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75results about How to "Solve the swelling problem" patented technology

Swelling-resistant two-dimensional SA-MXene layered nanofiltration membrane, production and application

The invention discloses a production method of a swelling-resistant two-dimensional SA-MXene layered nanofiltration membrane. The production method of the swelling-resistant two-dimensional SA-MXene layered nanofiltration membrane comprises a first step of mixing MXene precursor powder and an etching agent solution, carrying out a stirring reaction, and conducting centrifugal washing to obtain a two-dimensional MXene nanosheet colloid solution; a second step of adding sodium alginate into the two-dimensional MXene nanosheet colloid solution, and evenly stirring and mixing an obtained mixture to obtain SA-MXene nanosheets; and a third step of stacking the SA-MXene nanosheets on a surface of a substrate to produce a membrane, and placing the membrane in a polyvalent metal solution for cross-linking to obtain the swelling-resistant two-dimensional SA-MXene layered nanofiltration membrane. According to the method, by evenly grafting the sodium alginate onto surfaces of MXene nanosheets, through a cross-linking effect of the sodium alginate and polyvalent metal ions, stable hydrophilic cross-linked networks are formed in interlayer channels of the nanosheets, thus the problem of swelling of a layered membrane is solved, meanwhile, due to the fact that the sodium alginate is doped, a large number of oxygen-containing functional groups are introduced onto surfaces of the mass transferchannels, the channel electronegativity is improved, and the layered membrane shows excellent selective filtering performance.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY

Low-platinum proton exchange membrane fuel cell membrane electrode and preparation method thereof

The invention belongs to the technical field of fuel cells, and particularly relates to a low-platinum proton exchange membrane fuel cell membrane electrode and a preparation method thereof. The low-platinum proton exchange membrane fuel cell membrane electrode comprises catalyst layers coated on the two sides of a proton exchange membrane, each catalyst layer comprises a porous material and a catalyst filled in the porous material, and the catalyst is one or more of platinum-carbon catalysts with the platinum loading capacity of 40%-60%. The catalyst layer of the membrane electrode is prepared from the porous material and the catalyst filled in the porous material, the usage amount of platinum is reduced by adjusting the structure of the catalyst layer of the membrane electrode, the usageamount of platinum is reduced by adopting a partial structure ordering process and adjusting the structure of the catalyst layer of the membrane electrode, and the cost of the fuel cell is reduced. Compared with a traditional membrane electrode, the membrane electrode provided by the invention adopts a partially ordered structure, so that the catalyst utilization rate can be effectively improved,the catalyst loading capacity is reduced, the membrane electrode swelling problem is solved, amplification is easy, and batch production is facilitated.
Owner:WUXI WEIFU HIGH TECH CO LTD

Preparation method of composite proton exchange membrane for fuel cell

The invention discloses a preparation method of a composite proton exchange membrane for a fuel cell, and belongs to the technical field of fuel cells. The preparation method comprises the steps of performing H < + > conversion treatment on F < + > type perfluorinated sulfonic acid resin particles to convert the F < + > type perfluorinated sulfonic acid resin particles into H < + > type perfluorinated sulfonic acid resin, dissolving the H < + > type perfluorinated sulfonic acid resin, and adding water and a high-boiling-point solvent to prepare a perfluorinated sulfonic acid resin solution; adding water, a high-boiling-point solvent, a surfactant and a catalyst Pt40 / C60 into part of the perfluorinated sulfonic acid resin solution, and performing ultrasonic dispersion to obtain catalyst slurry; coating the surface of a base material with the perfluorinated sulfonic acid resin solution, and pre-drying at 50-80 DEG C to obtain a viscoelastic proton exchange membrane; and coating the surface of the viscoelastic proton exchange membrane with the catalyst slurry, and carrying out primary drying and secondary drying to obtain the composite proton exchange membrane. According to the preparation method disclosed by the invention, the catalyst can be uniformly distributed on the surface of the proton exchange membrane, the adhesive force of catalyst particles on the proton exchange membrane is effectively improved, and the thickness uniformity is improved.
Owner:长园泽晖新能源材料研究院(珠海)有限公司

CCM coating process for realizing swelling resistance by using protective back film

The invention discloses a CCM coating process for realizing swelling resistance by using a protective back film. The process comprises the following steps: coating a first surface of a proton exchangemembrane with a catalyst slurry, and performing drying to form a first catalyst layer; preparing a protective film with a flexible carrier layer, laminating a layer of protective film with the flexible carrier layer on the first surface of the proton exchange membrane containing the first catalyst layer, and laminating the protective film with the proton exchange membrane; coating the second surface of the proton exchange membrane with the catalyst slurry, and performing drying to form a second catalyst layer, so as to obtain a membrane electrode with a temporary protective membrane; finally,carrying out heat treatment or ultraviolet (UV) irradiation on the membrane electrode with the temporary protective film, and stripping the temporary protective layer to obtain the membrane electrode; and if heat treatment is selected, spraying a nano oxide solution on the surface of the first catalyst layer before the first catalyst layer is dried. In the membrane electrode preparation process,the swelling of the proton exchange membrane is effectively avoided, the preparation process is simple, the production efficiency is high, and the battery performance is excellent.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Proton membrane for PEM water electrolysis and CCM integrated preparation process and equipment

The invention discloses a PEM water electrolysis proton membrane and CCM integrated preparation process and equipment, the equipment adopts a combination of multiple nozzles and a slit type coating head, the multiple nozzles can independently spray different components of a catalyst layer multi-component composite slurry within an ultra-short time, the spraying rate and atomization degree of the different components are accurately controlled, and the production efficiency is improved. The problem of poor dispersibility of different catalysts and binders in the catalyst slurry in the same solution is solved; the preparation process comprises the following steps of: sequentially compounding the base membrane pretreatment layer, the catalyst layer 1, the functional layer 1, the composite reinforced membrane, the functional layer 2, the catalyst layer 2 and the like on the substrate to realize the integrated preparation of the PEM water electrolysis composite reinforced membrane and the CCM catalyst layer; and finally, the PEM membrane electrode has relatively low surface resistance, relatively high conductivity, mass transfer rate and chemical durability, so that the cost of PEM electrolyzed water is reduced, and the service life is prolonged.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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