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Method for preparing graphite series nano fluid

A nanofluid and graphite technology, applied in chemical instruments and methods, heat exchange materials, etc., can solve problems such as general thermal conductivity, wear and corrosion of heat exchangers, achieve good product stability, improve thermal conductivity, and source of raw materials wide effect

Inactive Publication Date: 2008-05-28
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Metal particles have insufficient thermal conductivity and corrosion problems; SiC, Al 2 o 3 、TiO 2 There are general thermal conductivity and wear problems on the heat exchanger; diamond, carbon nanotubes and C 60 The high cost of production severely limits their application (diamond and carbon nanotubes also have wear problems on heat exchangers)
[0004] In short, the existing production methods of nanofluids have problems such as high cost and wear of heat exchangers, and cannot meet the urgent needs of the market for high-performance nanofluids that can be produced in large quantities and at low cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Oxidation of graphite: 100 grams of natural graphite powder and 50 grams of sodium nitrate are added to 4000 grams of 98% concentrated sulfuric acid cooled to 0°C, and after mixing, add 300 grams of potassium permanganate under stirring, and the temperature during the feeding process Control the temperature below 10°C, continue to stir for 30 minutes after the addition is complete, add 4500 grams of water, increase the temperature to 98°C, maintain at this temperature for 15 minutes, and then add 7000 grams of 40°C water and 210 grams of hydrogen peroxide, mix well and take advantage of Hot filter, wash the filter cake with water until there is no sulfate ion in the filtrate, and finally the filter cake is vacuum dried at 50°C to obtain graphite oxide;

[0020] (2) Surface modification: Use 100 grams of graphite oxide obtained in step (1) to contain 10 grams of polystyrene sodium sulfonate, 4 grams of polyvinylpyrrolidone, 4 grams of sodium polynaphthalene sulfonate, an...

Embodiment 2

[0023] (1) Oxidation of graphite: 100 grams of natural graphite powder and 20 grams of sodium nitrate are added to 1000 grams of 98% concentrated sulfuric acid cooled to 0℃, and after mixing, add 100 grams of potassium permanganate under stirring. The temperature during the addition Control the temperature below 10°C, continue stirring for 10 minutes after the addition is complete, add 1000 grams of water to increase the temperature to 60°C, maintain at this temperature for 30 minutes, then add 4000 grams of 40°C water and 120 grams of hydrogen peroxide, mix well and take advantage of Hot filter, wash the filter cake with water until there is no sulfate ion in the filtrate, and finally the filter cake is vacuum dried at 50°C to obtain graphite oxide;

[0024] (2) Surface modification: Use 100 grams of graphite oxide obtained in step (1) with 5 grams of sodium polystyrene sulfonate, 3 grams of sodium polynaphthalene sulfonate, 1 gram of polyvinylpyrrolidone, 1 gram of maleic acid a...

Embodiment 3

[0027] (1) Oxidation of graphite: 100 grams of natural graphite powder and 30 grams of sodium nitrate are added to 3000 grams of 98% concentrated sulfuric acid cooled to 0℃, and after mixing, add 200 grams of potassium permanganate under stirring, and the temperature during the feeding process Control the temperature below 10°C, continue to stir for 30 minutes after the addition is complete, add 2000 grams of water, increase the temperature to 90°C, maintain at this temperature for 30 minutes, then add 4000 grams of 40°C water and 90 grams of hydrogen peroxide, mix well and take the Hot filter, wash the filter cake with water until there is no sulfate ion in the filtrate, and finally the filter cake is vacuum dried at 70°C to obtain graphite oxide;

[0028] (2) Surface modification: Use 100 grams of graphite oxide obtained in step (1) with 8 grams of sodium polystyrene sulfonate, 1 gram of sodium polynaphthalene sulfonate, 1 gram of acrylamide copolymer, and 1 gram of polyethylene...

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PUM

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Abstract

The invention discloses a process for preparing nanophrase fluid of graphite, which comprises graphitic oxidation, surface modification and deoxidization of graphitic oxidation with surface modification. The surface modification means that surfaces of achieved 100 parts by mass of graphitic oxidation are modified to prepare graphitic oxidation with surface modification by 1-20 parts by mass of surface modifying agent. Deoxidization of graphitic oxidation with surface modification means that nanophrase graphite with surface modification is achieved by deoxidizing 100 parts by mass of products with 1-100 parts by mass of deoxidization agent. Finally the nanophrase graphite is prepared into nanophrase fluid of graphite, which is dispersed in dispersive medium by ultraphonic wave. The process of the invention can produce nanophrase fluid with high thermal conductivity, and replace nanophrase fluid of diamond, carbon nanotubes, carbon 60 and the like. Further the process of the invention has the advantages of simple technique, low cost, rich raw materials supply, and stable products, which cause no abrasion to heat exchangers.

Description

Technical field [0001] The invention relates to a method for preparing nanofluids, in particular to a method for preparing graphite-based nanofluids by using graphite as a raw material and using an oxidation-reduction method. Background technique [0002] In industries such as electric power, metallurgy, chemical industry, air conditioning, transportation and microelectronics, the application of heat exchangers is very common. Commonly used heat exchange working fluids are water, mineral oil, glycol, etc. These working fluids have low thermal conductivity and poor heat exchange performance, and have gradually become the main obstacle to enhancing heat transfer. [0003] At room temperature, the thermal conductivity of solid materials such as copper is generally 1-3 orders of magnitude greater than that of pure fluids (at room temperature, the thermal conductivity of copper is 645 times that of water and 2655 times that of engine oil), so high thermal conductivity is added to the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/08
Inventor 王卫星解东来
Owner SOUTH CHINA UNIV OF TECH
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