A fire resistant glazing assembly with various additional functions in impact safety, solar control, bullet and blast resistance, burglary and forced entry resistance, natural disaster protection, decoration and aesthetics, privacy protection, sound insulation and signal defense security. The fire resistant glazing assembly comprises: (a) two or more glass sheets that are parallel and spaced-apart from each other, the distance between any two adjacent glass sheets is from 1 mm to 40 mm; (b) one plastic film that is adhered onto one of opposite surfaces of the glass sheets or more plastic films that are respectively adhered onto more opposite surfaces of the glass sheets; (c) one or more intumescent interlayers that are between the glass sheets and bond with the glass sheet or the plastic film adhered onto the glass sheet. The fire resistant glazing assembly achieves various additional functions by means of different plastic films existing inside the glazing assembly. The adopted plastic film is compatible with fire resistant glazing assembly and has at least one specific function in safety and security, solar control, decoration and aesthetics, privacy protection, sound insulation and signal defense security.