The invention relates to benzimidazole-epoxy matrix resin and a preparation method thereof. The resin consists of an A component and a B component. The preparation method comprises the following steps of (1) putting N,N,N',N'-tetraglycidyl-2,2-di-[4-(4-amino phenoxyl) phenyl] propane and 2-(4-amino phenyl)-5-amino benzimidazole into a reaction kettle, heating and raising the temperature to 70-80 DEG C, stirring and reacting for 15min-30min, adding a reactive diluent and an organic solvent, stirring uniformly, obtaining the A component, (2) mixing a curing agent with the organic solvent, stirring and dissolving uniformly, obtaining the B component, and (3) mixing the A component with the B component and stirring uniformly in a use process. The preparation method is simple; and the obtained matrix resin is excellent in comprehensive performance, can be applied to glass fiber or carbon fiber reinforced advanced composites, and can also be applied to adhesive agents of substrates such as metal, glass and ceramics.