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267results about How to "Good flame retardant performance" patented technology

High-flame-retardant polypropylene material and preparation method thereof

The invention discloses a high-flame-retardant polypropylene material and a preparation method thereof. The material is composed of the following raw materials in parts by mass: 60-75 parts of homo-polypropylene aggregates, 5-15 parts of homo-polypropylene powder, 10-20 parts of a brominated flame retardant, 3-8 parts of an antimony flame retardant, 1-3 parts of a flame retardant synergist, 0-10 parts of a cooling master batch, 0-3 parts of a flexibilizer, 0-1 part of a lubricant, 0-1 part of an ultraviolet light absorber, and 0-1 part of an antioxidant. The preparation method of the material comprises the following steps: 1) uniformly mixing all materials in certain proportion; and 2) adding the obtained mixture into a twin-screw extruder, carrying out high-temperature mixing and shearing, and after the obtained object is subjected to water cooling, sequentially carrying out bracing and grain-sized dicing, so that the high-flame-retardant polypropylene material is obtained. The high-flame-retardant polypropylene material disclosed by the invention is excellent in flame resistance, good in self-extinguishment, excellent in aging resistance, good in insulating property and heat resistance, not easy to deform by heating, excellent in processing fluidity, and easy to shape.
Owner:GUANGDONG JUSHI CHEM CO LTD

N-semi aromatic hydrocarbyl diamine-bisphenol tetrafunctional fluorene-based benzoxazine and preparation method thereof

InactiveCN103936686AGood flame retardant performanceImprove crosslink density and toughnessOrganic chemistryDiamineParaformaldehyde
The invention provides N-semi aromatic hydrocarbyl diamine-bisphenol tetrafunctional fluorene-based benzoxazine and a preparation method thereof. A N-semi aromatic hydrocarbyl diamine-bisphenol tetrafunctional benzoxazine monomer is obtained by the following steps: reacting substituted or unsubstituted salicylaldehyde with 2, 7-diamido-9, 9-bis-(4-hydroxy phenyl) fluorene, using sodium borohydride for reduction to obtain substituted or unsubstituted 2-hydroxy benzylamino bisphenol fluorene, and performing a one step Mannich condensation reaction of the substituted or unsubstituted 2-hydroxy benzylamino bisphenol fluorene and aliphatic amine and paraformaldehyde. The reaction process is simplified, the total product yield is increased; by adjusting of rigid and flexible groups in the aliphatic amine and the substituted or unsubstituted salicylaldehyde compound, the melting point of the benzoxazine monomer is improved, the crosslinking density and toughness of polybenzoxazine are improved, and the problems that fluorene-based benzoxazine with a structure with larger steric hindrance is small in molecular weight, low in crosslinking density, and poor in toughness and thermal performance reduction caused by the introduction of flexible groups can be solved.
Owner:HARBIN ENG UNIV

Flame-retardant coiled material and preparation method thereof

The invention discloses a flame-retardant coiled material and a preparation method thereof. The flame-retardant coiled material is a laminated structure which is formed by bonding a flame-retardant surface layer and a chopped fiber layer by a flame-retardant paint and carrying out curing. The flame-retardant paint is composed of a component A and a component B in a weight ratio of 10:(2-5). The component A comprises the following ingredients in percentage by mass: an epoxy resin, a flame-retardant resin, a flame-retardant diluter, a toughener, a dispersing agent, a defoaming agent, a leveling agent, a flame-retardant additive, a color paste and the balance of inorganic filler. The component B comprises a curing agent and the balance of curing accelerator. The flame-retardant additive comprises at least one of antimony trioxide, aluminum hydroxide, magnesium hydroxide, melamine cyanurate, chlorinated paraffin, tri(2-chloropropyl) phosphate and dimethyl methylphosphate. The epoxy resin, flame-retardant resin, flame-retardant diluter and flame-retardant additive are utilized to form the compound system, thereby fully displaying the synergistic effects of the components, and greatly enhancing the flame retardancy of the flame-retardant paint.
Owner:浙江港流高分子科技股份有限公司

Flame-retardant activated carbon fabric and preparation method thereof

The invention relates to a flame-retardant activated carbon fabric and a preparation method thereof. The flame-retardant activated carbon fabric is characterized in that an activated carbon layer, a water-based adhesive film layer and a hot-melt adhesive powder particle layer are sequentially covered on a base material which is subjected to flame-retardant treatment. The preparation method comprises the following steps of: spraying or padding the base material with an environment-friendly water-based flame retardant and drying; serially coating a prepared activated carbon paste and a water-based flame-retardant hot-melt adhesive powder particle paste on the base material, and drying to obtain the final product of flame-retardant activated carbon fabric. During the drying process, the water-based adhesive film layer is formed between the carbon layer and the hot-melt adhesive powder particle layer. The preparation method of the flame-retardant activated carbon fabric is simple and environment-friendly, and the product has good flame retardant property. Owing to the good adsorption property of activated carbon, the fabric can remove formaldehyde, benzene, TVOC and other harmful gases in the air. When the fabric is used, the fabric can be cut freely and laminated thermally. The flame-retardant activated carbon fabric is easy and convenient to use and has a wide application range.
Owner:WUXI DINGHAO NEW MATERIAL SCI RES

Low smoke zero halogen flame-retardant mould shrinkage sleeve and preparation method as well as application thereof

The invention discloses a low smoke zero halogen flame-retardant mould shrinkage sleeve and a preparation method as well as application thereof. The low smoke zero halogen flame-retardant mould shrinkage sleeve comprises the following raw materials in parts by weight: 85-100 parts of polyolefine resin, 8-15 parts of maleic anhydride functional group-grafted ethylene-vinyl acetate copolymer, 3-20 parts of red phosphorus powder, 4-30 parts of expandable graphite, 10-90 parts of magnesium hydroxide, 0.5-2.5 parts of antioxidant, 1-3 parts of lubricant, 1-2.5 parts of cross-linking auxiliary agent and 5-8 parts of black master batch. The preparation method comprises the following steps of: uniformly mixing the raw materials; extruding by using a double-screw extruder at the temperature of 100-160 DEG C; performing wire drawing, air cooling and granulation; injecting the granular material formed by granulation into the mould shrinkage sleeve; performing irradiation at the dosage of 8-12Mrad; and then extending and drawing the mould shrinkage sleeve, which is subjected to irradiation cross-linking, at the temperature of 140-160 DEG C and cooling and forming to obtain the low smoke zero halogen flame-retardant mould shrinkage sleeve. The preparation method is simple; an obtained product has superior flame retardant performance and low smoke formation; meanwhile, superior mechanical property, electrical insulation performance and thermal resistance performance are kept.
Owner:广州凯恒科塑有限公司

High-temperature-resistant high-moisture-resistant halogen-free flame-retardant polyester type polyurethane thermoplastic elastomer composition

ActiveCN102120875AImprove high temperature and high humidity precipitation performanceGood flame retardant performanceInsulated cablesInsulated conductorsHalogenChemistry
The invention relates to a high-temperature-resistant high-moisture-resistant halogen-free flame-retardant polyester type polyurethane thermoplastic elastomer composition. The invention aims to solve the technical problem of precipitation of the halogen-free flame-retardant polyester type polyurethane elastomer in a high-temperature high-moisture environment, maintain the softness and mechanical strength of the elastomer and conform to the RoHS instruction, thereby satisfying the requirements for high-performance electronic/electric appliance materials and the development characteristics of no halogen and flame retardancy. The invention is characterized in that the high-temperature-resistant high-moisture-resistant halogen-free flame-retardant polyester type polyurethane thermoplastic elastomer composition is prepared from the following components in percentage by weight: 5.0-40.0% of organic phosphonate flame retardant, 0.0-15.0% of nitrogen-containing compound, 1.0-15.0% of viscosity modifier, 0.1-1.5% of antioxidant and ultraviolet absorbent, and the balance of polyether type polyurethane thermoplastic elastomer. The components are premixed, extruded and granulated to obtain the product.
Owner:HANGZHOU JLS FLAME RETARDANTS CHEM

Halogen-free flame retardant polylactic acid toughening modification composite material and preparing method thereof

InactiveCN105694405AGood flame retardant performanceExcellent toughness and elongation at breakBiodegradable plasticAntioxidant
The invention discloses a halogen-free flame retardant polylactic acid toughening modification composite material.The composite material is mainly composed of 50.0-80 wt% of polylactic acid, 5.0-20.0 wt% of biodegradable plastic, 10.0-20.0 wt% of phosphorus based flame retardant, 0.5-20.0 wt% of reactive compatibilizer and 0.2-1.0 wt% of antioxidant.Hypophosphite and phosphonate with different ratios are taken as the flame retardant to achieve flame retarding of polylactic acid, polylactic acid is toughened through a bio-based elastomer, a reactive polymer is added to serve as the reactive compatibilizer, and the halogen-free flame retardant biodegradable polylactic acid toughening modification composite material is prepared through melting reaction and blending.The composite material has excellent flame retarding property, elongation at break and toughness.The biodegradable halogen-free flame retardant polylactic acid toughening modification composite material is efficient and low in toxicity and is an environment-friendly biodegradable flame retardant plastic.The composite material has excellent flame retarding property and mechanical property and can be used in the fields such as packaging, film, textile and automobiles.
Owner:QINGDAO UNIV OF SCI & TECH

High-molecular flame-retardant foam material and preparation method thereof

The invention provides a high-molecular flame-retardant foam material which is prepared by mixing the following components in parts by weight: 83.5 to 97.5 parts of polymer resin, 1.8 to 8.8 parts of flame retardant, 0.4 to 4.2 parts of surface active agent and 2 to 15 parts of polystyrene foam particles. The preparation method of the high-molecular flame-retardant foaming heat insulating material comprises the following steps: the polymer resin, the flame retardant and the surface active agent are mixed uniformly to prepare a high-molecular organic flame-retardant adhesive, then after being mixed, the high-molecular organic flame-retardant adhesive and a curing agent are added into the polystyrene foam particles, and the high-molecular flame-retardant foaming heat insulating material can be formed quickly through hot pressing. The high-molecular flame-retardant foam material provided by the invention synthesizes the characteristic of low heat conductivity coefficient of the foam particles and efficient flame-retardant effect of the high-molecular organic flame-retardant adhesive, really achives integration of flame retardance and heat preservation, and uses various flame-retardant compounds for mixing to form the flame retardant, and the prepared high-molecular flame-retardant foaming heat insulating material is better in flame retardant property, better in thermal insulation effect, and higher in oxygen indexes.
Owner:南通南京大学材料工程技术研究院

Spray finishing polyurethane rigid foam raw material and foam produced thereof

The invention relates to a sprayed rigid polyurethane foam raw material and foam produced therefrom. The sprayed rigid polyurethane insulation foam raw material comprises an isocyanate component and a polyol component, and can be used in various insulating fields. The sprayed rigid polyurethane foam raw material comprises component A and component B, the volume ratio of the component A to the Component B ranges from 1:1 to 1.5:1; the component A is of isocyanate and the component B is of polylol and various additives, and the optional additives comprise a catalyst, a foam stabilizer, a flame retardant and a foaming agent. The sprayed rigid polyurethane foam raw material is characterized in that the foaming agent comprises a chemical foaming agent and a physical foaming agent, the chemical foaming agent is of water, and the physical foaming agent comprises a main foaming agent accounting for 0.1%-30% of the component B and other physical foaming agents based on mass percentage. Products constructed with the foam raw material have good adhesive force and flame retardance, low thermal conductivity and good dimensional stability. The raw material can be conveniently used for rigid polyurethane foam construction in the insulation fields including external wall insulation of buildings.
Owner:万华化学(佛山)容威聚氨酯有限公司 +2

Trine expansion type flame retardant and synthetic method thereof

ActiveCN107118347AGood char formation and thermal stabilityGood flame retardant performanceSolventDiamine
The invention relates to a trine expansion type flame retardant and a synthetic method thereof. The synthetic method is characterized by comprising the following steps: adding a solvent into a container, adding cyanuric chloride and 1-oxyphospha-4-hydroxymethyl-2,6,7-trioxabicyclo[2.2.2] octane into the container, cooling to 0-45 DEG C in water bath or oil bath and stirring and dispersing, dropwise adding an acid-binding agent to react step by step, thereby obtaining unary substitute; adding matters containing aliphatic diamine or aliphatic dihydric alcohol and a mixture of the solvent and the acid-binding agent into another container, cooling to -10 to 10 DEG C in ice bath or a freezing reactor, slowly dropwise adding a phosphorus-containing compound to react, thereby obtaining phosphorus-containing intermediate; adding the obtained unary substitute (CNC-PEPA) and the obtained phosphorus-containing intermediate into a reaction container with the solvent, dropwise adding the acid-binding agent, heating to 80-130 DEG C to react, cooling, washing and drying to obtain powder solid, namely the trine expansion type flame retardant. The trine expansion type flame retardant has the advantages of being great in molecular weight, relatively moderate in proportion of an acid source, a carbon source and a gas source in a molecular structure, relatively high in char forming content, relatively good in thermal stability and the like.
Owner:蕉岭金鹏精细化工有限公司

Double-coated microencapsulation expansion flame retardant natural rubber and preparation method thereof

The invention discloses double-coated microencapsulation expansion flame retardant natural rubber and a preparation method thereof and relates to rubber and a preparation method thereof. The method comprises the following steps of: sequentially mixing a rubber matrix, stearic acid, zinc oxide, an accelerant, an anti-aging agent, carbon black, paraffin, double-coated microencapsulation ammonium polyphosphate/mesoporous molecular sieve MCM-41, pentaerythritol, ammonium polyphosphate and sulfur in an open mill, and performing microencapsulation on the ammonium polyphosphate and mesoporous molecular sieve MCM-41 by employing melamine resin-zinc borate double coating, so that the thermal stability of the rubber matrix is improved. The coating defect of the melamine resin layer can be filled through the outer zinc borate layer, so that the microencapsulation coating is complete. The outer zinc borate layer is a flame retardant and an inorganic matter, and the flame retardant property and the mechanical property are effectively improved. In addition, the mesoporous molecular sieve MCM-41 has the special catalysis and adsorption functions and is synergistic with the expansion type flame retardant, so that the flame retardant property and carbon layer stability of the composite material are further improved.
Owner:SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
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