Expanded carbon flame-proof polypropelene composition and preparation method thereof

A technology for flame-retardant polypropylene and its composition, which is applied in the field of intumescent charcoal flame-retardant polypropylene composition and its preparation. The production method is simple and reliable, the mechanical properties remain unchanged, and the flame retardant performance is excellent.

A technology for flame-retardant polypropylene and its composition, which is applied in the field of intumescent charcoal flame-retardant polypropylene composition and its preparation. The production method is simple and reliable, the mechanical properties remain unchanged, and the flame retardant performance is excellent.

CN101293984AActive Publication Date: 2008-10-29CHINA PETROLEUM & CHEM CORP +1

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  • Expanded carbon flame-proof polypropelene composition and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1~4

[0027] Polypropylene (4# powder, Zhonglan Tianjin Chemical Plant), compatibilizer maleic anhydride grafted polypropylene (g-PP, American EXXON company), ammonium polyphosphate (APP, Zhenjiang Star Flame Retardant Material Factory), Pentaerythritol (PER, Jilin Changsong Chemical Plant), melamine cyanurate (MCA, Zhonglan Chenguang Chemical Research Institute), montmorillonite (NanocorI.44P, American Naco Corporation), zinc oxide (ZnO, commercially available), Antioxidant B225 (Swiss Ciba Company), silane coupling agent (KH-550, Nanjing Shuguang Chemical Factory), put into a low-speed mixer and stir evenly, so that all components are fully mixed evenly. Then the above mixed material was extruded and granulated in a twin-screw extruder (TE-30, Nanjing Ruiya Company) at 180-200°C. The extruded pellets were dried in a constant temperature oven at 80°C for 6 hours, and then injected into standard specimens at a temperature of 190-210°C for various mechanical property tests. The spec...

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Abstract

The invention relates to an expansive char-forming flame-retardant polypropylene composition and a production method thereof. The composition comprises the following components: 100 weight parts of polypropylene, 10-30 weight parts of ammonium polyphosphate, 2.8-8.3 weight parts of pentaerythritol, 2.8-8.3 weight parts of melamine cyanurate and 0.5-5 weight parts of montmorillonite. The total additional amount of ammonium polyphosphate, pentaerythritol and melamine cyanurate is at least 31 weight parts. The production method comprises the following steps: proportioning all components (including polypropylene, ammonium polyphosphate, pentaerythritol, melamine cyanurate and montmorillonite) at the given ratios, melting, mixing, extruding and granulating. The composition has better flame retardation, good processability and mechanical property. The production method is simple and reliable.

Description

technical field [0001] The present invention relates to a modified polypropylene, and furthermore, relates to an expanded charcoal flame-retardant polypropylene composition and a preparation method thereof. Background technique [0002] Polypropylene is a general-purpose plastic with excellent comprehensive properties, but it is a flammable material with a low oxygen index, a high heat release rate during combustion, a high calorific value, a fast flame propagation speed, and is not easy to extinguish, which limits the application of polypropylene. [0003] In the past, the flame-retardant polypropylene was mostly halogen-based flame-retardant, and the addition amount was large, which was not only very harmful to the environment, but also had a negative impact on the mechanical and processing properties of the material. [0004] Intumescent flame retardant polymer is a new flame retardant technology developed on the basis of flame retardant coatings. It blends intumescent f...

Claims

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Application Information

Patent Timeline
29 Oct 2008
Publication
CN101293984A
IPC
C08L23/12; C08K5/3492; C08K3/32; C08K5/053; C08K3/34
Inventors
金滟; 蔡涛