The invention provides an aqueous film-forming foam extinguishing agent special for a fire extinguishing bullet and a throwing type fire extinguisher. The aqueous film-forming foam extinguishing agent has the advantages of being small in additive amount, rapid in fire extinguishing, good in recrudescence resisting effect, environmentally friendly, efficient and the like. The aqueous film-forming foam extinguishing agent comprises, by weight, 8 percent to 12 percent of main foaming agents, 8 percent to 20 percent of auxiliary foaming agents, two percent to 10 percent of antifreeze agents, 12 percent to 22 percent of cosolvents, 0.1 percent to one percent of stabilizers, 8 percent to 20 percent of fire retardants, two percent to five percent of burning-resistance agents and the balance water. The main foaming agents are selected from F1157N, F1203 and F1460, the auxiliary foaming agents are selected from lauryl sodium sulfate, ammonium lauryl sulfate, alkyl glycoside, dodecyl dimethyl betaine and cocamidopropyl betaine. The antifreeze agents are selected from ethylene glycol, glycerol and the like. The cosolvents are selected from dodecanol, n-butyl alcohol and diethylene glycol diethyl ether. The stabilizing agents are selected from xanthan gum, Arabic gum, guar gum and sodium alginate tech grade. The fire retardants are selected from ammonium polyphosphate and ammonium dihydrogen phosphate.