The application discloses a
solar cell and a preparation method, an
assembly and a
system thereof. The
solar cell comprises a
silicon substrate, a doped layer and a
passivation layer which are sequentially arranged on the
silicon substrate, the
passivation layer is provided with an
electrode groove which locally exposes the doped layer, and the
electrode groove is provided with a back
electrode. The back electrode comprises a seed
metal silicide layer, a seed
metal oxide thin layer, a mixed conductive layer and an outer
metal layer which are sequentially arranged on the doped layer. The seed
metal silicide layer is one or more of a
molybdenum silicide layer, a
nickel silicide layer and a
titanium silicide layer, the seed metal
oxide thin layer is one or more of a
molybdenum oxide thin layer, a
nickel oxide thin layer and a
titanium oxide thin layer, the thickness of the seed metal oxide thin layer is not more than 20 nm, and the mixed conductive layer is formed by mutual
diffusion of the seed metal oxide and a seed metal-outer
metal alloy body. The
solar cell has a new electrode structure, can promote improvement of the electrode structure and performance, reduce the cost, has excellent current
transmission performance and small metal composite loss.