Hollow fluorescent carbon quantum dots as well as preparation method and application thereof
A carbon quantum dot and fluorescence technology, which is applied in the field of hollow fluorescent carbon quantum dots and their preparation, can solve the problems of unfavorable continuous and large-scale production of carbon quantum dots, low fluorescence quantum yield of carbon quantum dots, non-renewable energy, etc. Conditions require no energy consumption, good solubility and dispersion, stable optical properties
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Embodiment 1
[0037] Step 1, weigh 1.0g of glucose and place it in a glass container, add 6mL of ethylenediamine, stir well, then gradually add 4mL of concentrated phosphoric acid to obtain a dark brown sticky substance;
[0038] Step 2, after the glass container is naturally cooled, add 20mL of secondary water to it, stir and dissolve to obtain a dark brown solution, filter to remove insoluble matter to obtain a clear dark brown solution, remove impurities by dialysis, and obtain pure hollow carbon quantum dots aqueous solution;
[0039] In step 3, the hollow carbon quantum dot aqueous solution is freeze-dried to obtain the hollow carbon quantum dot, and its relative quantum yield (based on quinine sulfate) is 9.4%.
[0040] Characterization and application see Figure 1-13 .
Embodiment 2
[0042] Step 1, weigh 1.0g of sucrose and place it in a glass container, add 6mL of ethylenediamine, stir well, then gradually add 4mL of concentrated phosphoric acid to obtain a dark brown sticky substance;
[0043] Step 2, after the glass container is naturally cooled, add 22mL of secondary water therein, and the rest are the same as in Example 1;
[0044] Its relative quantum yield (based on quinine sulfate) is 8.7%.
Embodiment 3
[0046] Step 1, weigh 1.0g of fructose and put it in a glass container, add 6mL of ethylenediamine, stir well, then gradually add 4mL of concentrated phosphoric acid to obtain a dark brown sticky substance;
[0047]Step 2, after the glass container is naturally cooled, 25mL of secondary water is added thereto, and the rest are the same as in Example 1;
[0048] Its relative quantum yield (based on quinine sulfate) is 4.2%.
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