Technological process for directly producing spongy iron from high-phosphor oolitic hematite

A technology of oolitic hematite and a process method, which is applied in the direction of improving process efficiency and the like, can solve the problems of high phosphorus content and low iron recovery rate, and achieves the effects of high resource utilization rate, saving cost and shortening process flow

Inactive Publication Date: 2009-07-22
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
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Problems solved by technology

[0003] The purpose of the present invention is to change the existing method to limit the product to the production of iron concentrate for blast furnace ironmaking in view of the problems of high phosphorus content and low iron recovery rate in the existing meth

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  • Technological process for directly producing spongy iron from high-phosphor oolitic hematite

Examples

Experimental program
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Effect test

Embodiment 1

[0008] The raw material is a high-phosphorus oolitic hematite ore containing 28.81% iron and 0.625% phosphorus. The direct reduction roasting conditions are: the amount of reducing agent coal is 20%; the amount of sodium carbonate is 20%; after mixing, reduce and roast in a muffle furnace at 950°C for 35 minutes; cool; grind to a particle size of -0.076 at a grinding concentration of 70% mm accounts for 88%, magnetic separation at a magnetic field strength of 80kA / m. Metal iron powder with iron content of 92.45%, phosphorus content of 0.07%, and other impurity content meeting steelmaking requirements is obtained.

Embodiment 2

[0010] The raw material is a high-phosphorus oolitic hematite ore containing 37.75% iron and 1.03% phosphorus. The direct reduction roasting conditions are: the amount of reducing agent coal is 24%; the amount of sodium carbonate is 24%; after mixing, reduce and roast in a muffle furnace at 1000 ° C for 30 minutes; cool; grind to a particle size of -0.076mm at a concentration of about 78% Accounting for 90%, magnetic separation at a magnetic field strength of 80kA / m. Metal iron powder with an iron content of 91.68%, a phosphorus content of 0.065%, and other impurity contents meeting steelmaking requirements is obtained.

Embodiment 3

[0012] The raw material is a high-phosphorus oolitic hematite ore containing 43.34% iron and 1.36% phosphorus. The direct reduction roasting conditions are: the amount of reducing agent coal is 32%; the amount of sodium carbonate is 30%; after mixing, reduce and roast in a muffle furnace at 900°C for 40 minutes; cool; grind to a particle size of -0.076mm at a concentration of about 75% Accounting for 85%, magnetic separation at a magnetic field strength of 80kA / m. Metal iron powder with an iron content of 91.85%, a phosphorus content of 0.035%, and other impurity contents meeting steelmaking requirements is obtained.

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Abstract

A technique method for directly producing spongy iron by using high phosphorus oolitic hematite belongs to the iron making field, and is characterized in that the high phosphorus oolitic hematite is added with a dephosphorizing agent and then is subjected to direct metallization reducing roast by taking coal as a reducing agent, low intensity magnetic separation for raising iron and reducing phosphorus is carried out, thus obtaining the substance with more than 90 percent of iron metal and phosphorus less than 0.08 percent. The invention has the advantages as following: (1) the utilization rate of resource is high, thus shortening the process flow of making raw steel material from iron ore, avoiding from polluting environment in concentrated ore sintering, pelletizing and blast furnace ironmaking in other methods, and having obvious environmental benefits, energy-saving and consumption reduction effects; (2) the technique method is simpler than other methods, the iron raising process and phosphorus reducing process can be completed simultaneously; and (3) coal power with low cost is directly taken as the reducing agent instead of the expensive coke, thus saving the cost in coking process and avoiding from polluting environment; the varieties are simple, the source is rich, the discharging amount of pollutants in the method is less than that in other methods and the pollutants are easy to deal with.

Description

technical field [0001] The invention belongs to the field of ironmaking, and relates to a process method of direct metallization reduction roasting of high-phosphorus iron ore and synchronous dephosphorization-weak magnetic separation process, in particular to adding a dephosphorization agent to high-phosphorus oolitic hematite and using coal as a reducing agent. Direct metallization reduction roasting-weak magnetic separation process for iron extraction and phosphorus reduction. Background technique [0002] High-phosphorus oolitic hematite is the most widely distributed and most important sedimentary iron deposit in my country's iron ore resources, accounting for about 1 / 9 of the domestic iron ore resources. Because the iron minerals and gangue minerals in the high-phosphorus oolitic hematite are embedded in oolitic particles with extremely fine particle size, and accompanied by collophosite which is difficult to separate by general beneficiation methods, it is an extremel...

Claims

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Application Information

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IPC IPC(8): C21B13/00
CPCY02P10/20
Inventor 孙体昌杨慧芬祁超英王化军杨大伟徐承焱
Owner UNIV OF SCI & TECH BEIJING
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