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310results about How to "Little pollution" patented technology

Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor

The invention relates to a manufacturing domain of nanopowder composite, especially to a nano antibacterial powder coating and one-step manufacturing method of microsuspension. The nano antibacterial powder coating consists of water, mixture monomer, pigment, surface processing agent, nanometre-sized inorganic antiseptic particle and auxiliary agent. The method comprises dispersing components such as water and suspending disperser by ultra-audio wave, then performing dispersion by high-shear emulsifier to prepare the predispersion; afterwards, adding the other components into polymerization kettle according to priority, after agitation and heating, adding the said predispersion at one time, reacting at a constant temperature, then cooling, discharge, centrifugally dewatering and drying to obtain the product. The invention solves the problems that the nanoparticles are easy to aggregate inside the organic polymer existed in present technology and the manufacturing engineering of the traditional powder coating is difficult, and has advantages that the process flow is short, the equipment investment is low, and can save working hours and energy resource, is of no dust pollution, the prepared powder coating particles is of regular shape, and has better levelling property in application.
Owner:HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY

Preparation method of 2-chloronicotinic acid

The invention discloses a preparation process for 2-Chloronicotinic acid. In the prior art, the disadvantage is that the overdosed catalyzer is used and has a bad effect, the oxidation yields are very low; during the chlorination reaction, POCl3 can make chloro-substitutions on a plurality of positions of nicolinamide- N- oxido, which leads to that the chloro-substitution products on 2-position have low yields. In the invention, with the existence of acetyl pyruvic molybdenum, the 3-Pyridinecarbonitrile takes water as the solvent and is dripped in 20 to 30 percent of H2O2, and then is made a heat preservation to realize a full oxidation reaction; under the anhydrous reaction and with the positive pressure protection of nitrogen, the acquired nicolinamide- N- oxido is cooled between minus 10 and 10 DEG C to be diluted by the halohydrocarbon solvent, and then is dripped in the organic base, and is reacted with the chlorination reagent under the action of phenyl dichlorophosphate; the strong alkaline solution is used to make a dehydration reaction with the acquired 2-chloro-3-cyanopyridine. The invention takes the acetyl pyruvic molybdenum as the catalyzer and oxidizer, has high oxidation yields; adopts the organic base as the acid-binding agent, makes chloro-substitutions between the chlorination reagent and the nicolinamide- N- oxido, and has above 85 percent of chloro-substitution yields.
Owner:ZHEJIANG MEDICINE CO LTD XINCHANG PHAMACEUTICAL FACTORY

High-concentration wastewater zero-discharging method

ActiveCN105198143ARealize in-depth treatment and even zero discharge problemsEfficient reverse osmosis treatmentEnergy based wastewater treatmentMultistage water/sewage treatmentHigh concentrationReverse osmosis
The invention relates to the field of industrial wastewater treatment, in particular to a high-concentration wastewater zero-discharging method. Accoridng to the method, a 'nanofiltration + efficient reverse osmosis + membrane distillation + evaporative crystallization' method is adopted to treat high-concentration wastewater. Firstly, nanofiltration is adopted to remove hardness, multivalent ions and parts of organic matter in the high-concentration wastewater so as to obtain nanofiltration producing water and nanofiltration concentrated water, then an efficient reverse osmosis technology is adopted to conduct deep concentration treatment on the nanofiltration producing water, deep concentration treatment is conducted on the obtained efficient reverse osmosis concentrated water through membrane distillation to obtain membrane-distillation concentrated water, further evaporative crystallization treatment is performed to enable salt solids in the membrane-distillation concentrated water to crystallize out, and centralized drying disposal is performed, wherein salt is added into the nanofiltration concentrated water to perform precipitation treatment so as to obtain calcium residues, supernate obtained after precipitation is subjected to activated carbon adsorption and then is mixed with the high-concentration wastewater, and the mixed liquid is fed into a nanofiltration unit for circular treatment. By means of the high-concentration wastewater zero-discharging method, water resources are recycled to the most degree while the problem of high-concentration wastewater discharging is solved, and zero discharging of high-concentration wastewater is basically achieved.
Owner:CHINA PETROLEUM & CHEM CORP +1

Nano composite powder coatings and dispersion polymerization preparation method thereof

The present invention relates to the field of nano-powder composite material preparation, in particular to a composite nano-powder coating and a preparation method adopting dispersion polymerization thereof. The ingredients used to prepare the nano-powder coating include water, alcohol, monomer mixture, inorganic nano-particles, pigment filler and assistant. Surface treatment is first carried out on the nano-particles and the pigment filler, which are then added into the monomer mixture and dispersed by ultrasonic so that mixed solution is produced. Then, the mixed solution is added into alcohol-water mixed solution containing dispersion stabilizer and dispersed by ultrasonic, and after six hours of temperature reaction, the product undergoes centrifugation and vacuum drying so that the final product is prepared. The present invention resolves the defects of the prior art, including large powder particle diameter, uneasy scumbling and uneven coating, and avoids the problems of the complexity of the traditional preparation technique and the easy agglomeration of nano-particles in organic polymers. The preparation method adopting dispersion polymerization has the advantages of short process flow, little investment, energy saving, no powder pollution, etc.; the prepared powder coating is characterized by neat particle shape, small particle diameter and easy scumbling and has functions such as antibacterial function and ultraviolet-resisting function; the powder coating in use has good leveling property.
Owner:HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY

Forward osmosis coupled membrane distillation wastewater treatment apparatus and method thereof

The invention provides a forward osmosis coupled membrane distillation wastewater treatment apparatus and a method thereof. The apparatus includes a first stage forward osmosis unit or a second stage forward osmosis unit and a membrane distillation unit. The above forward osmosis unit is composed of a forward osmosis raw water pool, a forward osmosis raw water pump, a forward osmosis membrane module, a forward osmosis driving liquid pool and a forward osmosis driving liquid pump; the membrane distillation unit is composed of a membrane distillation thick water raw water pool, a membrane distillation thick water pump, membrane distillation, a membrane distillation water heating pool, a membrane distillation thick water raw water pump, a membrane distillation water feeding pump and a membrane distillation assembly; and the forward osmosis unit is connected with the membrane distillation unit through a pipeline and a valve. The method comprises the following steps: high salinity wastewater treated by the membrane distillation unit is used as a forward osmosis driving liquid, membrane distillation thick water is diluted through continuous concentration of forward osmosis feeding liquid side raw water, the diluted membrane distillation thick water returns to the membrane distillation unit and is continuously treated, and above steps are cycled. The apparatus and the method effectively solve the treatment problem of the membrane distillation thick water, and maximally recover the water resource in the wastewater.
Owner:CHINA PETROLEUM & CHEM CORP +1

Dynamic membrane automatic water flow-out solid-liquid separation method applicable to domestic sewage treatment

The invention provides a dynamic membrane automatic water flow-out solid-liquid separation method applicable to domestic sewage treatment. The method includes: adding powder particles with fine water permeable performance into activated sludge to form biological intensified powder mixed liquid to structurally improve the activated sludge; combining with the dynamic membrane separation technique to greatly improve the filtering capacity and water permeability of dynamic membrane filter cakes; performing solid-liquid separation of discharged water by allowing a dynamic membrane component to be driven by a water head having lower fixed gravity action and formed by liquid level waterhead between the upper liquid level of the immersed dynamic membrane component in a reaction device and a wateroutlet, stably controlling the unit area membrane filter flux of the dynamic membrane component to be more than 20-60L / m2h and the continuous operating time to be longer than 120h without action of external power; and allowing the dynamic membrane to completely shed with the air backwashing time being 1min-2min and the air inlet pressure being 9.8-49kPa. The dynamic membrane component does not need to be chemically cleaned regularly, and control and operation of the method can be automatically controlled in the whole process. The dynamic membrane solid-liquid separation technique can realize automatic water flowing out under differential pressure of low-liquid-level waterhead, energy consumption is greatly reduced, operation process is simplified, and discharged water is high in quality.
Owner:TONGJI UNIV

Vanadium pentoxide extraction method by direct acid dipping of stone coal ash containing vanadium

The invention provides a method for extracting vanadic oxide from vanadiferous stone coal ash slag through direct acid leaching. The method comprises the following steps: an acid leaching solution obtained by the vanadiferous stone coal ash slag through direct acid leaching is added with ammonium sulphate to prepare tschermigite as a byproduct; a vanadiferous mother solution is added with an iron simple substance and is heated, evaporated, condensed and crystallized to form an intermediate salt crystal in order that vanadium is fully enriched in intermediate salt; the intermediate salt is dissolved to prepare an extractive stock solution; the extractive stock solution is subjected to extraction, back extraction, oxidation and vanadium precipitation to prepare ammonium ployvanadate; and the ammonium ployvanadate is subjected to pyrolysis and deamination to prepare a V2O5 product with purity of over 98 percent. The process is wholly operated in a liquid phase and has no pollution by exhaust gas; waste liquid is basically returned to a system for reclaiming and utilization; the discharged waste liquid is little and is easy to treat; the total reclaiming rate of vanadium can reach over 75 percent; simultaneously, aluminum resource in the ash slag can be reclaimed to form the tschermigite as the byproduct; and the yield of the byproduct can reach dozens to hundreds of times of the yield of the V2O5 product. The process has the advantages of good operating condition, high mechanization and automation degree, high resource utilization rate, low comprehensive cost, good benefit and light pollution.
Owner:ZHEJIANG UNIV +1

Methods for edulcoration and desalinization of 1,3-methyl glycol fermentation liquor

ActiveCN101117306ASolve the problem of membrane foulingSolve technical problems such as flow channel blockageHydroxy compound separation/purificationLoss rateDistillation
An impurity removing and desalting method for 1, 3-propanediol zymotic fluid relates to a 1, 3-propanediol zymotic fluid, which provides the An impurity removing and desalting method for 1, 3-propanediol zymotic fluid. Micro filtering impurity removing is that the 1, 3-propanediol zymotic fluid with germ is preprocessed by a filtering bag and enters a ceramics film device micro for micro filtering impurity removing. The germ body and protein macromolecular matter are removed from zymotic fluid to get the zymotic filter fluid of the 1, 3-propanediol. The salt removing by electrodialysis is that zymotic filter fluid containing the 1, 3-propanediol is put into an electrodialysis device to remove salt and completes when filtrate conductance is reduced to 2000 us. Therefore, the electrodialysis operation is stopped. The filter fluid enters the following technics for condensation and purification. The invention has a bigger film flux, a good treating effect and light ion exchanging film pollution. The salt removing by electrodialysis has low energy consumption and good treating effect. The conductance of material liquid can be completely reduced to 2000 us to satisfy techincs demand of following concentration and distillation. The loss rate of the 1, 3-propanediol is low with little environment pollution.
Owner:SUNTAR MEMBRANE ENVIRONMENT TECH +1

Method for separating and purifying cisatracurium besylate by preparative liquid chromatography

The invention discloses a method for separating and purifying cis-benzene sulfonic acid atracurium through preparative liquid chromatography, which is to use a mobile phase to dissolve benzene sulfonic acid atracurium, load the benzene sulfonic acid atracurium on a preparative liquid-phase chromatographic silica gel column, perform normal-phase or opposite-phase liquid-phase chromatographic separation under the elution of the mobile phase, and reclaim the cis-benzene sulfonic acid atracuriums, wherein immobile-phase silica gel is modified bonded silica gel, and the particle diameter of the immobile-phase silica gel is between 1 and 200 micrometers; the load ratio of the immobile-phase silica gel to atracurium is not more than 1,000; and the pressure of the silica gel column is between 250 and 400 psi. The cis-benzene sulfonic acid atracurium obtained by the method has high purity, high yield and low cost; the amount of an organic solvent used is low; the pollution is light; and the maneuverability is strong. The treatment time of the method is shortened by approximately 10 times compared with the prior art, and simultaneously the method can feed samples continuously, realize automatic operation and the like.
Owner:SHANGHAI PHARMA DONGYING JIANGSU PHARMA CO LTD

Method and technology for high-value comprehensive utilization of banana stems and leaves

The invention provides a comprehensive utilization method of banana stem and leaf resources. The method adopts banana stems and leaves as raw materials to successively produce tannic acid, pectin, paper pulp fibers, fuel ethanol, and yeast fodder. The method comprises the steps of: adopting banana stems and leaves as the raw materials, crushing the banana stems and leaves into a slurry form by beating via an extractant, and extracting tannin via an extracting liquid while pulping; subjecting the rest banana stem and leave slurry to acidolysis, and extracting pectin of the banana stems and leaves by stewing the banana stem and leave slurry at a normal pressure; and subjecting the remaining slurry to acidolysis, and degrading polysaccharide, starch and the other degradable substances into soluble degraded sugars by stewing at a high temperature and a high pressure, wherein the degraded sugars and reducing sugar of the banana stems and leaves constitute a soluble substance aqueous solution, so that a separation of cellulose from degradable substances is realized. The method provided by the invention can share the comprehensive utilization cost of banana stems and leaves, and can greatly increase the utilization efficiency of banana stem and leaf resources.
Owner:HAINAN BEIOU BIOENERGY DEV
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