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75 results about "Hexafluorotitanic acid" patented technology

Hexafluorotitanic acid (systematically named oxonium hexafluoridotitanate(2-)) is an inorganic compound with the chemical formula (H₃O)₂[TiF₆]. As with most oxonium salts, it is not stable when undissolved, or under neutral to basic conditions, tending to decompose in those conditions to titanium fluorides or oxyfluorides. Under highly acidic conditions, it decomposes to titania, which accelerated by fluoride scavengers. Under highly basic conditions, it is hydrolysed to titanium hydroxide. A related salt, is the anhydrous fluoronium hexafluoridotitanate(2-) or (H₂F)₂[TiF₆].

Rare-earth modified Ti-Zr chemical passivation solution for surface treatment of aluminium profiles and using method of rare-earth modified Ti-Zr chemical passivation solution

The invention discloses a rare-earth modified Ti-Zr chemical passivation solution for surface treatment of aluminium profiles and a using method of the rare-earth modified Ti-Zr chemical passivation solution. The rare-earth modified Ti-Zr chemical passivation solution is characterized in that the passivation solution is a main salt for auxiliary film-formation, which takes rare-earth compounds as a Ti-Zr passivation treatment solution, and a passivation film is light yellow in appearance and has field judgement property on the quality of a formed film. A formula of the rare-earth modified Ti-Zr chemical passivation solution is as follows: each litre of solution contains 0.5g.L<-1>-10g.L<-1> of potassium fluotitanate (hexafluorotitanic acid), 0.5g.L<-1>-10g.L<-1> of potassium fluozirconate (fluozirconic acid), 0.5g.L<-1>-5g.L<-1> of cerium nitrate (ceric sulfate and ammonium ceric nitrate), 2g.L<-1>-10g.L<-1> of potassium nitrate, 0.5g.L<-1>-3g.L<-1> of sodium fluoride (potassium fluoride), 0.5g.L<-1>-1g.L<-1> of sodium dodecyl benzene sulfonate or OP-10, 0.2mL-5mL.L<-1> of nitric acid and 1g.L<-1>-5g.L<-1> of boric acid. The using method of the rare-earth modified Ti-Zr chemical passivation solution comprises the following steps of: (1) clearing dirt, such as dirt attached to an aluminium alloy; (2) pretreating the surface of the aluminium alloy; (3) carrying out passivating treatment on the surface of the aluminium alloy by using the rare-earth modified Ti-Zr chemical passivation solution; and (4) washing the aluminium alloy by using water and drying the aluminium alloy. The rare-earth modified Ti-Zr chemical passivation solution disclosed by the invention has the advantages of light yellow appearance, high film formation speed, simple process, uniformity in film layer, strong corrosion resistance, low environment pollution and the like.
Owner:GUANGDONG XINGFA ALUMINUM

Chromium-free passivation solution and hot-dip galvanized metal material

The invention relates to a chromium-free passivation solution and a hot-dip galvanized metal material. The chromium-free passivation solution is prepared from a raw material mixture through uniform mixing. The raw material mixture contains one or more silane coupling agents and water. The chromium-free passivation solution is characterized in that the raw material mixture also contains one or more titanium compounds, one or more inorganic silicon compounds, one or more water-soluble film-forming agents and tannic acid or phytic acid, wherein the one or more titanium compounds are selected from hexafluorotitanic acid, ammonium hexafluorotitanate, potassium hexafluorotitanate, metatitanic acid and titanyl sulfate and the one or more inorganic silicon compounds are selected from nanoscale silica powder, silica sol and sodium silicate. The chromium-free passivation solution has good corrosion resistance, good water resistance, good heat resistance, good fingerprint resistance and excellent roller coating performances. A passivation method adopting the chromium-free passivation solution can greatly shorten treatment time, can be utilized for passivation plate production in a spray mode or a roller coating mode, and also can avoid an oiling process in galvanized plate production.
Owner:PANGANG GROUP VANADIUM TITANIUM & RESOURCES +3

Production process for cogeneration of polymerization ferric chloride water purification agent by using potassium fluotitanate

ActiveCN102951688ALow volume of mother liquorReduce mother liquor lossIron halidesWater/sewage treatment by flocculation/precipitationPotassiumCogeneration
The invention discloses a production process for cogeneration of polymerization ferric chloride water purification agent by using potassium fluotitanate. The production process comprises the following steps: adding hydrofluoric acid and potassium chloride in a leaching tank; opening the leaching tank to stir; adding a theoretical amount of titanium ore; heating to 90-105 DEG C and leaching; sealing to react to obtain hexafluorotitanic acid iron slurry; settling the leached slurry to obtain a hexafluorotitanic acid iron clear liquid for later use; dissolving the potassium chloride by using a hexafluorotitanic acid potassium mother liquid; filtering to obtain a clear liquid for later use; adding metered potassium chloride liquid into a certain amount of hexafluorotitanic acid iron clear liquid while stirring; continually reacting and crystallizing to obtain the hexafluorotitanic acid potassium; carrying out solid-liquid separation on the hexafluorotitanic acid potassium slurry; washing the hexafluorotitanic acid potassium, wherein a part of wastewater enter the potassium chloride for dissolving and recycling; and the other part of wastewater enter an impurity-removing reaction tank; adding metered fine lime in the impurity-removing reaction tank; filter pressing and adding quantified oxidizing agent and stabilizing agent; and standing to obtain polymerization ferric chloride. With the adoption of the production process, the hexafluorotitanic acid potassium mother liquid is recycled, the concentration of the hexafluorotitanic acid potassium mother liquid is improved, and the impurities in the hexafluorotitanic acid potassium mother liquid are removed; and the ferric element is oxidized, alkalified, aged and polymerized to obtain the polymerization ferric chloride.
Owner:福建省漳平市九鼎氟化工有限公司

High-corrosion-resistance marine aluminum alloy surface metal-organic skeleton film treatment liquid and using method thereof

The invention relates to the technical field of metal surface treatment, in particular to a high-corrosion-resistance marine aluminum alloy surface metal-organic skeleton film treatment liquid and a using method thereof. The treatment liquid is prepared from the following components of 25-1600 ppm of hexafluorozirconic acid with the concentration being 45%, 12.5-1000 ppm of hexafluorotitanic acidwith the concentration being 50%, 5-120 ppm of manganese difluoride, 25-600 ppm of glucose, 5-40 ppm of sodium sulfate with the concentration being 50%, and the balance water. The aluminum alloy surface is coated with the treatment liquid to form a metal-organic skeleton film. According to the metal-organic skeleton film treatment liquid, metal ions are provided through the hexafluorozirconic acidand the hexafluorotitanic acid, organic unsaturated bonds are provided through the glucose and combined with the metal ions to form a skeleton, adhesion precipitation of aluminum oxides is facilitated, film forming is easy, the corrosion resistance and the adhesion of the skeleton film are improved advantageously, meanwhile, chromium-free raw materials are adopted, and the environmental protection and pollution-free effects are achieved.
Owner:广东省珠海市质量计量监督检测所

Aluminum alloy natural color chromate-free passivation treatment agent and preparation method thereof

The invention discloses an aluminum alloy natural color chromate-free passivation treatment agent. The aluminum alloy natural color chromate-free passivation treatment agent is prepared from, by weight percentage, 5-10% of potassium persulfate, 1-5% of sorbitol, 0.5-1.5% of ammonium metavanadate, 0.1-0.5% of sodium diisobutyl naphthyl sulfonate, 0.1-0.5% of potassium zirconium carbonate, 0.05-0.08% of polyoxyethylene 10 lauryl ether, 0.01-0.05% of sodium pyrrolidone carboxylate, 0.05-0.1% of cerium salt, 3-10% of inorganic acid, 0.5-2% of organic acid and the balance water. The cerium salt isone or a mixture of cerium oxalate, cerium zincate, cerium formate and cerium acetate. The inorganic acid is one of hexafluorozirconic acid and hexafluorotitanic acid or a mixture of both. The organicacid is one of formic acid, acetic acid and oxalic acid. According to the chromate-free passivation treatment agent, a chromate-free passivation film formed on the surface of aluminum alloy is colorless and transparent, and the natural color of the aluminum alloy is not changed; and after treatment is conducted through the aluminum alloy natural color chromate-free passivation treatment agent, the corrosion resistance of the aluminum alloy is greatly improved, and the treatment agent can be applied to occasions without surface coating.
Owner:LINYI JINHU COLOR COATING ALUMINUM IND

Environment-friendly emission reduction washing-free type metal surface treatment agent

The invention discloses an environment-friendly emission reduction washing-free type metal surface treatment agent. The environment-friendly emission reduction washing-free type metal surface treatment agent comprises zirconium/titanium compounds, rare earth metal compounds, silane, alcohol amine, resin and the like. The zirconium/titanium compounds are mixed compounds with one or a plurality of types of hexafluorozirconic acid, hexafluorotitanic acid, potassium fluozirconate, sodium fluozirconate, ammonium fluozirconate, potassium fluotitanate, sodium fluotitanate, ammonium fluorotitanate, organic zirconium and organic titanium compounds and derived structure compounds of the mixed compounds, the rare earth metal compounds are compounds with one or a plurality of types of rare earth chloride, rare earth nitrate, rare earth hydrate, rare earth carbonate, rare earth acetate and rare earth sulfate, the rare earth chloride, the rare earth nitrate, the rare earth hydrate, the rare earth carbonate, the rare earth acetate and the rare earth sulfate contain one or a plurality of types of rare earth elements including cerium, lanthanum and neodymium, and the silane is a mixture of organicsilane coupling agents and one or a plurality of types of derivatives, hydrolysate and premixes of the organic silane coupling agents. The environment-friendly emission reduction washing-free type metal surface treatment agent has the advantages that the environment-friendly emission reduction washing-free type metal surface treatment agent which is a washing-free environment-friendly metal surface pretreatment agent does not contain phosphorus, is free of heavy metal, little in wastewater discharge, excellent in corrosion resistance and low in cost and is environmentally friendly.
Owner:上海优梓新材料科技有限公司

Preparation method and application of {001} crystal face exposed porous titanium dioxide nanosheet

The invention discloses a preparation method and application of a {001} crystal face exposed porous titanium dioxide nanosheet, and belongs to a preparation method and application of a semiconductor photocatalytic material. The invention specifically relates to a method for preparing a {001} crystal face exposed porous titanium dioxide nanosheet in a cyclohexanol-hexafluorotitanic acid-tetrabutyltitanate reaction system, and application of the {001} crystal face exposed porous titanium dioxide nanosheet as a semiconductor material in the aspect of hydrogen evolution reaction of photocatalyticdecomposition of water. The method comprises the following steps: dissolving hexafluorotitanic acid and tetrabutyl titanate in cyclohexanol; adding the obtained solution into a closed homogeneous reaction container for reaction; and after the reaction is finished, quickly cooling the reaction product, and separating, washing and drying the reaction product to obtain a target product. The method is simple and convenient in process and good in repeatability, and the obtained product is high in purity, good in dispersity and uniform and controllable in size distribution, has a nano-porous structure and a high {001} crystal face exposure ratio, and is expected to be produced on a large scale. The titanium dioxide nanosheet is used as a photocatalytic material and has excellent hydrolysis hydrogen evolution performance, so that the titanium dioxide nanosheet has good economic benefits and a relatively wide market prospect.
Owner:CHINA UNIV OF MINING & TECH

Chromium-free passivating pretreatment method for mirror aluminum board

The invention relates to a chromium-free passivating pretreatment method for a mirror aluminum board. The pretreatment method comprises the following steps: degreasing, washing with water, surface conditioning, washing with water, chromium-free passivating, and pure water washing, wherein a degreasing solution comprises the following components: 1-4wt% of potassium hydroxide, 0.5-1.6wt% of potassium metasilicate, 0.3-1.2wt% of potassium tetraborate, 0.5-2wt% of alkoxy ether fatty alcohol and 0.1-0.8wt% of compound corrosion inhibitor; a surface conditioning solution comprises the following components: 1-4% of phosphoric acid and 0.15-0.3wt% of hydrofluoric acid; a chromium-free passivating solution comprises the following components: 0.2-0.6wt% of hexafluorozirconic acid, 0.05-0.2wt% of hexafluorotitanic acid, 0.5-1.6wt% of magnesium nitrate, 0.03-0.07wt% of hydrofluoric acid, 0.02-0.05wt% of sodium sulfate, 0.1-0.3% of 3-amino propyl ethoxy silane and 0.006-0.01wt% of lanthanum rare earth compound. When the mirror aluminum board is processed by using the chromium-free passivating pretreatment method disclosed by the invention, the mirror surface does not lose light, the passivating film is colorless and transparent, and a hexavalent chromium passivation method for the mirror aluminum board at present can be replaced.
Owner:SHANGHAI REAL INDAL

Method for effectively degrading algal toxin in water

The invention relates to a method for effectively degrading algal toxin in water. The method comprises the following processing steps: (1) adding MC(Microcystin)-LR into an alcohol-water mixed solvent, oscillating to enable the MC-LR to be completely dissolved, adding ammonium hexafluorotitanate, boric acid and ammonium hexafluorosilicate, reacting for 15-25 hours at the constant temperature of 35 DEG C, immersing a quartz fiber filter band into substances generated through the reaction, taking out and airing the quartz fiber filter band, calcining the quartz fiber filter band at the temperature of 400 DEG C for 2-2.5 hours with the temperature increasing rate of 10 DEG C/min, cooling, and taking out the quartz fiber filter band, so as to obtain the quartz fiber filter band loaded with titanium dioxide porous micro-spheres with the molecular imprinting function; (2) sewing the prepared quartz fiber filter band loaded with the titanium dioxide porous micro-spheres with the molecular imprinting function into a filter sleeve capable of sleeving an ultraviolet lamp tube according to the profile of the ultraviolet lamp tube; (3) inserting the ultraviolet lamp tube capable of being immersed into water into the filter sleeve, and then, placing the filter sleeve into a photoreaction container filled with microcystin polluted water. Through the adoption of the method, the efficiency for degrading algal toxin in water is relatively high.
Owner:张易祥
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