The invention discloses a fuel cell electrode gas diffusion layer carbon fiber paper manufactured with pulp and a preparation method thereof. The preparation method mainly comprises the steps of making the pulp, mixing the pulp, manufacturing the paper in a combined manner of downstream net papermaking and guniting net papermaking, drying, hot pressing and the like. The mechanical property of theprepared carbon fiber paper is improved by adding the bonding fibers, and the carbon nanotubes, graphene and the activated carbon are added when the pulp is mixed. The prepared carbon fiber paper comprises a base paper bottom layer made by downstream net papermaking and a base paper surface layer made by guniting net papermaking, and the graphene, the carbon nanotubes and the activated carbon arecontained in the base paper surface layer. The carbon fiber paper prepared by the invention has a porous structure, the excellent gas-forming property, low resistance and high conductivity, and can provide gas, electron and drainage channels for electrode reaction, has the certain mechanical strength, chemical stability, thermal stability, thermal conductivity, gas dispersion and homogenization characteristics, has a large specific surface area, can adsorb the harmful gas, buffers the system reaction, and avoids the instability after high-temperature treatment.