The invention discloses a preparation method of a high-activity
palladium-carbon catalyst and application of the high-activity
palladium-carbon catalyst in preparation of monosilane, and belongs to the technical field of
palladium-carbon catalysts. According to the invention,
hydrogen peroxide is utilized to treat a
biochar material, so that the structure of the
biochar material is destroyed and partially dissolved, then 2, 9, 16, 23-tetraamino
phthalocyanine and 2, 2 '-
bipyridine-4, 4'-dicarboxaldehyde are self-assembled in the
biochar material to form a
Schiff base structure, a porous net structure is constructed, the specific surface area is increased, more contact space and rich N sources are provided, and the biochar material has good electrochemical performance. After
roasting, the adsorption capacity and the
chemical reaction activity of the
activated carbon are enhanced. N atoms change the
density distribution of
electron clouds, are beneficial for adsorbing substances and coordinating with palladium ions, improve the
dispersity and stability of the palladium ions and are beneficial for
diffusion and adsorption of gas molecules. Through {2-[(dimethylamino) methyl]-1, 3-
thiazole-4-yl}
methanol and 1, 3-
propane sultone, the palladium-carbon catalyst has amphipathicity, can reduce interfacial tension, adjust interfacial behaviors, prevent a product from being mixed with a
solvent and promote separation during a catalytic reaction, can be recycled, and reduces the cost.