Halogen-free fire-retardant high heat conducting insulating resin composition and heat dissipation metal-base copper clad plate

A technology of insulating resin and high thermal conductivity, which is applied in the direction of epoxy resin glue, metal layered products, synthetic resin layered products, etc., which can solve the problems of poor thermal conductivity, difficult production, and lack of electrical insulation performance Effect of heat resistance and high peel strength

Active Publication Date: 2012-07-11
ALLSTAE TECH ZHONGSHAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, due to the constraints of various factors such as their own technology, equipment, materials and funds, many metal substrate manufacturers use commercialized FR-4 prepreg or FR-4 based copper clad laminates (the thermal conductivity is only 0.3) for their insulating layers. w / m K), there is no thermal conductive filler added to the insulating layer, therefore, the thermal conductivity of this metal-based copper clad laminate is very poor, and it does not have high-strength electrical insulation properties
Ceramic-based copper-clad laminates with high thermal conductivity have high manufacturing costs and difficulty in production, and it is difficult to popularize them for special materials.

Method used

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  • Halogen-free fire-retardant high heat conducting insulating resin composition and heat dissipation metal-base copper clad plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] Halogen-free epoxy resin GESR901 (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 475g / eq) 4 parts by weight, FC Hard XI-1072 (Resinous Kasei Co., Ltd. epoxy equivalent: 253g / eq) 4 parts by weight , GELR128E (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 185g / eq) 3 parts by weight; HyPox RK 84L (CVC ThermosetSpecialties, elastomer content 32 mass%, epoxy equivalent: 1350g / eq) 2 parts by weight; KET4131A70 ( KOLON, epoxy equivalent: 215.5g / eq) 1 weight part; Synthetic rubber 1072CG (Nantex Industry Co., Ltd. acrylonitrile content 27 mass %) 8 weight parts; Diaminodiphenyl sulfone 2 weight parts; 0.05 parts by weight of base-2-ethyl-4-methylimidazole (2E4MZ-CN); 55 parts by weight of aluminum oxide (average particle diameter 2-3 μm, purity more than 99%), nano-alumina (average particle diameter 30nm, purity 99.99%) 20 parts by weight; antioxidant 1010 (CIBAGEIGY Co., Ltd.) 0.1 parts by weight. Put the above components in a sand mill, add methyl ...

Embodiment 2

[0066] Halogen-free epoxy resin GESR901 (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 475g / eq) 4 parts by weight, FC Hard XI-1072 (Resinous Kasei Co., Ltd. epoxy equivalent: 253g / eq) 4 parts by weight , GELR128E (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 185g / eq) 3 parts by weight; HyPox RK 84L (CVC Thermoset Specialties, elastomer content 32 mass%, epoxy equivalent: 1350g / eq) 2 parts by weight, synthetic rubber 4 parts by weight of 1072CG (Nantex Industry Co., Ltd. acrylonitrile content 27 mass %), 4 parts by weight of PPO*MX-90 (phenoxy resin, SABIC INNOVATIVE PLASTICS); 2 parts by weight of diaminodiphenyl sulfone; 1- 0.05 parts by weight of cyanoethyl-2-ethyl-4-methylimidazole (2E4MZ-CN); 55 parts by weight of aluminum oxide (average particle diameter 2-3 μm, purity more than 99%), nano-alumina (average particle diameter 30nm , purity 99.99%) 20 parts by weight; antioxidant 1010 (CIBA GEIGY Co., Ltd.) 0.1 parts by weight. Put the above com...

Embodiment 3

[0069] Halogen-free epoxy resin GESR901 (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 475g / eq) 5 parts by weight, FC Hard XI-1072 (Resinous Kasei Co., Ltd. epoxy equivalent: 253g / eq) 4 parts by weight , GELR128E (Hongchang Electronic Materials Co., Ltd., epoxy equivalent: 185g / eq) 5 parts by weight; HyPox RK 84L (CVC ThermosetSpecialties, elastomer content 32 mass%, epoxy equivalent: 1350g / eq) 7 parts by weight, JER1256 ( Mitsubishi Chemical Corporation, epoxy equivalent: 9052g / eq) 6 parts by weight; diaminodiphenylsulfone 2.5 parts by weight; 1-cyanoethyl-2-ethyl-4-methylimidazole (2E4MZ-CN) 0.05 parts by weight 35 parts by weight of aluminum nitride (average particle diameter 2-3 μm, purity more than 99%), 25 parts by weight of aluminum oxide (average particle diameter 2-3 μm, purity more than 99%); Antioxidant 1010 (CIBA GEIGY Co., Ltd.) 0.1 parts by weight. Put the above components in a sand mill, add methyl ethyl ketone solvent, adjust the solid content of...

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Abstract

The invention discloses a halogen-free fire-retardant high heat conducting insulating resin composition and a heat dissipation metal-base copper clad plate (CCL). The composition comprises the following components in parts by weight: 10-45 parts of halogen-free epoxy resin, 0-15 parts of thermoplastic resin and/or synthetic rubber, 0.1-5 parts of curing agent, 0.02-1 parts of accelerator, 0.5-1 parts of antioxidant and 25-80 parts of heat conducting filler. The halogen-free fire-retardant high heat conducting insulating resin composition of the invention adopts high heat conducting filler, and the cured composition shows good thermal conductivity, electric insulativity and welding heat resistance as well as high adhesive force. The invention also discloses a heat dissipation metal-base CCL prepared by using the above halogen-free fire-retardant high heat conducting insulating resin composition, which has high thermal conductivity and high peel strength, does not have the problems of peel-off and deterioration even being subjected to thermal cycle of quick heating and quick cooling, and also has high electrical breakdown resistance, good heat resistance and soldering resistance and the like, and the flame retardant rating of the heat dissipation metal-base CCL reaches UL-94V0.

Description

technical field [0001] The invention relates to a halogen-free flame-retardant high-thermal-conduction insulating resin composition, and the invention also relates to a heat-dissipating metal-based copper-clad board made of the halogen-free flame-retardant high-thermal-conduction insulating resin composition. Background technique [0002] With the rapid development of the electronics industry, the size of electronic products is getting smaller and smaller, and the power density is getting higher and higher. Solving the problem of heat dissipation is a huge challenge for the design of the electronics industry. Metal-based copper clad laminate is undoubtedly one of the effective means to solve the problem of heat dissipation. Metal-based copper clad laminate is a copper clad laminate with good heat dissipation function. It is composed of a unique three-layer structure, which are circuit layer, thermal insulation layer and metal base layer. The working principle of the metal-b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L67/00C08L33/00C08L71/12C08L79/08C08L9/02C08K13/02C09J163/00B32B15/092B32B27/18
Inventor 李国法陈庞英张家骥刘沛然
Owner ALLSTAE TECH ZHONGSHAN
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