrared transmissivity is above 0.86. The invention is iron hand in the velvet glove and wearable. The fiber product is multifunctional, high in quality, which satisfies subsequent manufacturing demand greatly and improves quality of final product and is simple in manufacturing process, low in cost with good effects.
Owner:ZHEJIANG SCI-TECH UNIV

Conjugate Electrospinning Devices, Conjugate Nonwoven and Filament Comprising Nanofibers Prepared by Using the Same

Discloses are a conjugate electrospinning devices for preparing fibers (nanofibers) having a nano-level thickness, and nanofibers prepared using the same. The conjugate electrospinning devices comprises: spinning dope main tanks (1); metering pumps (2); a nozzle block (4); nozzles (5) aligned on the nozzle block; a collector (7) for collecting fibers spun from the nozzle block; and a voltage generator (9) for applying a voltage to the nozzle block and the collector (7), wherein [I] nozzles for spinning two or more different kinds of spinning dope are aligned on a nozzle block (4) regularly or in random order in repetitive units at the same ratio or in different ratios, aligned in random order at a predetermined ratio, or aligned thereon in random order at a predetermined ratio, or aligned thereon repetitively; [II] the number of the spinning dope main tanks (1) is two or more; and [III] a spinning dope drop device (3) is arranged between the spinning dope main tanks (1) and the nozzle block (4). Since two or more different kinds of spinning dopes are combined and electrospun, and thus the physical properties (features) of a non-woven fabric and a filament can be easily managed by a simple process. Nanofibers and their non-woven fabrics can be mass produced because the fiber formation effects are maximized.
Owner:KIM EE +1

Liquid crystalline thermosets from ester, ester-imide, and ester-amide oligomers

Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. These properties make the end-capped liquid crystal oligomers highly processable by a variety of melt process shape forming and blending techniques including film extrusion, fiber spinning, reactive injection molding (RIM), resin transfer molding (RTM), resin film injection (RFI), powder molding, pultrusion, injection molding, blow molding, plasma spraying and thermo-forming. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures. The resulting thermosets display many properties that are superior to their non-end-capped high molecular weight analogs.
Owner:NASA
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