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46 results about "Composite epoxy material" patented technology

Composite epoxy materials (CEM) are a group of composite materials typically made from woven glass fabric surfaces and non-woven glass core combined with epoxy synthetic resin. They are typically used in printed circuit boards.

High-thermal-conductivity flexible epoxy composite material as well as preparation method and application thereof

PendingCN121427254AHeat-exchange elementsFirming agentEpoxy matrix
The invention provides a high-thermal-conductivity flexible epoxy composite material as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The composite material disclosed by the invention is prepared by adding polydopamine modified BN and FG which are jointly used as fillers into an epoxy matrix and adopting polyether amine as a curing agent. The polydopamine modified BN and the FG are jointly used, so that a synergistic interaction effect can be achieved in the aspects of heat-conducting property, dielectric property and mechanical strength. The epoxy composite material disclosed by the invention can obtain excellent heat-conducting property, dielectric property and insulating property under the compatibility of specific raw materials. And when the curing agent with a long molecular chain is adopted, the epoxy composite material can obtain excellent flexibility, and the problem of brittleness of the existing epoxy composite material is solved. A research basis is provided for preparation and performance research of the flexible epoxy composite material, and the flexible epoxy composite material has a good application prospect.
Owner:SICHUAN UNIV +1

High-strength low-density epoxy SMC composite material and preparation method thereof

ActiveCN121045742BFiberMicrosphere
The application belongs to the field of epoxy resin composites, and specifically provides a high-strength low-density epoxy SMC composite material and a preparation method thereof, which is prepared by the following steps: S01. Taking a PVC core plate, gluing after grooving, then laying a fiber cloth, vacuumizing under negative pressure after film covering, then pouring a pre-impregnation liquid, and placing to obtain a pre-cured composite plate; S02. Taking the pre-cured composite plate, placing overnight after mold pressing treatment, and then obtaining after demolding and edge trimming treatment; the pre-impregnation liquid preparation step comprises the following: mixing an active diluent, an accelerator, modified microspheres and a filler, first adding an epoxy resin, stirring, then adding the remaining amount of epoxy resin, and then adding a curing agent and a demolding agent, and continuously mixing to obtain the pre-impregnation liquid; the modified microspheres are used as a pre-impregnation liquid additive component, and the prepared SMC composite material product has a density ≤1.57 g / cm 3 , an impact strength ≥84.5 KJ / m 2 , and good flame retardance.
Owner:ZHEJIANG SIDA NEW MATERIAL CO LTD

A method for regulating the dynamic performance of hot-pressing molding epoxy vitrimer composites by the content of oriented filler V-shaped

ActiveCN117124521BPolymer scienceResin matrix
The application discloses a method for regulating the dynamic performance of hot-pressing molding epoxy vitrimer composites by the V-shaped content of oriented fillers, uses flake graphite as the lamellar oriented filler, and uses the dynamically chemically cross-linked epoxy vitrimer as the resin matrix, so that the content of the lamellar oriented filler is changed by changing the single-layer thickness and the number of layers while keeping the total thickness unchanged, and the V-shaped regulation method of the dynamic performance of the hot-pressing molding anisotropic epoxy vitrimer composites is realized. The dynamic performance of the epoxy vitrimer composite presents a V-shaped change trend with the content of the lamellar oriented filler, which is completely different from the linear inhibition behavior of conventional fillers, and the application can be used for regulating the dynamic performance of the epoxy vitrimer by the V-shaped content of the oriented filler.
Owner:INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS

Epoxy fiber composite material for wind turbine blades and method of making

The wind power blade epoxy fiber composite material and preparation method relate to material technology and environmental protection technology, and the preparation method comprises the following steps: (1) preparation of glycidyl ester type epoxy resin: after mixing, the low molecular weight glycidyl ester type epoxy resin is reacted with a chain extender modifier, and the low molecular weight glycidyl ester type epoxy resin molecules are combined into high molecular weight glycidyl ester type epoxy resin molecules; (2) preparation of an epoxy resin composition: the glycidyl ester type epoxy resin prepared in the step (1) is uniformly mixed with an amine curing agent at room temperature to obtain the epoxy resin composition; (3) the epoxy resin composition is impregnated into inorganic fibers, and after drying, the wind power blade epoxy composite material is obtained. The wind power blade material has good mechanical properties, high heat resistance, low production cost, and is easy to recycle.
Owner:四川东树新材料有限公司

Epoxy-terminated polyurethane flexibilizer as well as preparation method and application thereof

The invention provides an epoxy-terminated polyurethane flexibilizer and a preparation method and application thereof, and belongs to the technical field of epoxy composites.The epoxy-terminated polyurethane flexibilizer is prepared from polyol, isocyanate, a chain extender, a catalyst, metal salt and epoxy resin, and the chain extender comprises hydroxybenzoxazine. The epoxy-terminated polyurethane toughening agent provided by the invention contains carbamate groups, benzoxazine groups and five-membered oxazolidinone structures, the groups have strong polarity, and due to the introduction of the five-membered oxazolidinone and the benzoxazine groups, the toughening agent has excellent stability at a high temperature and in a salt mist old chemical process, so that the toughness of the toughening agent is improved, and the service life of the toughening agent is prolonged. The toughening agent is added into the epoxy resin structural adhesive, the adhesion of the epoxy resin structural adhesive to metal materials can be improved while the glass transition temperature is not reduced, and the toughening agent further contains a polyether chain segment which can improve the low-temperature impact resistance of the epoxy resin structural adhesive.
Owner:NINGBO FENGMEI CHEM TECH CO LTD

Silk protein peptide modified alumina filler, epoxy resin composite material and preparation method thereof

PendingCN122325935APolymer scienceFirming agent
This invention discloses a silk fibroin peptide-modified alumina filler, an epoxy resin composite material, and their preparation method. The preparation method of the epoxy resin composite material includes the following steps: S1: Preparation of silk fibroin peptide-modified alumina filler: Silk fibroin peptides are dispersed in water, and alumina filler is added to allow the silk fibroin peptides to be adsorbed onto the surface of the alumina filler; then, after solid-liquid separation and drying, silk fibroin peptide-modified alumina filler is obtained; S2: Preparation of epoxy resin composite material: The silk fibroin peptide-modified alumina filler is mixed evenly with epoxy resin and a curing agent, and then cured to obtain an epoxy resin composite material based on silk fibroin peptide-modified alumina. The epoxy resin composite material obtained utilizes biodegradable silk fibroin peptides to modify the surface of the alumina filler, constructing a three-dimensional thermally conductive network with low interfacial thermal resistance, thereby achieving synergistic optimization of the thermal conductivity and degradability of the epoxy composite material.
Owner:STATE GRID ANHUI ELECTRIC POWER CO LTD ELECTRIC POWER SCI RES INST +1

Toughening curing agent, preparation method of toughening curing agent, epoxy composite material and application of epoxy composite material

The invention provides a toughening curing agent and a preparation method thereof as well as an epoxy composite material and application thereof, and belongs to the technical field of composite materials. A long-chain modifier diamine compound with excellent flexibility and mechanical properties is adopted to modify an anhydride curing agent, amino groups of the diamine compound react with anhydride groups of the anhydride curing agent, the long-chain modifier with excellent mechanical properties is embedded into the curing agent, and the curing agent with a rigid-flexible-rigid structure is formed; the molecular chain segment length of the curing agent can be effectively increased, so that the free volume ratio of the molecular structure of the epoxy composite material is improved, the epoxy composite material can obtain a displacement space when subjected to mechanical stress, generation of internal stress is reduced, and reliable toughening of the epoxy composite material is realized; the anhydride curing agent can endow the epoxy composite material with excellent heat resistance and mechanical properties at high temperature.
Owner:NANJING ELECTRIC HIGH VOLTAGE BUSHING +2

Rear cover laminated board with improved bending performance and preparation method thereof

The invention discloses a rear cover laminated board with improved bending performance and a preparation method thereof, relates to the technical field of electronic product shells, and provides the rear cover laminated board with improved bending performance and the preparation method thereof. The silicon carbide fiber is used as a base material, the tensile strength of the silicon carbide fiber is high, and excellent rigid support can be provided for the laminated board, so that the bending strength of the epoxy composite material is improved, and the performance requirement of a 3C shell is met. The modified epoxy resin is used as a matrix, the silicon carbide ceramic fiber cloth coated with dopamine is doped, and the cobalt hydroxide nanosheets are loaded on the silicon carbide ceramic fiber cloth, so that the strength of the laminated board is enhanced. Then, dopamine is used for coating, and a silicon dioxide aqueous solution is used for forming a silicon dioxide-containing micro-nano structure on the surface, so that the surface hydrophobicity is enhanced. The prepared shell material not only has enough rigidity, but also has excellent toughness, and meets the requirements of'deformation resistance 'and'fracture resistance'.
Owner:HUIZHOU ZONGSHENG ELECTRONICS MATERIAL CO LTD

Double p flame retardant, epoxy composite material and application in type iv hydrogen storage cylinder

The application relates to a double-P flame retardant, an epoxy composite material and application in a type IV hydrogen storage cylinder, relates to the technical field of flame retardant materials, and solves the problem that the existing epoxy resin used in the type IV hydrogen storage cylinder cannot simultaneously consider strength, toughness and flame retardant characteristics.The double-P flame retardant is synthesized by the following steps: reacting green and environment-friendly renewable bio-based raw material vanillin with a catalyst triethylamine to obtain a first-step intermediate, then reacting the first-step intermediate with a biomass amine substance to obtain a Schiff base intermediate, and finally reacting the Schiff base intermediate with DOPO.The epoxy composite material is prepared by the flame retardant and the epoxy resin.The reaction process is convenient to operate, and the preparation method is simple, which not only provides a new idea for expanding the application of the epoxy resin in the field of high-performance materials, but also provides a relatively suitable winding layer material for hydrogen energy, especially the type IV hydrogen storage cylinder, and is suitable for industrial production.
Owner:CHANGCHUN UNIV OF TECH

Method for improving mechanical property of epoxy resin based on metamaterial skeleton support

The invention relates to a method for improving the mechanical property of epoxy resin based on metamaterial skeleton support, the mechanical property of the epoxy resin is improved by designing a honeycomb metamaterial skeleton, and the specific steps are as follows: S1, designing a skeleton structure: selecting a honeycomb shape of the honeycomb metamaterial skeleton, and regulating and controlling the geometric dimension and wall thickness parameters of the honeycomb shape; and S2, preparing metamaterial skeleton composite resin: printing and curing dual-curing epoxy resin by adopting a photocuring 3D printing technology to obtain a honeycomb metamaterial skeleton as a support, pouring thermocuring epoxy resin into gaps of the honeycomb metamaterial skeleton, and performing vacuum drying after curing to obtain the metamaterial skeleton composite resin. A photo-curing 3D printing metamaterial framework is adopted as a support, thermosetting epoxy resin is poured in gaps of the framework, and the metamaterial framework realizes directional optimization of a stress transfer path of the material by accurately regulating and controlling unit cell shapes, geometric dimensions, wall thickness parameters and the like, so that the mechanical property of the epoxy composite material is improved.
Owner:CHONGQING UNIV

Composite material rudder wing structure for aircraft and forming method of composite material rudder wing structure

The invention relates to the technical field of aircrafts, in particular to a composite material rudder wing structure for an aircraft and a preparation method thereof.The composite material rudder wing structure comprises a main beam and sandwich foam layers located on the two sides of the main beam, the main beam and the sandwich foam layers are of a structure with the middle thick and the two ends thin, and the main beam and the sandwich foam layers are connected through an adhesive; the main beam comprises at least three high-modulus glass fiber pultrusion plates, multi-axial glass fiber prepreg is arranged between the adjacent high-modulus glass fiber pultrusion plates, and the main beam and the sandwich foam layer are coated with a glass fiber-epoxy composite material layer. The rudder wing structure has the advantage of being light in weight, and the weight of the rudder wing structure can be reduced by 35%-40% compared with that of an aluminum alloy rudder wing; the rudder wing is made of a glass fiber composite material and has good wave-transparent performance, the surface of the rudder wing is subjected to appearance treatment through fluorocarbon paint, and the requirements for corrosion resistance, aging resistance and wave-transparent related performance are improved.
Owner:JIANGSU CHANGZHUO TECH CO LTD

Method, equipment and medium for detecting internal crack defects of epoxy composite material

The invention relates to the technical field of gas insulation, in particular to an epoxy composite material internal crack defect detection method, equipment and a medium, structural parameters of a 110kV epoxy basin-type insulator are measured, and three-dimensional modeling software is adopted to construct a three-dimensional structural model equal to a real object in proportion; applying a thermal boundary condition to the three-dimensional structure model body, respectively setting the depth and the deflection angle of the crack defect as h and theta, and setting the material attribute of the bubble defect area as air; the method comprises the following steps: acquiring surface thermal imaging characteristics of the defect of the epoxy basin-type insulator based on a solid heat transfer theory, outputting the surface thermal imaging characteristics of the defect of the epoxy basin-type insulator, and acquiring surface thermal imaging characteristics of the crack defect at different deflection angles under different defect depths by changing the depth and the deflection angle of the crack defect for many times based on the solid heat transfer theory. Equipment temperature resolution is used as a judgment basis, and feasibility exploration of crack defect detection at different deflection angles under different defect depths is realized.
Owner:GUIZHOU POWER GRID CO LTD

High-toughness, repairable, recoverable and flame-retardant epoxy vitrimer and composite material thereof

The invention belongs to the field of functional polymers, and particularly relates to a high-toughness, repairable, recoverable and flame-retardant epoxy vitrimer and a composite material thereof. The epoxy vitrimer is obtained by reacting dithio-diphenyl diglycidyl ether, bisphenol A diglycidyl ether, isocyanuric acid tri [2-(3-mercaptopropionyloxy) ethyl ester] and dithio-diphenyl diphosphate diphenyl at the temperature ranging from room temperature to 90 DEG C or above, after being completely cured, the epoxy vitrimer shows the characteristic of high toughness, the elongation at break reaches 200% or above, and the epoxy vitrimer shows that damage can be repaired and the service life of the epoxy vitrimer is prolonged. And hot-pressing recycling and reshaping and flame-retardant characteristics can be realized. The high-toughness, repairable, recoverable and flame-retardant epoxy vitrimer composite material is obtained by reacting the epoxy vitrimer resin and silicon dioxide modified by dithio diphenyl phosphate diphenyl glycidyl ether at the temperature ranging from the room temperature to 90 DEG C or above; the epoxy vitrimer composite material shows the characteristic of high toughness after being completely cured, the elongation at break reaches 150% or above, and the epoxy vitrimer composite material shows the characteristics of being repairable in damage, capable of being recycled and reformed through hot pressing and flame-retardant.
Owner:INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS

P / N synergistic flame retardant, preparation method thereof and application of P / N synergistic flame retardant in epoxy resin

The invention relates to the technical field of flame retardants, in particular to a P / N synergistic flame retardant, a preparation method thereof and application of the P / N synergistic flame retardant in epoxy resin. A conventional flame retardant is complex in structure, poor in compatibility with epoxy resin and large in influence on the performance of the epoxy resin. In order to solve the problems, the flame retardant is synthesized through a two-step method, firstly, 5-aminotetrazole and benzaldehyde or a derivative thereof react to generate a Schiff base intermediate, and then the intermediate and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide are subjected to a phosphorus-hydrogen addition reaction to obtain a final product. The limit oxygen index of the composite material can be increased to 35.8% by only adding 4wt% of the composite material into epoxy resin, the vertical combustion grade reaches UL-94 V-0 grade, and meanwhile, the influence on the original high transparency and mechanical property of the material is extremely small. The invention provides a new technical scheme for preparing the high-performance environment-friendly flame-retardant epoxy composite material.
Owner:CHANGZHOU UNIV

Carbon fiber / phenolic aldehyde / epoxy composite material with three-dimensional heat conduction network, preparation method thereof and heat management device

PendingCN121406081ACarbon fibersHeat management
The invention belongs to the technical field of preparation of carbon fiber heat-conducting composite materials, and discloses a carbon fiber / phenolic aldehyde / epoxy composite material with a three-dimensional heat-conducting network, which comprises a three-dimensional skeleton structure formed by hot-pressing and curing carbon fibers and phenolic resin, and the epoxy resin is subjected to vacuum impregnation, is filled in gaps of the three-dimensional skeleton structure and is subjected to hot-pressing curing. The preparation method comprises the steps of ultrasonic dispersion, vacuum filtration, hot press molding and vacuum infusion. The continuous three-dimensional carbon fiber network is constructed as a main heat conduction path, so that the heat conduction capability of the composite material is remarkably improved; experimental data show that by adjusting the content of the carbon fibers, the in-plane heat conductivity of the composite material can be increased to 56.19 W / (m.K), the out-plane heat conductivity can also be increased to 6.72 W / (m.K), excellent anisotropic heat conduction characteristics are shown, and heat dissipation requirements in different directions can be met in a targeted mode.
Owner:ZHUJI LINGKEN ZHONGZHI NEW MATERIAL CO LTD

High-strength low-density epoxy SMC composite material and preparation method thereof

ActiveCN121045742AFiberPolymer science
The invention belongs to the field of epoxy resin composite materials, and particularly provides a high-strength low-density epoxy SMC composite material and a preparation method thereof.The preparation method comprises the following steps that S01, a PVC core plate is taken, grooving is conducted, then glue brushing is conducted, then fiber cloth is laid, film covering is conducted, negative pressure vacuumizing is conducted, then presoaking liquid is poured, and standing is conducted to obtain a precured composite plate; and S02, taking the pre-cured composite board, carrying out mold pressing treatment, standing overnight, and carrying out demolding and trimming treatment, so as to obtain the composite board. The preparation method of the prepreg liquid comprises the following steps: mixing a reactive diluent, an accelerant, modified microspheres and a filler, adding epoxy resin for the first time, stirring, supplementing the balance of epoxy resin, adding a curing agent and a release agent, and continuously mixing to obtain the prepreg liquid; the SMC composite material product prepared by using the modified microspheres as a preimpregnation liquid adding component has the density of less than or equal to 1.57 g / cm < 3 >, the impact strength of more than or equal to 84.5 KJ / m < 2 > and good flame retardance.
Owner:ZHEJIANG SIDA NEW MATERIAL CO LTD

DLC-coated Al2O3 epoxy composite material and thermal conductivity improving method thereof, DLC-modified Al2O3 core-shell particle and preparation method and application thereof

The invention discloses a DLC (Diamond Like Carbon) coated Al2O3 epoxy composite material, a thermal conductivity improving method of the DLC coated Al2O3 epoxy composite material, DLC modified Al2O3 core-shell particles as well as a preparation method and application of the DLC modified Al2O3 core-shell particles. The DLC coated Al2O3 epoxy composite material comprises an epoxy resin matrix and a DLC modified Al2O3 core-shell particle filler, according to the DLC modified Al2O3 core-shell particle, Al2O3 serves as an inner core, DLC serves as a shell layer, and the sphybridization rate of the DLC shell layer is not smaller than 55%; the phonon matching degree between the epoxy resin and the filler can be effectively improved, the interface thermal resistance is reduced, and then the thermal conductivity of the epoxy composite material is improved.
Owner:STATE GRID ANHUI ELECTRIC POWER CO LTD ELECTRIC POWER SCI RES INST +1

An epoxy composite material based on hollow glass microspheres and its preparation method

PendingCN122278135APolymer scienceFirming agent
This invention belongs to the field of composite material technology, specifically relating to an epoxy composite material based on hollow glass microspheres as filler and its preparation method. Addressing the challenges of high surface polarity of hollow glass microspheres, poor compatibility with organic resins, and the difficulty of achieving a balance of high strength, high toughness, and aging resistance in existing composite materials, this invention utilizes ultraviolet ozone to synergistically activate glass microspheres, followed by surface modification with tannic acid. Simultaneously, a base epoxy resin, octaepoxypropyl cage-type polysilsesquioxane, and bis(2-aminophenyl)disulfide are mixed. Finally, tannic acid-modified glass microspheres and a curing agent are added to the prepolymer, followed by stepwise temperature curing to obtain the epoxy composite material.
Owner:JUCHUANG (JIANGMEN) NEW MATERIAL TECH CO LTD

A planar impact low-bursting-force directional fracture film cap and its preparation method

This invention relates to a planar impact low-bursting-force directional fracture membrane cap and its preparation method. The membrane cap comprises a membrane cap body (1), a stress concentration structure (2), and a sub-cap connecting structure (4). The membrane cap body (1) is a glass fiber epoxy composite material structure, and the membrane cap body (1) further includes a connecting flange (101), a reinforcement (102), a fracture sub-cap (103), and a weakening groove (104). This invention achieves the controllability of the fragments after the fracture of a membrane cap subjected to surface-to-surface impact, overcomes the uncontrollability of the fragments after the fracture of a membrane cap subjected to surface-to-surface impact in the prior art, and protects the integrity of the impact without damage.
Owner:BEIJING HANGTIAN XINFENG MECHANICAL EQUIP

Graphene-reinforced high-density epoxy composites for injection molding and methods of making

This invention belongs to the field of thermosetting polymer composite material preparation technology, and particularly to graphene-reinforced high-density epoxy composite materials for casting molding and their preparation method. The method uses a two-component epoxy resin system as the continuous phase and graphene as both a functional filler and a reinforcing filler. First, component A and component B are premixed in a specific ratio. Then, graphene is added stepwise and mixed at low speed. Subsequently, a vacuum degassing process is performed, followed by preheating the mold for casting, a second vacuuming process, and step-curing at 80℃ / 140℃. The graphene is preferably one of high-purity multilayer graphene, few-layer graphene, or single-layer graphene, and the addition process can be carried out in two, three, or four steps depending on the number of layers and the difference in bulk density. This method can balance the uniformity of graphene dispersion, slurry workability, product density, and consistent black surface appearance. The resulting products are suitable for electronic packaging, potting compounds, functional structural components, and thermally and electrically conductive castings.
Owner:深圳市贝伦斯智能穿戴科技有限公司 +1

A method for preparing a carbon fiber epoxy composite material with high mechanical performance and low thermal expansion coefficient

PendingCN122255527Aperformance impactomit conditionsFiberCarbon fibers
This invention discloses a method for preparing carbon fiber epoxy composite materials that combine high mechanical properties and a low coefficient of thermal expansion. Belonging to the field of composite materials, it addresses the technical challenge of simultaneously improving the mechanical properties and reducing the coefficient of thermal expansion of composite materials using existing carbon fiber processing methods. By non-covalently modifying carbon nanotubes with ionic liquids, unlike traditional covalent modification methods, the intrinsic strength of carbon nanotubes is preserved, constructing a multi-mechanism synergistic interface reinforcement system. This specifically addresses the key problems of traditional sizing agents having a single interfacial effect and hindered stress transmission. In this invention, flexible polyimide acts as a bridge at the interface, while rigid carbon nanotubes construct an effective armor on the fiber surface. The two form a rigid-flexible composite structure at the interface, which effectively alleviates interfacial stress concentration, significantly improves interfacial stress transmission efficiency, achieves uniform dispersion of external loads, and ultimately improves the mechanical properties of the carbon fiber epoxy composite material.
Owner:JILIN INST OF CHEM TECH

Anticorrosive paint based on flame-retardant functional organic framework material

The invention relates to a metal surface anti-corrosion material, in particular to an anti-corrosion coating based on a flame-retardant functional organic framework material. The flame-retardant waterborne epoxy resin coating comprises the following components in parts by mass: 100-120 parts of waterborne epoxy resin, 15-30 parts of a nitrogen-chlorine-zinc organic framework material, 10-20 parts of a flame-retardant aid, 40-55 parts of a curing agent, 5-10 parts of pigment filler and 10-15 parts of water. The material has excellent thermal / mechanical properties; the material can be widely applied to the fields of photocatalysis, catalysis, adsorption and the like; the protective performance of the epoxy composite material is improved, and meanwhile, the mechanical property of the epoxy composite material is effectively improved.
Owner:JIANGSU CHAMPION TECHNOLOGY GROUP CO LTD

Preparation method and application of high-voltage GIS / GIL epoxy composite material based on short-chain grafted cross-linked network

The invention relates to a preparation method and application of a high-voltage GIS / GIL epoxy composite material based on a short-chain grafted cross-linked network. The preparation method comprises the following steps: step 1, preparing experimental raw materials and carrying out pretreatment; 2, a uniform casting master batch PPU-EP-MTHPA is prepared; step 3, preparing a uniform casting master batch Al2O3 (aluminum oxide)-PPU (polypropylene)-EP (ethylene propylene)-MTHPA (methyl tetrahydrofuran); 4, the uniform casting master batch Al2O3-PPU-EP-MTHPA is subjected to vacuum gravity casting, and the uniform casting master batch Al2O3-PPU-EP-MTHPA is subjected to vacuum gravity casting; and step 5, carrying out segmented curing and internal stress elimination on the Al2O3-PPU-EP-MTHPA subjected to gravity casting, and finally obtaining an epoxy composite material sample based on the short-chain grafted cross-linked network or a GIS / GIL basin-type insulator finished product. According to the invention, the electrical, thermal and mechanical properties of the epoxy composite material for high-voltage GIS / GIL can be synergistically enhanced.
Owner:HEBEI UNIV OF TECH

High-toughness epoxy composite insulating material and preparation method thereof

PendingCN121181950AResin matrixFirming agent
The invention relates to the technical field of epoxy resin synthesis, in particular to a high-toughness epoxy composite insulating material and a preparation method thereof. The preparation method specifically comprises the following steps: magnetizing and modifying short glass fibers; sequentially adding an anhydride curing agent and nano silicon dioxide into epoxy resin to obtain a mixed solution; the preparation method comprises the following steps: adding modified magnetized glass fibers and an accelerant into a mixed solution, applying a magnetic field in a gradient curing process, and directionally arranging the glass fibers in a resin matrix, so that the resin forms a three-dimensional cross-linked network under a fiber-particle synergistic effect, thereby obtaining the high-toughness epoxy composite material. The method is simple and easy to operate, and the repeated treatment effect has good reproducibility, so that the batch production of the high-toughness epoxy resin material can be realized. While the insulating property of the epoxy composite material is ensured, the mechanical property of the epoxy composite material is effectively improved, and a reference is provided for localization of high-toughness epoxy electrical materials.
Owner:CHINA ELECTRIC POWER RESEARCH INSTITUTE CO LTD +2

Epoxy composite material for direct-current GIS / GIL insulator, preparation method of epoxy composite material and direct-current GIS / GIL insulator

The invention provides an epoxy composite material for a direct-current GIS / GIL insulator, a preparation method of the epoxy composite material and the direct-current GIS / GIL insulator, and relates to the field of high-voltage equipment. The epoxy composite material for the direct current GIS / GIL insulator is prepared from the following raw materials in parts by weight: 95 to 105 parts of low-chlorine epoxy resin, 30 to 70 parts of anhydride curing agent and 300 to 450 parts of inorganic filler, the total chlorine content of the low-chlorine epoxy resin is 300 ppm to 800 ppm. By controlling the total chlorine content of the low-chlorine epoxy resin, incomplete curing, reduction of electrical performance and other performance and even influence on environmental protection property and safety caused by too high chlorine content are avoided, and the problems that after the chlorine content is extremely low, the system activity is reduced, the gelation time is prolonged by 20-30% at the same curing temperature, an accelerant needs to be additionally added, and the cost is low are solved. Otherwise, the problems of incomplete reaction, Tg, cross-linking density reduction and the like can be caused.
Owner:MOTIC (XIAMEN) INTELLIGENT ELECTRIC CO LTD

An epoxy composite based on waste PET depolymerization product modified titanium dioxide and its preparation and application

The application belongs to the technical field of epoxy composites, and discloses an epoxy composite based on waste PET depolymerization product modified titanium dioxide and a preparation and application thereof.The epoxy composite is made of the following raw materials in parts by weight: 100 parts of epoxy resin, 5-50 parts of modified titanium dioxide, 0.2-0.5 parts of catalyst and 5-20 parts of curing agent; the modified titanium dioxide is prepared by reacting 100 parts by weight of titanium dioxide precursor with 2-10 parts by weight of waste PET depolymerization product terephthalic acid and forming a gel by dropping ethanol aqueous solution, cleaning and drying.The method overcomes the poor compatibility of titanium dioxide with epoxy resin, easy agglomeration and other shortcomings, the dispersibility of the modified titanium dioxide in the epoxy resin is obviously improved, and the prepared epoxy composite has good dielectric properties and is used for packaging materials of electronic components and capacitor materials.
Owner:SOUTH CHINA UNIV OF TECH

An epoxy composite material that can be repaired and reworked at sub-glass transition temperature conditions and methods of making and use thereof

The application provides an epoxy composite material which can be repaired and reprocessed under conditions below the glass transition temperature, a preparation method and application thereof, and belongs to the field of advanced materials. The epoxy resin containing imine bonds and VU dynamic covalent bonds is used as a matrix, and a shaped composite material is prepared through continuous fiber reinforcement. The composite material has good initial interlaminar shear strength and repair capacity, can be hot-pressed and repaired under conditions below the glass transition temperature, and the fibers can be recycled without damage. The composite material prepared by the application has significant advantages in composite material repair, service life extension, secondary processing, recycling and reprocessing, recycling, and resource saving and environmental protection, and has great potential and broad application prospects in the field of composite materials.
Owner:SICHUAN UNIV

Epoxy high-temperature mold

The utility model provides an epoxy high-temperature mold, relates to the technical field of molds, and aims to solve the problems that a common glass fiber reinforced plastic mold is relatively large in thermal expansion coefficient, is easy to thermally deform and is greatly damaged by high-temperature curing when the conventional mold is used for producing. The epoxy high-temperature mold comprises a mold body and a mounting component, the mold body is an epoxy high-temperature mold body, and the mold body comprises a main body made of an epoxy composite material; the mounting assembly is connected with the mold body, the gap part of the framework is welded in a # shape, and the framework is in contact with the mold body. The main body can bear higher temperature, can meet the requirements of various high-temperature processes, can keep the stability and the dimensional precision of a mold in the manufacturing of a high-temperature cured and molded composite material, is small in linear shrinkage rate, is favorable for ensuring the precision and the quality of a product, has better tolerance to various resins, and is suitable for large-scale production. And the epoxy mold can be repaired in a repairing manner, so that the production cost is reduced.
Owner:QINGDAO TIETONGDA NEW MATERIAL TECH CO LTD

MXene@bn heterostructure heat-conducting filler and epoxy composite material thereof and preparation method thereof

ActiveCN119529388BHeterojunctionBoron nitride
The application provides a MXene@BN heterostructure heat-conducting filler and a preparation method of an epoxy composite material thereof, boron nitride and MXene nanosheets are modified by cation and anion modifiers respectively, and a heterostructure filler is constructed by using electrostatic self-assembly. The filler is applied to an epoxy resin, and the prepared MXene@BN / epoxy composite material exhibits excellent thermal conductivity and electrical insulation. The method is simple and efficient in preparation process, is suitable for large-scale industrial production, can balance high thermal conductivity and excellent electrical insulation performance under low filler loading, and provides an innovative and efficient heat dissipation solution for the electronic packaging field.
Owner:EAST CHINA UNIV OF SCI & TECH