This invention relates to a preparation method and application of excellent anticorrosion organic-inorganic hybridization paint. Chelating agent with good slow corrosion function and chelation is catalyst, it reacts with silane oxygen group compound, water, alcohol style solvent, cross blended matter to prepare organic-inorganic pant material, compact, flattening organic-inorganic hybridization paint can be got through control of reaction condition, the product's anticorrosion function can be improved by the chelating agent act with poly organosilicon times half oxygen alkyl. The paint doesn't contain chrome and other heavy metal element, the advantages are safety, non-poison, environmental protection, and good film capability, anticorrosion capability, anti-heat capability, chemical stability, mechanical stability, oxidation resistance, weathering resistance, insulativity etc. It can be used to metal surface protection and decoration.