2083 results about "Ethylenediamines" patented technology

The invention discloses a CO2 trapping absorbent which comprises 20%-50% of proton type ionic liquid, 20%-50% of a phase conversion driving agent and 20%-40% of water, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine, tetramethylenediamine, tetramethylethylenediamine and dimethyl piperazine, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine and dimethyl piperazine. The absorbent disclosed by the invention has the outstanding advantages of low viscosity, high absorption rate, high regeneration efficiency, high circulation capacity and low regeneration energy consumption, and has a good application prospect.

The invention discloses an absorbable suture line for surgical suture and a preparation method thereof, and relates to the technical field of medical materials. The absorbable suture line for surgical suture is prepared from the following raw materials in parts by weight: 50 to 65 parts of polylactic acid, 15 to 20 parts of polyglycolic acid, 3 to 5 parts of sodium carboxymethyl cellulose, 3 to 8 parts of a toughening agent, 3 to 6 parts of an antibacterial agent, 0.3 to 0.8 part of a lubricating agent, 1 to 2 parts of sodium hyaluronate and 5 to 10 parts of polyvinyl alcohol. The toughening agent is obtained by reacting hydroxyethyl acrylate with ethylenediamine to generate a four-arm compound and then reacting with 6-caprolactone and DL-lactide. The absorbable suture line for surgical suture prepared by the invention has excellent tensile property and antibacterial property, and can meet the application requirements of clinical medical treatment.

The invention belongs to the field of electroplating, and particularly relates to a platinum electroplating solution, a preparation method thereof and application of the platinum electroplating solution in wafer electroplating. The platinum electroplating solution comprises the following components: a platinum salt which is 0.02 mol / L in terms of platinum (II); the platinum salt is ethylenediamine platinum chloride (II) or ethylenediamine platinum iodide (II); the concentration of the complexing agent is 0.16 to 0.46 mol / L; the complex is a linear molecule with amino groups at two ends or 1, 2-diaminocyclohexane; the carbon number n between two amino groups of a linear molecule with amino groups at two ends is selected from 2, 3 and 4; the concentration of the electrolytic salt is 0.13-0.53 mol / L, and the electrolytic salt comprises carboxylic acid ammonium salt or ammonium sulfate salt; the pH regulator is used for regulating the pH of the platinum electroplating solution to 7; the solvent is ultrapure water. The platinum plating layer formed by the method has excellent morphology, uniform distribution, high purity and excellent compactness, and the produced wafer electronic product has excellent corrosion resistance, high-precision conductivity and high-quality electronic signal transmission performance.

The invention discloses preparation and application of a block cationic copolymer / quaternary ammonium salt chitosan-based composite hydrogel. The preparation method comprises the following steps: reacting a sodium alginate solution with a NaIO4 solution at room temperature in a dark place to obtain an oxidized sodium alginate solution; adding ethylene glycol into the oxidized sodium alginate solution, reacting, concentrating, dialyzing and drying to obtain oxidized sodium alginate; the preparation method comprises the following steps: mixing acrylamide, 1-butyl-3-vinyl imidazole ammonium bromide, 3-acrylamide phenylboronic acid and quaternary ammonium salt chitosan, dissolving in water, adding ammonium persulfate and N, N-methylene bisacrylamide, heating for reaction, and cooling to obtain a cooling liquid; adding the oxidized sodium alginate solution into the cooling liquid, continuously adding polymerized N, N, N ', N'-tetramethylethylenediamine, reacting and curing to obtain composite hydrogel; and soaking the composite hydrogel in a glycerin / water mixed solution to obtain the composite hydrogel. When the composite hydrogel is used as a wound dressing, the composite hydrogel has the characteristics of good antibacterial activity, high sterilization efficiency, good anti-freezing and anti-drying performance and difficulty in generating drug resistance.

The invention discloses an organic amine composite absorbent for carbon capture and application thereof, and belongs to the technical field of carbon dioxide capture, the organic amine composite absorbent for carbon capture is in a solution state and comprises the following components: a main agent, an auxiliary agent, an accelerant A, an accelerant B and water; wherein the mass ratio of the main agent to the auxiliary agent is 2: (1-2); the mass ratio of the auxiliary agent to the accelerant A is 2: (1-2); the mass ratio of the accelerant A to the accelerant B is 2: (1-2); the total mass concentration of the main agent, the auxiliary agent, the accelerant A and the accelerant B in the organic amine composite absorbent for carbon capture is 30-40 wt%; the main agent is selected from N-methyldiethanolamine or N, N-diethyl ethanolamine, the auxiliary agent is selected from piperazine or hydroxyethyl ethylenediamine, the accelerant A is selected from triethylene glycol monomethyl ether and / or ethylene glycol monomethyl ether, and the accelerant B is selected from ethyl butyl ether and / or isobutyl ether. The organic amine composite absorbent for carbon capture has a wide application prospect in removal of carbon dioxide in flue gas.

The invention discloses a preparation method of an In2O3-Cu-Cu2O ternary heterojunction catalyst and a preparation method of the In2O3-Cu-Cu2O ternary heterojunction catalyst. The method comprises the following steps: at room temperature and normal pressure, firstly, dissolving indium chloride tetrahydrate in a mixed solvent of ethylenediamine-ethylene glycol (the volume ratio is 1: 20-1: 30) and dihydric alcohol amine to obtain a homogeneous solution; then transferring the solution to a hydrothermal kettle, adding deionized water and Cu2O powder with different volumes, and carrying out hydrothermal crystallization at 160-200 DEG C for 10-14 hours; and centrifuging the obtained precipitate, alternately washing with water and alcohol for 2-3 times, carrying out vacuum drying at 60 DEG C for 5-7 hours, heating to 600 + / -10 DEG C at a speed of 3-5 DEG C / min in an N2 atmosphere, calcining for 3 hours, and cooling along with a furnace to obtain a target product. By adjusting the adding amount of the deionized water, the mass proportion of the three phases of In2O3, Cu and Cu2O can be continuously adjusted and controlled, and controllable preparation from'rich copper 'to'rich cuprous oxide' and'stable ternary 'is achieved.

The invention discloses a high-stability iron-cerium flow battery and a preparation method of electrolyte, and belongs to the technical field of flow batteries. A positive electrolyte and a negative electrolyte are cerium salt and ferric salt, and are respectively mixed with nitrilotriacetic acid, ethylenediamine tetraacetic acid, trans-1, 2-cyclohexanediamine tetraacetic acid, 1, 3-propane diamine tetraacetic acid, N-(2-ethoxyl) ethylenediamine-N, N ', N'-triacetic acid, iminodiacetic acid, iminodisuccinic acid, succinic acid, N, N '-bis (2-hydroxyethyl)-N, N', N '-triacetic acid and N, N'-bis (2-hydroxyethyl)-N, N '-bis (2-hydroxyethyl)-N, N'-bis (2-hydroxyethyl)- N, N '-ethylenediamine disuccinic acid, aspartic acid or a derivative chemical thereof are coordinated to form an aqueous solution of the coordination compound. The positive electrolyte and the negative electrolyte are prepared from the same and equal chelating agent and supporting electrolyte, and the matching degree of the acid-base property of the positive electrolyte and the negative electrolyte is maintained; the auxiliary electrolyte is added, so that the viscosity difference between the positive electrolyte and the negative electrolyte is reduced, the transmembrane migration of water is reduced, and the conductivity is improved. The selected chelating agent is stably combined with iron and cerium, transmembrane transportation of active substances is inhibited, ion cross contamination among different electrolytes is reduced, and meanwhile side reactions are reduced. The price is low, and the charge-discharge performance and the cycle life of the iron-cerium flow battery are effectively improved at relatively low cost.

The invention discloses a glue solution for a copper-clad plate and a preparation method of the glue solution, and relates to the technical field of copper-clad plates. According to the prepared glue solution for the copper-clad plate, the composite epoxy resin, the curing agent, the accelerant, the solvent, the flexibilizer and the inorganic filler, the composite epoxy resin comprises bisphenol A epoxy resin, epoxy phenyl polysiloxane, itaconic acid polyaryletherketone and hydroxyl-terminated fluorine-containing vinyl polysiloxane, so that the interface bonding force with the copper plate is enhanced; the dielectric constant and the dielectric loss are effectively reduced, the peel strength and the toughness of the material are also remarkably improved, and the toughening agent is modified polyether sulfone microspheres; the modified polyethersulfone microspheres are prepared by coating polyethersulfone microspheres with hexamethylenediamine tetrapropionamide diamine, the hexamethylenediamine tetrapropionamide diamine is prepared by carrying out acylation condensation reaction on hexamethylenediamine tetramethyl propionate and ethylenediamine, and the polyethersulfone microspheres are prepared by carrying out electrostatic spinning on a spinning solution of polyethersulfone and vinylpyridine, so that the peel strength of the glue solution is remarkably improved.

The invention discloses photocuring conductive hydrogel as well as a preparation method and application thereof. According to the invention, methacryloylethyl sulfobetaine (SBMA), acrylic acid (AA) and hydroxyethyl methylacrylate (HEMA) are used as comonomers, deionized water is used as a solvent, N, N '-methylenebisacrylamide (MBAA) is used as a cross-linking agent, ammonium persulfate (APS) is used as an initiator, tetramethylethylenediamine (TEMED) is used as an accelerator, and 2-hydroxy-4'-(2-hydroxyethoxy)-2-methyl propiophenone (Irgacure2959) is used as a photoinitiator; the conductivity is improved by adding an ionic compound potassium chloride (KCl), and the photocuring conductive hydrogel is prepared in a free radical polymerization manner by adopting an LED-UV curing box. The conductive hydrogel disclosed by the invention has the characteristics of good adhesion property, conductivity, mechanical property and the like, and has wide application in the fields of wearable strain sensors and other flexible electronics.

The invention belongs to the field of photocatalysts, and discloses a MoS2 / CdS composite photocatalyst, which is a composite material prepared by taking cadmium acetate as a cadmium source, thioacetamide as a sulfur source and ethylenediamine as a reaction solvent, synthesizing a CdS nanorod through a one-step hydrothermal method, and growing a MoS2 promoter at one end of the CdS nanorod. The invention also discloses an application of the MoS2 / CdS composite photocatalyst in hydrogen production by decomposing water molecules under an illumination condition. The MoS2 cocatalyst with an electron harvesting agent function is grown at one end of the CdS nanorod, so that the performance is improved, and the use of noble metals is avoided. The MoS2 / CdS composite photocatalyst disclosed by the invention has excellent catalytic activity and stable hydrogen evolution activity under a simulated sunlight condition.

The invention relates to the technical field of additive processing, and particularly discloses an additive for mixing raw materials of a carbon-based ceramic friction material and a preparation method of the additive. The preparation method comprises the following steps: mixing a treated multi-walled carbon nanotube with a sodium borate and ethylenediamine aqueous solution, calcining at high temperature to obtain a boron nitride-loaded multi-walled carbon nanotube, and combining with a cross-linking agent to prepare a functional filler; adding ethylenediamine, 3, 3-diphenylpropylamine and palladium acetate into the prepared N-methyl pyrrolidone and polyether-ether-ketone solution to obtain modified polyether-ether-ketone; and mixing the modified polyether-ether-ketone, a functional filler, an antioxidant, a lubricant and N, N-dimethylformamide to obtain the additive for mixing the raw materials of the carbon-based ceramic friction material. The additive provided by the invention has good compatibility, can significantly improve the processing molding performance and mechanical strength of the friction material, and effectively reduces the wear rate.

The invention relates to the technical field of drilling fluids, and discloses a 240 DEG C saturated salt resistant high-density environment-friendly polymer water-based drilling fluid as well as a preparation method and application thereof. The water-based drilling fluid contains a micro-crosslinked heterocyclic polymer filtrate reducer, a hyperbranched strong-adsorption filtrate reducer, a nano-intercalation composite shear strength improving agent, a microsphere blocking agent with soft outside and rigid inside and water, and the micro-crosslinked heterocyclic polymer filtrate reducer is prepared from sodium p-styrenesulfonate, N, N, N-trimethyl-3-(2-methylallylamido)-1-propylammonium chloride, N, N, N-trimethyl-3-(2-methylallylamido)-1-propylammonium chloride, N, N, N-trimethyl-3-(2-methylallylamido)-1-propylammonium chloride and water. The polymer is prepared from N, N-diethylacrylamide, N-vinyl caprolactam, tetramethylethylenediamine and phenyltriethoxysilane through a reaction. The 240 DEG C saturated salt resistant high-density environment-friendly polymer water-based drilling fluid disclosed by the invention can show good performance under high-temperature and high-salt conditions, is good in weighting capability, and can meet the requirements of deep oil and gas formation drilling.

The invention provides a carbon nanotube modified polypropylene composite material and a preparation method thereof, and belongs to the technical field of antibacterial materials. According to the method, plant fibers are used as precursors, carbon nanotubes are prepared through high-temperature calcination, and the carbon nanotubes are subjected to surface activation treatment by using aids such as L-cysteine hydrochloride, sodium ascorbate and ethylenediamine, so that the dispersity and interface bonding force of the carbon nanotubes in a polypropylene matrix are remarkably improved. And then, mixing the modified carbon nano tube with polypropylene, polyhydric alcohol and a catalyst, reacting, and granulating through a double-screw extruder to prepare the composite material with excellent performance. The composite material disclosed by the invention has excellent mechanical properties, thermal stability, antibacterial property and conductivity, and is suitable for the fields of automobile parts, electronic device shells, building materials, medical apparatuses and instruments and the like. The method is simple in process, environment-friendly and efficient, renewable resources are fully utilized, and the method has a wide industrial application prospect.

The invention provides a modified porous chitosan gel bead, a preparation method thereof and application of the modified porous chitosan gel bead in cobalt-nickel separation, and belongs to the technical field of chitosan preparation. The preparation method comprises the following steps: firstly, modifying chitosan by using polyethylene glycol and glutaraldehyde to obtain a porous chitosan gel bead with a cross-linked structure, and then grafting by using epichlorohydrin, ethylenediamine and 2-chloromethylpyridine hydrochloride to obtain the modified porous chitosan gel bead containing an aminomethylpyridine functional group. The modified porous chitosan gel bead has excellent selective adsorption on nickel ions in a cobalt-nickel solution with the pH value range of 2-5, and nickel-cobalt separation can be achieved. In addition, the modified porous chitosan gel bead also has a good nickel-cobalt separation effect in a salt-containing system. The preparation method of the modified porous chitosan gel bead provided by the invention is simple in process, and the raw material chitosan is wide in source, non-toxic and environment-friendly.

The invention belongs to the technical field of preparation of blocking removers, and particularly relates to a composite chelating blocking remover for an oil field and a preparation method of the composite chelating blocking remover. The composite chelating blocking remover for the oil field is prepared from the following raw materials in percentage by mass: 7 to 9 percent of 1-butyl-3-methylimidazole dodecyl sulfonate, 5 to 7 percent of erucamide propyl hydroxypropyl sulfobetaine, 3 to 4 percent of di-(2-ethylhexyl) sodium sulfosuccinate, 4 to 5 percent of ethylenediamine di-o-hydroxyphenylacetic acid, 5 to 7 percent of N, N '-di (2-hydroxybenzyl) ethylenediamine-N, N'-bis (2-hydroxybenzyl)-N, N '-bis (2-ethylhexyl)-N, N'-bis (2-hydroxybenzyl)-N, N '-bis (2-hydroxybenzyl)-N, N'-bis (2-hydroxyphenyl)-N, N '-bis (2-hydroxyphenyl)-N, N'-bis (2-hydroxyphenyl)-N The cleaning agent is prepared from the following components in percentage by weight: 3 to 4 percent of N, N '-diacetic acid, 2 to 3 percent of O-(3-(benzyloxy) propyl) hydroxylamine, 1 to 2 percent of heptadecenyl hydroxyethyl imidazoline quaternary ammonium salt, 1 to 1.5 percent of dimethyl diallyl ammonium chloride homopolymer and the balance of water. The composite chelating blocking remover for the oil field has excellent scale dissolution rate and paraffin inhibition rate when being applied to complex scale blocking removal of the oil field.

The invention relates to the technical field of polyester fibers, and discloses a waterproof antibacterial polyester fiber fabric and a preparation method thereof. A waterproof antibacterial copolyester polymer with a structure similar to that of PET polyester is obtained through esterification condensation polymerization of raw materials such as N, N '-di-Boc-S-methyl isothiourea and dimethyl terephthalate, the structure of the waterproof antibacterial copolyester polymer contains quaternary ammonium salt, guanidyl and a hydrophobic long-chain structure, the waterproof antibacterial copolyester polymer can be uniformly distributed in a polyester fiber matrix, migration of antibacterial groups is avoided, and the antibacterial property of the polyester fiber is improved. The antibacterial performance on bacteria is better exerted; the C-F bond energy is high, fluorine atoms are more easily embedded into a polymer, a channel for water molecules to migrate into a coating film is blocked, a stable protection layer can be formed on the surface of the fiber fabric, fibers are wrapped, moisture is prevented from permeating into the fibers, and therefore the waterproof effect is achieved; meanwhile, the hydrophobic layer also has certain durability and does not lose efficacy after being washed with water for many times.

The invention discloses an implantable absorbable PLA composite material and a preparation method thereof, and relates to the technical field of medical materials. The implantable absorbable PLA composite material is prepared from the following raw materials in parts by weight: 60 to 70 parts of PLA, 5 to 10 parts of poly (lactic-co-glycolic acid), 8 to 12 parts of polycaprolactone, 5 to 8 parts of modified hydroxyapatite, 2 to 3 parts of a toughening agent and 0.2 to 0.6 part of an antioxidant, the toughening agent is prepared by the following steps: reacting hydroxyethyl methylacrylate with ethylenediamine to prepare a four-arm compound, reacting the four-arm compound with 1-chloro-4-isocyanatobutane to prepare an isocyanate compound, and finally reacting the isocyanate compound with polyethylene glycol. The implantable absorbable PLA composite material prepared by the invention has excellent tensile property and impact resistance, and can meet the application requirements of clinical medical treatment.

The invention belongs to the technical field of electrocatalysis, and particularly relates to a preparation method of a nickel-iron-based transition metal boride / black phosphorus composite oxygen evolution reaction electrocatalyst. The invention provides a preparation method of a ferronickel-based transition metal boride / black phosphorus composite oxygen evolution reaction electrocatalyst, which is characterized by comprising the following steps: synthesizing a quasi-two-dimensional ethylenediamine modified black phosphorus nanosheet (eda-BP) by a hydrothermal method, and carrying out ultrasonic treatment on the surface of the obtained eda-BP to obtain the ferronickel-based transition metal boride / black phosphorus composite oxygen evolution reaction electrocatalyst. The nickel-iron-based transition metal boride / black phosphorus composite oxygen evolution reaction (OER) electrocatalyst (Ni < x > FeyB / eda-BP) is prepared by loading nickel-iron-based transition metal boride (Ni < x > FeyB) through an in-situ chemical reduction method, so that modification of a two-dimensional black phosphorus electrocatalyst is realized; the problems of instability of a quasi-two-dimensional black phosphorus catalyst, serious Fe loss of a nickel-iron-based catalyst, poor reaction kinetics and the like are solved to a great extent, and under the synergistic effect of the two parts, the electro-catalytic oxygen evolution reaction activity and the electro-catalytic stability of the composite catalyst are remarkably improved. The preparation method of the nickel-iron-based transition metal boride / black phosphorus composite oxygen evolution reaction electrocatalyst provides a new thought and a new way for designing and developing a novel efficient and stable oxygen evolution reaction electrocatalyst.

The invention provides an all-solid waste geopolymer grouting material and a preparation method thereof, and relates to the technical field of solid waste resource utilization and geopolymer grouting material preparation. The all-solid waste geopolymer grouting material comprises the following raw materials in parts by weight: 100-200 parts of an all-solid waste mixture, 40-50 parts of an alkaline activator, 0.1-0.5 part of an early strength agent, 0.5-1 part of a water reducing agent, 3-7 parts of a modifier and 70-90 parts of water, the all-solid waste material comprises slag powder, steel slag powder, phosphogypsum and fly ash; the modifying agent is prepared from aluminum dihydrogen phosphate, vinyl triacetoxysilane and ethylenediamine terminated polyethyleneimine. The all-solid waste geopolymer grouting material provided by the invention has the characteristics of good working performance, high early strength, micro-expansibility and the like.

The invention discloses a fibrous membrane prepared based on in-situ growth and application of the fibrous membrane in toluene adsorption, and belongs to the technical field of functional textiles. The method for preparing the fiber membrane based on in-situ growth comprises the following steps: (1) adding 2-aminoterephthalic acid and polyacrylonitrile into a solvent, and uniformly mixing to obtain a spinning solution; (2) performing electrostatic spinning on the spinning solution, and drying to obtain a fiber membrane; (3) placing the fiber membrane in an ethylene glycol solution, adding ethylenediamine, and carrying out thermal crosslinking; after the thermal crosslinking is finished, washing and drying to obtain a crosslinked fiber membrane; and (4) placing the cross-linked fiber membrane in a solvent, adding zirconium oxychloride, 2-aminoterephthalic acid and benzoic acid, and carrying out in-situ growth to obtain the fiber membrane prepared based on in-situ growth. The fiber membrane prepared on the basis of in-situ growth is high in methylbenzene adsorption capacity and can be recycled.

The invention relates to the technical field of high-performance fibers, in particular to a high-performance fiber containing carbon nanotubes and a preparation method of the high-performance fiber. The preparation method comprises the following steps: adding ammonium polyphosphate, alkylphenol polyoxyethylene ether and tetraethyl orthosilicate to obtain a silicon-coated ammonium polyphosphate material; then adding a silicon-coated ammonium polyphosphate material and gamma-aminopropyltriethoxysilane, so as to obtain a modified silicon-coated ammonium polyphosphate material; and mixing the modified silicon-coated ammonium polyphosphate material, tannic acid and a buffer solution to obtain the double-layer coated ammonium polyphosphate material. The fiber is obtained by adding a carbon nanotube material, a double-layer coated ammonium polyphosphate material, polytrimethylene terephthalate, a compatilizer and polypropylene and carrying out melt spinning. And then the fibers are sequentially soaked in an ethylenediamine solution, a polyglutamic acid solution and a chitosan solution, and the high-performance fibers are obtained. The obtained high-performance fiber has good flame retardance and antibacterial property, so that the high-performance fiber has a wide application prospect in the technical field of high-performance fibers.

The invention relates to a spongy gel phase change cold storage agent for fruit and vegetable preservation and a preparation method thereof. The preparation method comprises the following steps: 1) sequentially adding sodium alginate powder, an N, N '-methylene bisacrylamide aqueous solution, tetramethylethylenediamine and an ammonium persulfate aqueous solution into an acrylamide aqueous solution; (2) transferring the mixed solution into a polytetrafluoroethylene container, quickly putting the polytetrafluoroethylene container into a vacuum dryer filled with allochroic silicagel, vacuumizing by adopting a circulating water vacuum pump, and sealing for overnight cross-linking to prepare spongy gel; and 3) soaking the spongy gel in a potassium chloride solution to prepare the spongy gel phase change cold storage agent. The spongy gel phase change cold storage agent prepared by the method disclosed by the invention has high phase change latent heat and high flexibility; the device can be freely cut to fit the logistics space, and the problem that the internal environment temperature of the logistics space is not uniform due to local cooling is avoided; the potassium chloride solution is used as an additive for adjusting the phase change temperature of the gel cold storage agent, and the appropriate phase change temperature can be adjusted according to different fruits and vegetables.

The invention relates to an ultraviolet deoxidizing and fresh-keeping packaging material and application thereof, and belongs to the technical field of packaging materials. According to the invention, trimethylolpropane triacrylate and ethylenediamine are used as raw materials, a hyperbranched polymer with terminal double bonds is constructed based on Michael addition, then a sulfydryl-containing hindered amine light stabilizer obtained by ester exchange of methyl thioglycolate and pentamethylpiperidinol is added, and the hindered amine light stabilizer and alkyl mercaptan are subjected to a sulfydryl-alkene click reaction together. The light stabilizer and plastic are subjected to melt blending and then subjected to curtain coating to form a film to serve as an outer layer, and one face of the outer layer is coated with coating liquid prepared from a dispersing agent, PET, an active substance capable of generating triplet excitons under irradiation of ultraviolet light, an antioxidant, an ultraviolet light absorber and a stabilizer. When the ultraviolet deoxidization fresh-keeping packaging material is applied to packaging of articles, deoxidization can be achieved through irradiation of ultraviolet light, and the degradation effect of the ultraviolet light on the outer layer is very little.

The invention discloses a long-life phosphorescent sulfur quantum dot, a multicolor long-life phosphorescent sulfur quantum dot composition and a preparation method and application thereof, and belongs to the technical field of phosphorescent materials and information encryption. The preparation method comprises the following steps: carrying out solvothermal reaction on a sulfur source and ethylenediamine to obtain sulfur quantum dots, and adding a sulfur quantum dot aqueous solution into a boric acid matrix to react to prepare long-life phosphorescent sulfur quantum dots (SQDs-MA); the long-life phosphorescent sulfur quantum dots and a rhodamine B aqueous solution are blended and dried to prepare the multicolor long-life phosphorescent sulfur quantum dot composition (RhB / SQDs-MA). When excited by ultraviolet light, the SQDs-MA shows a wide absorption range of 200 to 700 nm. When excitation is carried out at 362 nm, the SQDs-MA shows a blue fluorescence emission peak at 436 nm. The SQDs-MA powder emits bright green phosphorescence after the irradiation of an ultraviolet lamp is turned off, and under the optimal excitation of 373 nm, the maximum phosphorescence emission value is displayed at 526 nm. Under the irradiation of ultraviolet light, the RhB / SQDs-MA can emit yellow, orange and red phosphorescence at the wavelength of 584 nm, 600 nm and 620 nm.

The invention belongs to the technical field of preparation of hot melt adhesives, and particularly relates to a high-strength quick-curing bio-based hot melt adhesive and a preparation method thereof. The preparation method comprises the following steps: preparing a dimer acid polymer from dimer acid, sebacic acid, polyether amine, ethylenediamine, an antioxidant and a catalyst, and mixing the dimer acid polymer with a beta nucleating agent toughened polypropylene / SiO2 nano-composite and an organic borosiloxane polymer to obtain the high-strength quick-curing bio-based hot melt adhesive. The prepared hot melt adhesive has good mechanical property, viscosity and self-healing property.

The invention provides a rapid visual D-limonene detection method and application thereof, and belongs to the technical field of analytical chemistry, the method comprises the following steps: uniformly mixing ethanol and water to form a solvent system, sequentially adding template agents Pluronic P123 and Pluronic F127, phloroglucinol, 1, 3, 5-trimethylbenzene and ethylenediamine, and uniformly stirring at room temperature; after the reaction is completed, washing, centrifuging, drying and calcining an obtained sample to obtain DNCzyme; the method comprises the following steps: adding TMB, H2O2 and DNCzyme into an acetic acid-sodium acetate buffer solution HAc-NaAc, finally adding D-limonene, incubating, and carrying out visual detection on the solution. The method for detecting the D-limonene through colorimetric sensing is rapid, simple, convenient, low in cost, high in sensitivity and good in selectivity, and visual detection is achieved by combining a smart phone.

The invention belongs to the technical field of photovoltaic coatings, and discloses a photovoltaic coating as well as a preparation method and application thereof. The photovoltaic coating is prepared from the following raw materials: a solvent, an ultraviolet light absorber, a wetting agent, an antistatic agent, modified hydrophilic silicon dioxide, nano magnesium fluoride and nano tin dioxide, the modified hydrophilic silicon dioxide is hydrophilic silicon dioxide modified by ethylenediamine and glacial acetic acid. A coating formed by the photovoltaic coating is high in adhesive force and resistant to aging, and the light transmittance, the self-cleaning property and the antistatic property of photovoltaic glass can be obviously improved.

The invention relates to the technical field of battery current collectors, and discloses a high-conductivity stainless steel foil for a positive current collector and a preparation method of the high-conductivity stainless steel foil. Comprising the following operation steps that 1, stainless steel foil is subjected to acid pickling and then dried, the stainless steel foil is soaked in an ethylenediamine tetramethylenephosphonic acid ethanol solution to be stirred for 2-3 h in the nitrogen atmosphere, the stainless steel foil is taken out to be cleaned and cured for 3-4 h at the temperature of 120-125 DEG C, after the stainless steel foil is cooled to the room temperature, washing and nitrogen drying are conducted, and prefabricated stainless steel foil is obtained; and 2, the prefabricated stainless steel foil is soaked in the anti-oxidation conductive copper composite sol for 25-40 s, taken out, dried, coated with an aluminum grid, ground, soaked in the graphene / carbon nanotube composite sol for 20-30 s, taken out, dried for 4-6 min at the temperature of 100-120 DEG C, ground and dried, and the high-conductivity stainless steel foil is obtained.

The invention discloses a method for enhancing Candida albicans biofilm resistance of azole drugs by using a zinc ion chelating agent, through the combined action of the zinc ion chelating agent N, N, N ', N'-tetra (2-picolyl) ethylenediamine (TPEN) and fluconazole, the activity of the Candida albicans biofilm can be reduced, and the Candida albicans biofilm can be enhanced. The early-stage adhesion process, the medium-stage yeast-to-hypha conversion process and the late-stage maturation process formed by the candida albicans biological membrane are inhibited, the structure of the candida albicans biological membrane is destroyed, then the high drug resistance of the candida albicans biological membrane to fluconazole is reversed, and the pathogenicity of the fluconazole is reduced; the problems of high drug resistance and sustained infection caused by the formation of a candida albicans biofilm are hopefully solved, and a direction is provided for the treatment of clinical fungal infection and the research and development of drugs.

The invention provides a gel composite adsorbent with a foaming structure as well as a preparation method and application thereof, and the preparation method comprises the following steps: S1, dissolving acrylamide powder in deionized water, and stirring to obtain a solution A; s2, dissolving sodium alginate in the solution A for thickening to obtain a solution B; s3, transferring the solution B into an ice-water bath; s4, adding N, N-methylene bisacrylamide into the solution B, stirring until the N, N-methylene bisacrylamide is completely dissolved, then adding N, N, N ', N'-tetramethylethylenediamine, and stirring until the N, N, N ', N'-tetramethylethylenediamine is uniform to obtain a solution C; s5, adding ammonium persulfate into the solution C, and stirring until the ammonium persulfate is completely dissolved to obtain a solution D; s6, the solution D is poured into a mold and then vacuumized to form gel, and a hydrogel sample is obtained after gel forming; s7, drying the hydrogel sample, and then soaking the dried hydrogel sample in a salt solution to obtain a soaked gel material; and S8, drying the soaked gel material to obtain the finished product composite adsorbent.