505 results about "Lime kiln" patented technology

A process for sequestering carbon dioxide from the exhaust gas emitted from a combustion chamber is disclosed. In the process, a foam including a foaming agent and the exhaust gas is formed, and the foam is added to a mixture including a cementitious material (e.g., cement-kiln dust, lime kiln dust, or slag cement) and water to form a foamed mixture. Thereafter, the foamed mixture is allowed to set, preferably to a controlled low-strength material having a compressive strength of 1200 psi or less. The carbon dioxide in the exhaust gas reacts with hydration products in the controlled low-strength material and in turn sequesters the carbon dioxide.

A method of scrubbing a gas stream with re-circulated kiln dust when the kiln dust is hydrated to form a sorbent. The sorbent is re-circulated with un-reacted flue gas stream for scrubbing.

The invention provides efficient, inexpensive, and environmental friendly catalysts and catalyst systems. The catalysts can be used to catalyze esterification and/or transesterification reactions, for example, for the preparation of biodiesel. Kiln dust, such as cement kiln dust (CKD) or lime kiln dust (LKD) can be used to convert a variety of feedstock acids and/or esters to biodiesel in high yield under mild conditions. The CKD and LKD catalyst systems are recyclable esterification or transesterification catalysts that can be used to prepare biodiesel, such as methyl soyate, from various feedstocks, including vegetable oils and animal fats.

The invention provides equipment for recycling low-temperature heat of a lime kiln; the equipment mainly comprises the lime kiln, a working medium storage tank, a working medium preheater, a steam generator, a steam adjusting device, a steam turbine, a generator, a transmitter and a condenser. A working medium is preheated by using low-temperature gas of the lime kiln through the working medium preheater; the preheated working medium is converted into steam by using the heat discharged by heat-conducting oil through the steam generator; and then the generator is driven to generate power by utilizing the steam turbine, and the generated power can be supplied to electrical equipment of the lime kiln device, and also can be merged into a general power grid. When the power is insufficient, the power from the general power grid can be supplemented to power driving equipment of the lime kiln, therefore, the operation flexibility is high. By adopting the equipment, the low-temperature heat of the lime kiln can be fully utilized, meanwhile, the emission of greenhouse gases is reduced, and the production cost of lime is reduced. The equipment can be used for recycling the low-temperature heat of the lime kiln and also can be used for recycling the energy of other low-temperature heat source systems.

The invention discloses a parallel flow heat accumulating type lime kiln production technology based on CO2 accumulation. The parallel flow heat accumulating type lime kiln production technology includes the steps that limestone raw materials are fed into two kiln chambers of a parallel flow heat accumulating type lime kiln; carrier gas is sprayed into the kiln chambers; combustion supporting gas is fed; in a combustion zone of the current kiln chamber, limestone absorbs the heat generated by fuel combustion to be decomposed to generate quick lime and CO2 gas; the quick lime is discharged after being cooled to 80 DEG C to 100 DEG C; cooling gas, the CO2 gas generated by decomposing the limestone and CO2 gas generated by fuel combustion are mixed to enter the other kiln chamber to preheat limestone; flue gas generated by preheating releases heat to the limestone, then the temperature of the flue gas is reduced, the flue gas is exhausted, and CO2 gas with the volume concentration larger than 95% is generated; the parallel flow heat accumulating type lime kiln starts reversing work. By means of the parallel flow heat accumulating type lime kiln production technology, the high-purity CO2 gas is obtained while the high-quality lime is prepared. Compared with an existing technology, circulation of N2 in a system is avoided, the energy used for heating the N2 is saved, and the flue gas is recycled to achieve the aims of increasing the product added value, saving energy and reducing consumption.

The invention relates to a production device for coproduction of calcium carbide by an electrothermal method and an oxygen thermal method. The production device comprises an oxygen thermal method calcium carbide furnace, an electrothermal method calcium carbide furnace, a semi-coke furnace, a lime kiln and a power generation system. A coal briquette preparation system is connected to the semi-coke furnace through a coal briquette preheater, and the semi-coke furnace is connected to the electrothermal method calcium carbide furnace and the oxygen thermal method calcium carbide furnace. A limestone supply device is connected to the lime kiln through a limestone preheater, and the lime kiln is connected to the electrothermal method calcium carbide furnace and the oxygen thermal method calcium carbide furnace. Calcium carbide furnace gas outlets of the calcium carbide furnaces are connected to a fuel inlet of the semi-coke furnace, a semi-coke tail gas outlet of the semi-coke furnace is connected to the fuel inlet of the lime kiln and the fuel inlet of a steam boiler, and a waste heat boiler is connected to a steam turbine. A power generator set is connected to the wiring end of the electrothermal method calcium carbide furnace through a power transmission device. The production device provided by the invention fully utilizes byproducts and waste heat of the calcium carbide furnaces and the semi-coke furnace, reduces the energy consumption and the calcium carbide production cost and improves the comprehensive economic benefits of an enterprise by combining the oxygen thermal method calcium carbide furnace and the electrothermal method calcium carbide furnace with the semi-coke furnace, the lime kiln and the power generation system.

The invention discloses an energy-saving lime kiln, which aims to solve the problems that heat energy is wasted because smoke discharged by the conventional lime kiln is not utilized and fuel consumption is increased because the preheating temperature of combustion-supporting air of the lime kiln is low. The energy-saving lime kiln comprises a kiln body, wherein a preheating zone, a calcining zone and a cooling zone are sequentially on the kiln body from top to bottom; a kiln gas outlet pipe is arranged above the preheating zone; a normal-temperature air input device and a preheated air inputdevice fixed on the normal-temperature air input device are arranged in the cooling zone; each of the normal-temperature air input device and the preheated air input device comprises an air pipe and an air cap connected with an air outlet of the air pipe; the air cap of the preheated air input device is arranged above the air cap of the normal-temperature air input device; the two air caps form adouble-layer air cap structure; the kiln gas outlet pipe is connected with an air inlet of a heat exchanger; a heat exchange pipe is arranged in the heat exchanger; a cold air inlet of the heat exchange pipe is connected with an air blower; a hot air outlet of the heat exchange pipe is connected with the air pipe of the preheated air input device; and an air outlet of the heat exchanger is connected with a draft fan.

A process and system for recovering waste heat from a kiln used for lime or cement production. The system unifies the kiln, a waste heat recovery and power generation circuit and a dry scrubber for scrubbing the pollutants from the kiln offgas. Essentially, the system employs the boiler component of the waste heat recovery and power generation circuit as a heat exchanger to recover the waste heat from the kiln, which is used to drive the steam turbines. The heat absorption from the latter stage lowers the temperature of the kiln offgas sufficiently for optimum performance from the scrubber. The presence of lime particles in the offgas effectively protects the boiler tube surfaces from corrosion which would occur at optimum scrubber temperatures, and subsequently provides the lime required as a scrubbing medium for the dry scrubber. Further, the efficient scrubbing allows for the use of any fuel for firing the kiln inclusive of high sulphur content compounds. A process for effecting the technology is also provided.

The invention discloses a preparation method for rice-grain-shaped light calcium carbonate. The preparation method comprises the following steps: calcining lime stones with natural gas, adding digesting water to complete digesting reaction, performing screening, impurity-removal and ageing, adding a crystal form controller, introducing lime kiln kiln-gas to perform carbonization, pumping into a homogenizing tank to perform re-aging, and introducing purified, cooled and compressed lime kiln kiln-gas to perform secondary carbonation reaction, thereby preparing calcium carbonate slurry; and adding a modifying agent into the calcium carbonate slurry and stirring, and performing filter-pressing and dehydrating, drying, crushing and grading, thereby obtaining the rice-grain-shaped light calciumcarbonate. The light calcium carbonate crystal form prepared by the preparation method is rice-grain-shaped, has a long diameter of 150-200 nm, a short diameter of 30-50 nm, a BET specific surface area of 20-22 m<2>/g, a small length-diameter ratio, a high specific surface area and good dispersion, and can be used for manufacturing food and cosmetics; and moreover, the process is simple and feasible, the cost is low, the price is low, and the economic benefits are relatively good.

The oxygen-enriched low heat value gas burning process in rotary lime kiln includes adopting low heat value gas of (1700-2000)x4.18 kJ/cu m, such as converter gas and coke oven gas, burning in oxygen-enriched air of oxygen content 23-25 % to reach over 100 deg.c higher calcining temperature, compressing oxygen in a compressor and blending oxygen into the comburant air for burning, and increasing the oxygen content to reinforce burning, concentrate high temperature area and speed the decomposition of limestone.

The invention discloses a device and method for electrically acquiring and purifying carbon dioxide. The device comprises the following main parts: a carbon dioxide absorbing tower, an electric concentration and extraction device and a gas-liquid separation tower. Carbon dioxide contained in a waste gas is absorbed by electrically-generated alkali liquor in the carbon dioxide absorbing tower to become a carbonate solution, after the carbonate solution enters the electric concentration and extraction device, carbonates are transferred to enter a concentration chamber and converged with electrically-generated hydrogen ions to gradually form carbonic acid, the carbonic acid continuously overflows after being saturated, and after the carbonic acid is separated and purified through the gas-liquid separation tower, the carbon dioxide is compressed and stored. The device disclosed by the invention has the advantages of no pollution, easiness for operation and recycling of electrically-generated alkali liquor, and the like and can be widely applied to industrial departments, namely coal-fired power generation, coke oven combustion of a coke making enterprise, lime kiln forging, and the like which generate carbon dioxide waste gases; and the obtained carbon dioxide gas is pure and can be used as an industrial raw material, such as organic fuel methanol, a fire extinguishing agent, a refrigerant, an artificial rainfall agent, and the like.

The invention discloses a rotary kiln and a poly-generation system utilizing the rotary kiln for producing metal hydride. The poly-generation system comprises a lime production sub-system, a pulverized coal production sub-system, a calcium carbide production sub-system, a magnesium metal production sub-system, a waste heat utilizing and gas recycling sub-system, a metal hydrogen storage sub-system and a cement clinker production subsystem. Limestone, magnesite/dolomite, quartz sand and coal serve as raw materials, and the limestone is roasted into lime; in a lime kiln built through zirconia bricks, the lime and the coke powder are subjected to the high-temperature reaction so that liquid calcium carbide can be obtained; the magnesite/dolomite is roasted into magnesium oxide, and the calcium carbide, the magnesium oxide and the quartz sand are mixed to generate magnesium; high-concentration carbon dioxide, coal pyrolysis gas and calcium carbide tail gas obtained through decomposing of the limestone and the magnesite are recycled and processed, and hydrogen and food-level carbon dioxide are obtained; magnesium hydride is generated through union of hydrogen and magnesium; and carbide slag and magnesium slag are processed, and cement clinker and carbon powder are obtained. According to the poly-generation system, emission of solid waste is avoided, and carbon emission is greatly reduced.

The invention discloses a double-O-shaped lime kiln which comprises a raw material delivering mixing distributing system, a kiln main body structure, a discharging system, a dust removing system and a power device. The power device is configured with each system; the kiln main body structure is double-O-shaped; and the wall of the kiln main body structure is a fully sealed calcination structure and sequentially composed of a high-alumina brick layer, a light-weight insulating brick layer, a heat insulation fiber layer and a steel furnace shell from inside to outside. The double-O-shaped lime kiln has the advantages of being obvious in energy saving, high in automation degrees, high in qualities of finished products, low in construction costs, short in construction periods and capable of reaching the standard of environmental protection; the use ratio of fuel thermal values can reach over 80%, electric energy can be averagely saved by over 40%, and a microcomputer network control system is used so that production and activity are improved, labor intensity of workers is reduced, and working environment is improved; and according to the trail use, the double-O-shaped lime kiln is stable, reliable, low in fault rate, high in capability of interference resistance, high in accuracy of a weighing system, complete in functions and simple in operating.

A method of utilizing dicyandiamide waste residues and carbide slag to produce lime comprises the following steps: evenly mixing and stirring the dicyandiamide waste residues and the carbide slag according to a scheduled weight ratio, obtaining blank through compression moulding, wherein the scheduled weight ratio is 95 to 39 percent of the dicyandiamide waste residues and 5 to 70 percent of the carbide slag; sending the pressed blank into a carbonization furnace, passing tail gas into the carbonization furnace to conduct carbonization and drying, wherein carbonization time is 4 to 8 hours, moisture of the dried blank is less than 5 percent; and sending the carbonized and dried blank to a lime kiln to conduct calcination to obtain lime, wherein calcination temperature is 800 to 1000 DEG C. The dicyandiamide waste residues and the carbide slag can be utilized to produce lime with high purity through the method of utilizing the dicyandiamide waste residues and the carbide slag to produce lime.

The invention discloses a method for preparing nano calcium carbonate for weather-resistant ink. The method comprises the following steps of diluting an aged lime emulsion, adding a crystal form control agent into the diluted aged lime emulsion, then conveying slurry into a carbonating reaction kettle, and controlling the temperature of lime mortar to be 15 to 18 DEG C; introducing kiln gas of a lime kiln into the lime mortar, carrying out a carbonating reaction until pH (potential of Hydrogen) is decreased to 7.0, then heating obtained slurry to 30 to 35 DEG C, and repeating the step for 3 to 5 times; afterwards, heating nano calcium carbonate suspending liquid, adding a compound surface treating agent, which is prepared from saturated fatty acid saponified liquid, levopimaric acid and acrylic polyurethane, into the nano calcium carbonate suspending liquid, and agitating an obtained mixture; carrying out pressure filtration, drying and disintegration on obtained calcium carbonate slurry by using conventional methods, so that a product is obtained. The method has a simple and feasible process and is simple to operate; the quality of the product is stable; the application effect is good; not only can the flowability and the glossiness of the ink be effectively improved, but also the yellowing of the nano calcium carbonate can be effectively reduced; the weather resistance of the ink is improved; moreover, the moisture of the product can be effectively maintained; the method has better economic benefit and social benefit.

The invention relates to a thermal feeding device for a calcium carbide furnace. The device is used for directly feeding calcium oxide of 400-500 DEG C discharged from a lime kiln stewing tank into a dump truck without cooling, crushing or screening, carrying into an improved annular stock cabin through a track and a crane, mixing with coke in a feed pipe, and feeding a mixture into an enclosed calcium carbide furnace for producing calcium carbide. Due to the adoption of a process disclosed by the invention, the conveying and feeding ways of calcium carbide furnace charge are improved, and the conveying and feeding safety of the calcium carbide furnace charge is enhanced; and meanwhile, the temperature of calcium oxide entering the calcium carbide furnace can be up to 400-500 DEG C, so that heating time in the calcium carbide furnace is reduced, and the energy consumption of the calcium carbide furnace is lowered.