Water industrial paint based on organosilicon acrylic acid epoxy ester water dispersion and preparation method thereof

A technology of epoxy acrylate and dispersion, applied in coating, latex paint, etc., can solve the problems of unsatisfactory adhesion, poor promotion and application, and easy powdering of coating film.

Inactive Publication Date: 2007-03-14
广州市允升环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are also some patent announcements in water-based metal coatings, such as the disclosed coatings of patents CN1255935A, CN 1055747A, etc., the formed coating film is either easy to pulverize, has poor weather resistance, or has unsatisfactory adhesion, or cannot be crosslinked at room temperature, resulting in The compactness of the coating film is poor, so the promotion and application status is not good
U.S. Patent US6172159 has prepared a kind of water-based polyester resin, and is directly coated on the water-based paint of metal with it as base material, but this water-based paint can only be used as primer, and is not suitable for as topcoat; Patent US5770657 Although the water-based epoxy-amine curing system provided and the water-based polyurethane system prepared by the patent US6395820 have high comprehensive performance, they are all two-component water-based coatings with a short pot life and inconvenient transportation and construction; therefore, At present, it is still necessary to develop high-performance waterborne metal industrial coatings that can be cured at room temperature with good durability, flash corrosion resistance, excellent wet adhesion, and low water vapor and oxygen transmission rates.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0072] The specific steps of the preparation process of the self-made organosilicon epoxy acrylate aqueous dispersion in the present invention are as follows:

[0073] (1) In the reaction kettle, add the fatty acid in the formula amount, stir and heat up to 110-130°C, stop stirring, add the epoxy resin and catalyst in the formula amount, start stirring, continue to heat up to 200-240°C; Esterification reaction, until the acid value reaches 6-10mgKOH / g, and the viscosity (gauge tube 25°C) reaches 8-10s, the esterification reaction is completed;

[0074] (2) When the reaction temperature is lowered to 160-180°C, stop stirring, add the unsaturated acid anhydride in the formula, start stirring, and raise the temperature to 2-4°C / min (please give the range value to avoid point value). 230~250℃, then keep warm for 0.5~1 hour;

[0075] (3) Cool down to 100-120°C, start to drop the pre-mixed acrylic monomer, silane coupling agent and initiator in the formulated amount for 2-3 ...

Embodiment 2

1000

[0089] The preparation process of the silicone epoxy acrylate water dispersion in this example is the same as that in Example 1.

[0090] The preparation method of this water-based industrial paint is:

[0091] (1) Add the prescribed amount of deionized water, BYK-P104, Tego Wet KL245, and 1 / 3 of BYK-022 into the dispersion kettle, and stir for 15 minutes at a speed of 1000rpm to make the materials evenly mixed.

[0092] (2) Add the silicone epoxy acrylate aqueous dispersion with a formula amount of 1 / 2, and stir at a speed of 400 rpm for 20 minutes to mix the materials evenly.

[0093] (3) Add iron oxide red, aluminum tripolyphosphate, WD-D-500 composite iron-titanium antirust pigment, talcum powder, barium sulfate, and 1 / 3 BYK-022 in the prescribed amount in turn, and stir at 600rpm for 1.5 hours to mix the material evenly.

[0094] (4) Grinding the above slurry by a sand mill until the fineness is ≤30 μm.

[0095] (5) Add the remaining silicone acrylate...

Embodiment 3

[0101] components

[0102] BYK-022

[0103] The preparation process of the silicone epoxy acrylate water dispersion in this example is the same as that in Example 1.

[0104] The preparation method of this water-based industrial paint is:

[0105] (1) Add the prescribed amount of deionized water, BYK-P104, Tego Wet KL245, and 1 / 3 of BYK-022 into the dispersing kettle, and stir at 950rpm for 30 minutes to make the materials mix evenly.

[0106] (2) Add the silicone epoxy acrylate aqueous dispersion with a formula amount of 1 / 2, and stir at a speed of 500 rpm for 20 minutes to make the materials evenly mixed.

[0107] (3) Add iron oxide red, aluminum tripolyphosphate, WD-D-500 type composite iron-titanium antirust pigment, talcum powder, barium sulfate, and 1 / 3 BYK-022 in sequence, and stir at 700 rpm for 1 hours to mix the material evenly.

[0108] (4) Grinding the above slurry by a sand mill until the fineness is ≤30 μm.

[0109] (5) Add the remaining si...

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Abstract

The present invention provides one kind of water thinned industrial paint based on water dispersed organosilicon epoxy acrylate. The water thinned industrial paint is prepared with water dispersed organosilicon epoxy acrylate, inert antirust pigment, active antirust pigment, nanometer material modified antirust pigment, stuffing, dispersant, wetting agent, thickener, drying agent, mildew inhibitor, preservative, defoaming agent, deionized water and other materials. The water thinned industrial paint with water dispersed organosilicon epoxy acrylate as base material can form coating with the features of high mechanical strength and high anticorrosive performance similar to that of epoxy resin as well as the features of high weather resistance and good decoration performance like acrylate resin. The water thinned industrial paint has convenient use and wide application range.

Description

technical field [0001] The invention relates to water-based industrial paint technology, in particular to a water-based industrial paint based on a silicone acrylate epoxy ester aqueous dispersion and a preparation method thereof. Background technique [0002] According to statistics, the annual corroded and rusted metals in the world account for more than 20% of the annual output, which brings huge economic losses to the world. The annual economic loss caused by metal corrosion in my country accounts for about 4% of the gross national product, exceeding the sum of the losses caused by fire, wind disaster and earthquake. Using paint to prevent metal corrosion is the simplest, most economical and most effective method. However, most of the current metal protective coatings are solvent-based coatings, in which the volatile organic compound content (VOC) is about 50%, which will evaporate during production and construction, causing harm to the environ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D151/00C09D5/25C09D5/02C08F285/00
Inventor 英志祥
Owner 广州市允升环保科技有限公司
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