Coating compositions comprise a
coating base, a polyoxyalkylene
siloxane additive and a fluorochemical wherein the polyoxyalkylene
siloxane is of Formulae 1A, 1B, 1C, or 2:(R2)3SiO[Si(R2)2O]y[Si(R2)(R1)O]x[Si(R2)2O]zSi(R2)3Formula 1A(R2)3SiO[Si(R2)2O]x[Si(R2)2R1Formula 1BR1(R2)2SiO[Si(R2)2O]x[Si(R2)2O]Si(R2)2R1Formula 1Cwhereineach R2 is independently H,
alkyl, or
aryl;each R1 is a polyoxyalkylene group having the formula 3 as follows:—CnR4pH2n−pQCmR5pH2m−pOZR3Formula 3whereineach R4 and R5 is independently H,
alkyl, or
aryl;Q is CnHR4,
aryl, CH2CH(OR4), CH2(CH2OR4), S, O, SO, SO2, SO2NR4, OC(O), OC(NR4), NHC(X)NH, or OC(X)NH or
triazole;Z is [C2H4O]a and [C3H6O]b in block or
random order;X is O or S;m and n are each independently an integer of 2 to 8;a is an integer of 0 to about 30; b is an integer of 0 to about 20; provided that a+b is from 1 to about 50;each R3 is independently H, acyl, CH3, or a linear or branched
alkyl or aryl group having 1 to about 20 carbon atoms;w is an integer of from 1 to 3;x is an integer of from 1 to about 20;y is an integer of from 0 to about 20; andz is an integer of from 0 to about 10;and the fluorochemical is selected from the group consisting of a perfluoroalkyl ester, fluorinated urethane, fluoroalkyl
phosphate or salt thereof, fluoroalkyl
phosphate ester or salt thereof, a mixture of a fluoroalkyl
phosphate and a glycol ester, and fluoroalkylpolyoxyethylene.