High-thermal-conductivity strong-insulation epoxy composite material for solid-state transformer under low doping amount and preparation method thereof

A technology of solid-state transformers and composite materials, applied in the field of thermally conductive and insulating composite materials, can solve the problems of iron core hysteresis loss, coil insulation material loss and heat generation, damage to insulation performance, large amount of filler doping, etc., and achieve low dielectric constant and loss , Improve the electrical insulation performance, and the effect of simple processing technology

Pending Publication Date: 2020-11-03
GLOBAL ENERGY INTERCONNECTION RES INST CO LTD +1
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  • Summary
  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

However, in the solid-state transformer part of the power electronic transformer, the hysteresis loss of the iron core, the Joule heat of the coil, and the loss and heat generation of the insulating material itself will cause a local temperature rise of 150-170°C, which will affect the long-term stable operation of the equipment.
[0003] As the main insulating medium of solid-state transformers, epoxy resin has the advantages of good insulation performance, easy processing and molding, high hardness, and stable performance, but the intrinsic thermal conductivity of epoxy is not high (only 0.20-0.22W/(m·K )), which limits the heat dissipation efficiency of devices and power equipment. At the same time, during the operation of solid-state transformers, epoxy resin, as the main insulating medium, is often in a multi-field coupling environment such as electricity, heat, and machinery. The insulation performance puts forward higher requirements, so the study of high thermal conductivity and strong insulation epoxy composite materials for solid-state transformers is of great significance to the long-term stable operation of solid-state transformers
[0004] As far as the current research is concerned, the general means to achieve high thermal conductivity is to increase the doping amount of fillers and construct different structures, such as multi-l...

Method used

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  • High-thermal-conductivity strong-insulation epoxy composite material for solid-state transformer under low doping amount and preparation method thereof
  • High-thermal-conductivity strong-insulation epoxy composite material for solid-state transformer under low doping amount and preparation method thereof
  • High-thermal-conductivity strong-insulation epoxy composite material for solid-state transformer under low doping amount and preparation method thereof

Examples

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Effect test

Embodiment 1

[0057] This embodiment provides an epoxy composite material with high thermal conductivity and strong insulation for solid-state transformers and a preparation method thereof. The proportion of nano-boron nitride particles in the filler system is 4.994wt%. (1) First prepare nano-silica-coated boron nitride microparticles and modified nano-boron nitride particles with a core-shell structure:

[0058] Weigh 1 g of micron boron nitride particles and disperse them into 100 ml of absolute ethanol (analytical pure), and add 25 ml of deionized water (analytical pure). Heat in a constant temperature water bath, control the temperature at 35°C, ultrasonically disperse and stir with a magnetic rotor for 45 minutes, and make a crude BN suspension. 12ml ammonia water (NH 3 content between 30% by weight) was added to the BN suspension, and then 0.2ml of TEOS (tetraethylorthosilicate, analytically pure) was added dropwise, and reacted at room temperature for 12 hours. After the reaction, ...

Embodiment 2

[0070] This embodiment provides an epoxy composite material with high thermal conductivity and strong insulation for solid-state transformers and its preparation method. The proportion of nano boron nitride particles in the filler system is 3 wt%.

[0071] (1) First prepare nano-silica-coated boron nitride microparticles and modified nano-boron nitride particles with a core-shell structure:

[0072] Weigh 1 g of micron boron nitride particles and disperse them into 100 ml of absolute ethanol (analytical pure), and add 25 ml of deionized water (analytical pure). Heat in a constant temperature water bath, control the temperature at 20°C, ultrasonically disperse and stir with a magnetic rotor for 60 minutes, and make a crude BN suspension. 12mL ammonia water (NH 3 content between 25% by weight) was added to the BN suspension, and then 0.2 mL of TEOS (tetraethylorthosilicate, analytically pure) was added dropwise, and reacted at room temperature for 14 hours. After the reaction,...

Embodiment 3

[0083] This embodiment provides an epoxy composite material with high thermal conductivity and strong insulation for solid-state transformers and a preparation method thereof. The proportion of nano-boron nitride particles in the filler system is 5 wt%.

[0084] (1) First prepare nano-silica-coated boron nitride microparticles and modified nano-boron nitride particles with a core-shell structure:

[0085] Weigh 1 g of micron boron nitride particles and disperse them into 100 ml of absolute ethanol (analytical pure), and add 25 ml of deionized water (analytical pure). Heat in a constant temperature water bath, control the temperature at 40°C, ultrasonically disperse and stir with a magnetic rotor for 30 minutes, and make a crude BN suspension. 12mL ammonia water (NH 3 content between 20% by weight) was added to the BN suspension, and then 0.2mLTEOS (tetraethyl orthosilicate, analytically pure) was added dropwise, and reacted at room temperature for 15 hours. After the reactio...

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Abstract

The invention discloses a high-thermal-conductivity strong-insulation epoxy composite material for a solid-state transformer under a low doping amount and a preparation method thereof. The preparationmethod comprises the following steps: 1) preparing core-shell structure BN@SiO2 micron particles, and carrying out coupling agent surface modification and ball-milling treatment on nano BN; 2) preparing 100 parts of epoxy resin, 80 parts of a curing agent, 1 part of an accelerant and 20-80 parts of a micro-nano filler system, wherein nano BN accounts for 1-5wt% of the specific gravity of the filler system; (3) mixing the components in the step (2), and carrying out dispersion and defoaming treatment by virtue of an autoroatation and revolution stirrer; and 4) pouring the mixture obtained in the step 3) into a mold, and heating and curing the mixture in a drying box. Through a micro-nano co-doping technology, micron particles adopt a core-shell structure, the surfaces of the nano particlesare modified, and the epoxy-based composite material with excellent electrical and thermal properties can be obtained under the selected co-doping ratio; in addition, the preparation method is simplein step, low in filler doping amount, low in cost and suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of heat-conducting and insulating composite materials, and in particular relates to a high-heat-conducting and strong-insulating epoxy composite material for solid-state transformers with low doping content and a preparation method thereof. Background technique [0002] In recent years, with the increase of power consumption, the load of the power grid has become larger and larger. Power electronic transformers have attracted people's attention because of their huge development potential in distributed power generation systems and new energy power generation. However, in the solid-state transformer part of the power electronic transformer, the hysteresis loss of the iron core, the Joule heat of the coil, and the loss and heat generation of the insulating material itself will cause a local temperature rise of 150-170°C, which will affect the long-term stable operation of the equipment. [0003] As the main in...

Claims

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Application Information

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IPC IPC(8): C08L63/02C08K13/06C08K9/10C08K9/06C08K3/38C08G59/42C08G59/68
CPCC08G59/4215C08G59/686C08K3/38C08K9/06C08K9/10C08K13/06C08K2003/385C08K2201/005C08K2201/011C08K2201/014C08L2203/20C08L63/00
Inventor 邢照亮张翀戴熙瀛刘辉张卓肖雨尹立杨威胡俊鹏刘霆钧程卓林王诗航张闯付航李建英
Owner GLOBAL ENERGY INTERCONNECTION RES INST CO LTD
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