The invention discloses a method for
resource utilization of clay
vanadium-containing shale, and belongs to the field of
solid waste
resource utilization. Aiming at the situation that the clay
vanadium-containing shale cannot be effectively utilized due to the fact that the
vanadium grade is low and cannot meet the development and utilization requirements, so that resources are wasted, the vanadium grade in the clay vanadium-containing shale is improved through pre-enrichment, and the method mainly comprises the following process steps: (1) grading without
grinding after crushing: crushing the clay vanadium-containing shale to be-(2-4 mm), and crushing the clay vanadium-containing shale to be-(2-4 mm);
grinding is not needed, wet screening and grading are carried out with 25-45 [mu] m as the standard, oversize products and undersize products are obtained, and the undersize products are pre-enriched products I; (2) after-
grinding three-section full-open-circuit short-process flotation is conducted on oversize products, the oversize products are ground to-74 microns and account for 50%-85%, then three-section full-open-circuit short-process flotation is conducted in the acid environment that the pH of ore pulp ranges from 3 to 4, and flotation concentrate is a pre-enriched product II; the collecting agent is compounded and assembled autonomously, and the novel combined collecting agent comprises the following components in percentage by
mass: 50-75% of dodecyl
guanidine hydrochloride and 25-50% of
isooctyl alcohol. The combined inhibitor comprises the following components in percentage by
mass: 30-50% of water glass and 50-70% of
sodium fluosilicate.