6results about How to "Mild response" patented technology

This invention belongs to the field of hollow multi-component nanomaterial preparation technology, specifically disclosing a hollow Cu3NbSe4 nanomaterial, its preparation method, and its application. The microstructure of the nanomaterial is a nanoscale hollow cubic structure. The preparation method includes: (1) dissolving niobium source and selenium source separately in oleylamine solvent by heating for later use; (2) treating the soluble copper source and the niobium source dissolved in (1) in a high-boiling-point organic solvent for deoxygenation and dehydration, and then carrying out a solvothermal reaction; (3) when (2) is heated to a certain temperature, injecting the selenium source dissolved in (1) to carry out a solvothermal reaction, and separating the obtained solid product after the reaction is completed. The synthesis process of this invention is simple, the reaction conditions are mild, and the energy consumption and cost are low; more importantly, it realizes the preparation of hollow Cu3NbSe4 nanomaterial with uniform morphology and size, high crystallinity, and stronger light absorption capacity, and the prepared hollow Cu3NbSe4 shows excellent performance in photocatalytic hydrogen production.

The application discloses a preparation method of 2,4-dichlorophenoxyacetic acid synthesized by composite molecular sieve ZSM-5 and a water-reducing process, and relates to the following steps: under alkaline conditions, 2,4-dichlorophenol is reacted with a sodium chloroacetate solution under the catalysis of a composite molecular sieve catalyst to obtain 2,4-dichlorophenoxyacetic acid sodium salt crude product through condensation; and then hydrolysis and hydrochloric acid acidification are carried out to obtain 2,4-dichlorophenoxyacetic acid product. The process can reduce energy consumption, shorten reaction time and reduce production cost in obtaining 2,4-dichlorophenoxyacetic acid, and can improve the conversion rate and yield of the product and the color of the product. When a new batch of 2,4-dichlorophenoxyacetic acid sodium salt crude product is dissolved in the acidification reaction, the washing water of the last batch of 2,4-dichlorophenoxyacetic acid is used as the solvent reaction liquid, and the washing water of the last batch is used for the first water washing of the final product and is used in turn. The water consumption is reduced, the wastewater treatment cost is reduced, the conversion rate and yield of the product are improved, the product has high purity, the process is simple, the conditions are mild, and the raw materials can be recycled.

The present application belongs to zinc-nickel alloy plating layer, and particularly relates to an alkaline stripping solution for removing unqualified zinc-nickel alloy plating layer, a preparation method and application thereof. In order to safely and efficiently remove unqualified zinc-nickel alloy plating layer, the present application provides an alkaline stripping solution, which is composed of the following components in terms of mass concentration: main salt: NaOH 100-180 g / L; oxidizing agent: sodium nitrate 180-200 g / L and NaClO 10-20 g / L; complexing agent: salicylaldehyde oxime 30-50 g / L and diethylene triamine 30-50 g / L; corrosion inhibitor: 2-acetylpyrrole or 4-piperidine carboxamide 2-10 g / L; wetting agent: sodium dodecyl sulfate 0.5-1.5 g / L. After the components in the alkaline stripping solution are mixed in proportion, the alkaline stripping solution can be directly used for removing unqualified zinc-nickel alloy plating layer, the stripping rate reaches 0.6-1 um / min, and the stripping temperature range is wide without damaging the substrate.

This invention relates to the technical field of polymers, and more particularly to a long-chain branched poly(4-methyl-1-pentene), its preparation method, and its applications. The general structural formula of the long-chain branched poly(4-methyl-1-pentene) is shown in Formula I: where R is selected from C1-C8 alkyl groups, m is selected from natural numbers 2-10, and n is selected from natural numbers 0-50. A comonomer is obtained by reacting raw materials including α,ω-non-conjugated dienes and organosiloxane monomers; the comonomer is then polymerized with 4-methyl-1-pentene to obtain the long-chain branched poly(4-methyl-1-pentene). The preparation method is simple, the reaction is mild, the comonomer conversion rate is high, no complicated pretreatment or post-treatment processes are required, and conventional Ziegler-Natta catalysts can meet the requirements, showing broad prospects for industrial production. The selected raw materials are all commonly used in industry, and no special raw materials are required, ensuring cost-effectiveness and suitability for industrial applications.