Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof
A technology of epoxy acrylate and dispersion, applied in coating, latex paint, etc., can solve the problems of unsatisfactory adhesion, poor promotion and application, and easy powdering of coating film.
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Embodiment 1
[0072] The specific steps of the preparation process of the self-made organosilicon epoxy acrylate aqueous dispersion in the present invention are as follows:
[0073] (1) In the reaction kettle, add the fatty acid in the formula amount, stir and heat up to 110-130°C, stop stirring, add the epoxy resin and catalyst in the formula amount, start stirring, continue to heat up to 200-240°C; Esterification reaction, until the acid value reaches 6-10mgKOH / g, and the viscosity (gauge tube 25°C) reaches 8-10s, the esterification reaction is completed;
[0074] (2) When the reaction temperature is lowered to 160-180°C, stop stirring, add the unsaturated acid anhydride in the formula, start stirring, and raise the temperature to 2-4°C / min (please give the range value to avoid point value). 230~250℃, then keep warm for 0.5~1 hour;
[0075] (3) Cool down to 100-120°C, start to drop the pre-mixed acrylic monomer, silane coupling agent and initiator in the formulated amount for 2-3 ...
Embodiment 2
1000
[0089] The preparation process of the silicone epoxy acrylate water dispersion in this example is the same as that in Example 1.
[0090] The preparation method of this water-based industrial paint is:
[0091] (1) Add the prescribed amount of deionized water, BYK-P104, Tego Wet KL245, and 1 / 3 of BYK-022 into the dispersion kettle, and stir for 15 minutes at a speed of 1000rpm to make the materials evenly mixed.
[0092] (2) Add the silicone epoxy acrylate aqueous dispersion with a formula amount of 1 / 2, and stir at a speed of 400 rpm for 20 minutes to mix the materials evenly.
[0093] (3) Add iron oxide red, aluminum tripolyphosphate, WD-D-500 composite iron-titanium antirust pigment, talcum powder, barium sulfate, and 1 / 3 BYK-022 in the prescribed amount in turn, and stir at 600rpm for 1.5 hours to mix the material evenly.
[0094] (4) Grinding the above slurry by a sand mill until the fineness is ≤30 μm.
[0095] (5) Add the remaining silicone acrylate...
Embodiment 3
[0101] components
[0102] BYK-022
[0103] The preparation process of the silicone epoxy acrylate water dispersion in this example is the same as that in Example 1.
[0104] The preparation method of this water-based industrial paint is:
[0105] (1) Add the prescribed amount of deionized water, BYK-P104, Tego Wet KL245, and 1 / 3 of BYK-022 into the dispersing kettle, and stir at 950rpm for 30 minutes to make the materials mix evenly.
[0106] (2) Add the silicone epoxy acrylate aqueous dispersion with a formula amount of 1 / 2, and stir at a speed of 500 rpm for 20 minutes to make the materials evenly mixed.
[0107] (3) Add iron oxide red, aluminum tripolyphosphate, WD-D-500 type composite iron-titanium antirust pigment, talcum powder, barium sulfate, and 1 / 3 BYK-022 in sequence, and stir at 700 rpm for 1 hours to mix the material evenly.
[0108] (4) Grinding the above slurry by a sand mill until the fineness is ≤30 μm.
[0109] (5) Add the remaining si...
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