The invention relates to a trine expansion type
flame retardant and a synthetic method thereof. The synthetic method is characterized by comprising the following steps: adding a
solvent into a container, adding
cyanuric chloride and 1-oxyphospha-4-
hydroxymethyl-2,6,7-trioxabicyclo[2.2.2]
octane into the container, cooling to 0-45 DEG C in water bath or
oil bath and stirring and dispersing, dropwise adding an acid-binding agent to react step by step, thereby obtaining unary substitute; adding matters containing aliphatic
diamine or aliphatic dihydric
alcohol and a mixture of the
solvent and the acid-binding agent into another container, cooling to -10 to 10 DEG C in ice bath or a freezing reactor, slowly dropwise adding a
phosphorus-containing compound to react, thereby obtaining
phosphorus-containing intermediate; adding the obtained unary substitute (CNC-PEPA) and the obtained
phosphorus-containing intermediate into a reaction container with the
solvent, dropwise adding the acid-binding agent, heating to 80-130 DEG C to react, cooling, washing and
drying to obtain
powder solid, namely the trine expansion type
flame retardant. The trine expansion type
flame retardant has the advantages of being great in molecular weight, relatively moderate in proportion of an acid source, a
carbon source and a gas source in a molecular structure, relatively high in
char forming content, relatively good in
thermal stability and the like.