A nanometer ceramic material dopant, medium material of ceramic capacitor and their production are disclosed. The formula of the dopant consists of aA.bB.cC.dR2 O3.eSiO2; A contains Na2O; B contains one or multiple of MgO and CaO; C contains one or multiple of MnO2 and Co3O4; R contains one of multiple of Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, among them a, b, c, d and e are coefficient, by computing mol%, 0<=a<=10%, 0<=b<=25%, 0<=c<=15%, 20%<=d<=60%, 10%<=e<=50% and b and c can't be zero at same time. Its advantages include large capacity, adjustable material formula, low sintering temperature, less medium loss, high dielectric constant and better reliability.