Super-high thermal conductivity and low thermal expansivity diamond composite material and preparation method thereof

A low thermal expansion coefficient, composite material technology, applied in the field of high-performance electronic packaging functional materials, can solve problems such as poor surface finish, surface finish requirements require plating or polishing, etc., to achieve weight reduction, good heat dissipation, and improved thermal conductivity Effect

Inactive Publication Date: 2011-03-16
UNIV OF SCI & TECH BEIJING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The Lawrence Livermore National Laboratory of the United States and Sun Microsystems developed a diamond-copper composite material as early as 1995, called Dymalloy [2] , the volume fraction of type I diamond is 55%, the diamond powder coated with metal on the surface is put into the mold for compaction, and then the copper alloy is infiltrated in vacuum, the thermal conductivity of the prepared composite material reaches 420W / m·k, and the material has a certain Plastic, easy to process, but because of the near net forming process, the surface finish is poor, if there is a requirement for surface finish, it needs to be plated or polished

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Raw materials: diamond powder particles with a particle size of 50-60 μm and pure copper blocks (industrial pure copper, purity > 99.5%).

[0024] Put the diamond powder of the above particle size into a metal cup, and put a pure copper sheet on the diamond powder. The metal cup filled with materials is then put on two metal cups in opposite directions. Then put the assembled kit into a vacuum furnace at 550°C, 5×10 -2 Vacuum treatment was carried out under vacuum for 2 hours. Then put the assembly kit into the equipment for high-pressure synthesis, and carry out ultra-high-pressure infiltration sintering. The sintering process is as follows: the temperature is raised to about 1100°C and a pressure of 5.3GPa is applied, and the temperature is kept for 10 minutes, and the sintering is completed. After cooling, take out the sample, remove the mold, cut off the remaining copper infiltrated, and process the sample into the required size (φ10×3mm), that is, the diamond / Cu ...

Embodiment 2

[0026] Raw materials: diamond particles and pure copper blocks with a particle size of 180-212 μm.

[0027] The diamond raw material powder with the above-mentioned particle size and the copper sheet are assembled into a kit for ultra-high pressure infiltration sintering. The specific process is the same as that of Experiment 1. The prepared diamond / Cu composite has a thermal conductivity of 683W / mK and a density of 3.96g / cm 3 , The coefficient of thermal expansion is 2.31ppm / K.

Embodiment 3

[0029] Raw materials: diamond particles and pure copper blocks with a particle size of 500-600 μm.

[0030] The diamond raw material powder with the above-mentioned particle size and pure copper sheet were assembled into a kit for ultra-high pressure infiltration and sintering. The specific process was the same as that in Experiment 1. The prepared diamond / Cu composite has a thermal conductivity of 717W / mK and a density of 3.91g / cm 3 , The coefficient of thermal expansion is 2.16ppm / K.

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Abstract

The invention discloses a super-high thermal conductivity and low thermal expansivity diamond composite material and a preparation method thereof, and belongs to the field of high-performance functional materials. The composite material consists of at least two phases of high thermal conductivity diamond grains and high thermal conductivity metals or alloy materials. The preparation method for the composite material comprises the following steps of: putting high thermal conductivity sheet or block metals or alloy materials on the high thermal conductivity diamond powder grains, loading, sealing, performing vacuum heat treatment, and performing melt infiltration sintering at certain high temperature under high pressure to make high thermal conductivity metals melted and infiltrated in the diamond grains so as to form the super-high thermal conductivity and low thermal expansivity composite material. The method makes high thermal conductivity nonmetal materials and high thermal conductivity metal materials firmly combined, so the composite material has the compactness of over 99 percent, and the thermal conductivity of 600 to 800W/(m.K); the thermal expansivity (less than 5ppm/K) matched with an electronic device can ensure that a workpiece works stably for a long time under the condition of high heating density; and the composite material has wide industrial application prospect.

Description

technical field [0001] The invention belongs to the field of high-performance electronic packaging functional materials, and in particular provides a diamond-reinforced metal composite material with ultra-high thermal conductivity and low thermal expansion coefficient and a preparation method thereof. Background technique [0002] The high power density devices used in communication satellites and the plasma materials used in nuclear fusion devices will generate and accumulate a large amount of heat during operation. High demands were made. Many electronic components of aerospace vehicles need to work normally at an ambient temperature of 40-60°C, so the heat generated during the operation of the instrument must be discharged in time. One of the primary problems brought about by the improvement of chip integration and packaging density is that the unit power of the device continues to increase, and the heat generation continues to increase, which makes the working environme...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/05C22C9/00
Inventor 贾成厂陈惠李尚劼
Owner UNIV OF SCI & TECH BEIJING
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