54results about "Insertable electrodes" patented technology

A fuel cell comprising: (a) a binary anode, (b) a cathode, and (c) a liquid electrolyte disposed between and interacting with the binary anode and the cathode, wherein the binary anode includes at least one liquid fuel and at least one solid fuel. Preferably, the electrolyte includes an alcohol such as methanol, and the solid fuel includes aluminum, magnesium and / or zinc.

A refuelable anode structure containing anode paste for a metal air electrochemical cell is provided. The anode paste comprises metal particles, a gelling agent, and a base. The spent anode structure may be removed after discharging. The anode structure may thereafter be electrically recharged to convert oxidized metal into consumable metal fuel, or mechanically emptied and refilled with fresh metal fuel paste.

A metal air cell system is provided. The system includes a cathode having a pair of oxidant sides and anode sides. An anode is provided in two parts, each part having a side complementary each anode side of the cathode. A separator is disposed between the anode and cathode to electrically isolate the anode and the cathode. Electrolyte is disposed between the cathode and the anode, the electrolyte provided within the anode, separately at the interface between the cathode and the anode, or both within the anode and separately at the interface between the cathode and the anode. This configuration generally allows a single oxidant flow to be exposed to both portions of the cathode due to the central passage of the oxidant.

A device / system having an integrated refuelable and rechargable metal-air FCB based power supply unit for generating and providing electrical power to at least one electrical-energy-consuming load device disposed therein. An external power source is used to recharge the metal-air FCB subsystems embodied therein. A control subsystem automatically transitions between discharging mode (wherein at least one metal-air FCB subsystem supplies electrical power to the electrical power-consuming load device) and a recharging mode (wherein the external power source is electrically coupled to at least one metal-air FCB subsystem to thereby recharge the metal-air FCB subsystem(s). The metal-air FCB subsystem(s) are refueled by manually loading and unloading metal-fuel from the metal-air FCB subsystem(s). Preferably, electrical power provided to the at least one electrical power-consuming load device is supplied solely by electrical power generated by discharging metal-fuel in the metal-air fuel cell battery subsystem(s). In addition, the metal-air FCB subsystem(s) preferably has a modular architecture that enable flexible and user-friendly operations in loading of metal-fuel, unloading of consumed metal-fuel, replacement of the ionic-conducting medium, and replacement of the cathode.

Improved metal-air fuel cell battery systems having metal-fuel realized in the form of metal-fuel tape cartridges and metal-fuel cards, which can be either manually or automatically inserted within the power generation bay of the system. In order to produce a range of output voltages, the metal-fuel tape has a plurality of electrically-isolated metal-fuel tracks and the metal-fuel cards have a plurality of electrically-isolated metal-fuel strips. An output voltage configuration subsystem is provided for configuring the voltages produced by the individual cells to produce a desired output. A subsystem is provided for detecting oxide formation on the metal-fuel tracks and strips so that only metal-fuel that has been oxidized is reduced during recharging operations. A subsystem is also provided for controlling the flow of oxygen into the power generation head in order to control the power output from the system.

A metal air cell system comprises a frame structure configured with variable airflow paths. The variable airflow paths provide alternatives between direct open loop airflow and semi-closed loop air flow, wherein air is at least partially circulated around the cell components. This is particularly useful for operation in different temperature environments. The open loop mode is useful for high temperature environments, and the semi-closed loop mode is useful for low temperature environments.

Improved metal-air fuel cell battery systems having metal-fuel realized in the form of metal-fuel tape cartridges and metal-fuel cards, which can be either manually or automatically inserted within the power generation bay of the system. In order to produce a range of output voltages, the metal-fuel tape has a plurality of electrically-isolated metal-fuel tracks and the metal-fuel cards have a plurality of electrically-isolated metal-fuel strips. An output voltage configuration subsystem is provided for configuring the voltages produced by the individual cells to produce a desired output. A subsystem is provided for detecting oxide formation on the metal-fuel tracks and strips so that only metal-fuel that has been oxidized is reduced during recharging operations. A subsystem is also provided for controlling the flow of oxygen into the power generation head in order to control the power output from the system.

In an air-metal fuel cell battery (FCB) system, wherein a plurality of movable cathode structures are mounted within a compact housing through which metal-fuel tape is transported along a predetermined path while an ionically-conductive medium is disposed between the metal-fuel tape and each movable cathode structure at points of contact. In illustrative embodiments, the movable cathode structures are realized as rotatable cathode cylinders, and transportable cathode belts. The ionically-conductive medium is realized as a solid-state ionically-conductive film applied to the cathode structures and / or metal-fuel tape, as well as ionically-conductive belt structures transported at the same velocity as corresponding cathode structures (e.g. cathode cylinders or belts) at the locus of points at which the ionically-conductive medium contacts the moving cathode structure and the moving metal-fuel tape. By virtue of the present invention, the volumetric power density characteristics of FCB systems can be significantly improved, while the likelihood of damage to the cathode structures and metal-fuel tape is substantially reduced.

Disclosed are various types of metal-air FCB-based systems comprising a Metal-Fuel Transport Subsystem, a Metal-Fuel Discharging Subsystem, and a Metal-Fuel Recharging Subsystem. The function of the Metal-Fuel Transport Subsystem is to transport metal-fuel cards or sheets to the Metal-Fuel Discharge Subsystem, or the Metal-Fuel Recharge Subsystem, depending on the mode of the system selected. When transported to or through the Metal-Fuel Discharge Subsystem, each metal-fuel card is discharged by (i.e. electro-chemically reaction with) one or more discharging heads in order produce electrical power across an electrical load connected to the subsystem while H2O and O2 are consumed at the cathode-electrolyte interface during the electro-chemical reaction. When transported to or through the Metal-Fuel Recharging Subsystem, discharged metal-fuel is recharged by one or more recharging heads in order to convert the oxidized metal-fuel material into its source metal material suitable for reuse in power discharging operations, while O2 is released at the cathode-electrolyte interface during the electro-chemical reaction. In the illustrative embodiments, various forms of metal fuel cards can be discharged and recharged in an efficient manner to satisfy a broad range of electrical loading conditions.

An electrochemical device having an electrode matrix including a multilayer structure laminating positive and negative electrodes with a separator interposed therebetween; wherein at least one of the positive and negative electrodes has a resistance control layer at least at an edge part exposed when the separator thermally shrinks on a surface on the separator side; and wherein the resistance control layer has a resistance value as a total resistance value of the electrode matrix falling in such a range that an estimated internal short circuit current between the positive and negative electrodes is equivalent to 0.09 C to 1 C.

Disclosed is a method and apparatus for extending path-length of metal-fuel tape during discharging and / or recharging operations so that a supply of metal-fuel tape contained within a cassette device or on a supply reel can be rapidly discharged and / or recharged in an improved manner. During discharging operations, a plurality of discharging heads are selectively arranged about the extended path-length of metal-fuel tape so as increase the rate at which electrical power is powered from the system. During recharging operations, a plurality of recharging heads are selectively arranged about the extended path-length of metal-fuel tape to decrease the time required to recharge the metal-fuel tape transported through the system.

The rechargeable metal air electrochemical cell generally includes a pair of air cathode portions centrally disposed and attached to each other with a collapsible mechanism. Anodes are disposed in ionic communication with each air cathode portions via a suitable electrolyte. For recharging, a pair of third charging electrodes is provided ionic communication with the anode portions.

Disclosed is a metal-air fuel cell battery system, wherein metal-fuel tape can be transported through its discharging head assembly as well as its recharging head assembly in a bi-directional manner while the availability of metal-fuel therealong is automatically managed in order to improve the performance of the system.

In an air-metal fuel cell battery (FCB) system, wherein metal-fuel tape, the ionically-conductive medium and the cathode structures are transported at substantially the same velocity at the locus of points at which the ionically-conductive medium contacts the moving cathode structure and the moving metal-fuel tape during discharging and recharging modes of operation. In a first generalized embodiment of the present invention, the ionically-conductive medium is realized as an ionically-conductive belt, and the metal-fuel tape, ionically-conductive belt, and movable cathode structure are transported at substantially the same velocity at the locus of points which the ionically-conducing belt contacts the metal-fuel tape and the cathode structure during system operation. In a second generalized embodiment of the present invention, the ionically-conductive medium is realized as a solid-state (e.g. gelatinous) film layer integrated with the metal-fuel tape. In a third generalized embodiment of the present invention, the ionically-conductive medium is realized as a solid-state film layer integrated with the movable cathode structure. By transporting the movable cathode structure, ionically contacting medium and metal-fuel tape within the system as described above, generation of frictional forces among such structures are minimized during system operation, and thus the damage to the cathode structure and metal-fuel tape is substantially reduced.

Disclosed is a method and apparatus for extending path-length of metal-fuel tape during discharging and / or recharging operations so that a supply of metal-fuel tape contained within a cassette device or on a supply reel can be rapidly discharged and / or recharged in an improved manner. During discharging operations, a plurality of discharging heads are selectively arranged about the extended path-length of metal-fuel tape so as increase the rate at which electrical power is powered from the system. During recharging operations, a plurality of recharging heads are selectively arranged about the extended path-length of metal-fuel tape to decrease the time required to recharge the metal-fuel tape transported through the system.

Electrochemical cell systems are disclosed herein that are capable of selective ionic isolation, oxidant isolation, oxidant removal, moisture control, and combinations thereof. Selective ionic isolation is generally effectuated by selectively eliminating or minimizing ionic communication between an anode and a cathode of the electrochemical cell.

A metal air cell system comprises a frame structure configured with variable airflow paths. The variable airflow paths provide alternatives between direct open loop airflow and semi-closed loop air flow, wherein air is at least partially circulated around the cell components. This is particularly useful for operation in different temperature environments. The open loop mode is useful for high temperature environments, and the semi-closed loop mode is useful for low temperature environments.

To provide a high capacity thin-type secondary battery suitably formed into a module and having no thickness fluctuation, excellent quality stability, and excellent heat radiation properties, by using a sheet-like separator having expansion anisotropy due to penetration of an electrolytic solution. A method of producing a thin-type secondary battery includes the steps of: sandwiching a sheet-like separator having expansion anisotropy due to penetration of an electrolytic solution, by a sheet-like electrode pair; inserting the separator sandwiched by the electrode pair and injecting the electrolytic solution, into a thin-type outer wrapper having an opened portion; penetrating the electrolytic solution into the separator without fixing motion of the separator in a maximum expanding direction and in a state where the maximum expanding direction of the separator and a penetrating direction of the electrolytic solution are substantially parallel to each other; and sealing the opened portion into a tightly sealed state.

The invention is achieved by applying a layer of the mixture that contains polymer and conductive particles over a first surface, when the mixture has a first viscosity that allows the conductive particles to rearrange within the layer. An electric field is applied over the layer, so that a number of the conductive particles are aligned with the field and thereafter the viscosity of the layer is changed to a second, higher viscosity, in order to mechanically stabilise the layer. This leads to a stable layer with enhanced and anisotropic conductivity that can be used in the manufacture of ESD devices.

In an air-metal fuel cell battery (FCB) system, wherein a plurality of movable cathode structures are mounted within a compact housing through which metal-fuel tape is transported along a predetermined path while an ionically-conductive medium is disposed between the metal-fuel tape and each movable cathode structure at points of contact. In illustrative embodiments, the movable cathode structures are realized as rotatable cathode cylinders, and transportable cathode belts. The ionically-conductive medium is realized as a solid-state ionically-conductive film applied to the cathode structures and / or metal-fuel tape, as well as ionically-conductive belt structures transported at the same velocity as corresponding cathode structures (e.g. cathode cylinders or belts) at the locus of points at which the ionically-conductive medium contacts the moving cathode structure and the moving metal-fuel tape. By virtue of the present invention, the volumetric power density characteristics of FCB systems can be significantly improved, while the likelihood of damage to the cathode structures and metal-fuel tape is substantially reduced.

Improved metal-air fuel cell battery systems having metal-fuel realized in the form of metal-fuel tape cartridges and metal-fuel cards, which can be either manually or automatically inserted within the power generation bay of the system. In order to produce a range of output voltages, the metal-fuel tape has a plurality of electrically-isolated metal-fuel tracks and the metal-fuel cards have a plurality of electrically-isolated metal-fuel strips. An output voltage configuration subsystem is provided for configuring the voltages produced by the individual cells to produce a desired output. A subsystem is provided for detecting oxide formation on the metal-fuel tracks and strips so that only metal-fuel that has been oxidized is reduced during recharging operations. A subsystem is also provided for controlling the flow of oxygen into the power generation head in order to control the power output from the system.

Disclosed are various types of metal-air FCB-based systems comprising a Metal-Fuel Transport Subsystem, a Metal-Fuel Discharging Subsystem, and a Metal-Fuel Recharging Subsystem. The function of the Metal-Fuel Transport Subsystem is to transport metal-fuel material, in the form of tape, cards, sheets, cylinders and the like, to the Metal-Fuel Discharge Subsystem, or the Metal-Fuel Recharge Subsystem, depending on the mode of the system selected. When transported to or through the Metal-Fuel Discharge Subsystem, the metal-fuel is discharged by (i.e. electro-chemically reaction with) one or more discharging heads in order produce electrical power across an electrical load connected to the subsystem while H2O and O2 are consumed at the cathode-electrolyte interface during the electro-chemical reaction. When transported to or through the Metal-Fuel Recharging Subsystem, discharged metal-fuel is recharged by one or more recharging heads in order to convert the oxidized metal-fuel material into its source metal material suitable for reuse in power discharging operations, while O2 is released at the cathode-electrolyte interface during the electro-chemical reaction. In the illustrative embodiments, various forms of metal fuel can be discharged and recharged in an efficient manner to satisfy a broad range of electrical loading conditions.

Systems and methods for preparing electrocatalysts are disclosed. The system includes-a high temperature synthesis device for preparing an array of electrocatalysts as electrolytic surfaces of working electrodes. At least a portion of the electrolytic surfaces are defined by different materials. The device includes a plurality of openings for receiving the array of working electrodes and a mask having a plurality of openings configured for exposing at least a portion of each of the working electrodes for forming the electrolytic surfaces thereon.

A method of and system for flushing one or more cells or components thereof in a particle-based electrochemical power source is provided. Reaction solution is delivered to and withdrawn from the one or more cells when the electrochemical power source is in a standby mode of operation.

In an air-metal fuel cell battery (FCB) system, wherein metal-fuel tape, the ionically-conductive medium and the cathode structures are transported at substantially the same velocity at the locus of points at which the ionically-conductive medium contacts the moving cathode structure and the moving metal-fuel tape during discharging and recharging modes of operation. In a first generalized embodiment of the present invention, the ionically-conductive medium is realized as an ionically-conductive belt, and the metal-fuel tape, ionically-conductive belt, and movable cathode structure are transported at substantially the same velocity at the locus of points which the ionically-conducing belt contacts the metal-fuel tape and the cathode structure during system operation. In a second generalized embodiment of the present invention, the ionically-conductive medium is realized as a solid-state (e.g. gel-like) film layer integrated with the metal-fuel tape, and the metal-fuel tape, ionically-conductive film layer and movable cathode structure are transported at substantially the same velocity at the locus of points which the ionically-conducing film layer contacts the metal-fuel tape and the cathode structure during system operation. In a third generalized embodiment of the present invention, the ionically-conductive medium is realized as a solid-state film layer integrated with the movable cathode structure, and the metal-fuel tape, ionically-conductive film layer and movable cathode structure are transported at substantially the same velocity at the locus of points which the ionically-conducing film layer contacts the metal-fuel tape and the cathode structure during system operation. By transporting the movable cathode structure, ionically contacting medium and metal-fuel tape within the system as described above, generation of frictional forces among such structures are minimized during system operation, and thus the damage to the cathode structure and metal-fuel tape is substantially reduced.

Disclosed are various types of metal-air FCB-based systems comprising a Metal-Fuel Transport Subsystem, a Metal-Fuel Discharging Subsystem, and a Metal-Fuel Recharging Subsystem. The function of the Metal-Fuel Transport Subsystem is to transport metal-fuel material, in the form of tape, cards, sheets, cylinders and the like, to the Metal-Fuel Discharge Subsystem, or the Metal-Fuel Recharge Subsystem, depending on the mode of the system selected. When transported to or through the Metal-Fuel Discharge Subsystem, the metal-fuel is discharged by (i.e. electro-chemically reaction with) one or more discharging heads in order produce electrical power across an electrical load connected to the subsystem while H2O and O2 are consumed at the cathode-electrolyte interface during the electrochemical reaction. When transported to or through the Metal-Fuel Recharging Subsystem, discharged metal-fuel is recharged by one or more recharging heads in order to convert the oxidized metal-fuel material into its source metal material suitable for reuse in power discharging operations, while O2 is released at the cathode-electrolyte interface during the electro-chemical reaction. In the illustrative embodiments, discharge and recharge parameters are detected and processed in order to generate control data signals that are used to control discharging and recharging parameters so that discharging and recharging operations and metal-fuel / metal-oxide management operations are carried out in an efficient manner.

A lithium-ion battery having an anode including an array of nanowires electrochemically coated with a polymer electrolyte, and surrounded by a cathode matrix, forming thereby interpenetrating electrodes, wherein the diffusion length of the Li+ ions is significantly decreased, leading to faster charging / discharging, greater reversibility, and longer battery lifetime, is described. The battery design is applicable to a variety of battery materials. Methods for directly electrodepositing Cu2Sb from aqueous solutions at room temperature using citric acid as a complexing agent to form an array of nanowires for the anode, are also described. Conformal coating of poly-[Zn(4-vinyl-4′methyl-2,2′-bipyridine)3](PF6)2 by electroreductive polymerization onto films and high-aspect ratio nanowire arrays for a solid-state electrolyte is also described, as is reductive electropolymerization of a variety of vinyl monomers, such as those containing the acrylate functional group. Such materials display limited electronic conductivity but significant lithium ion conductivity. Cathode materials may include oxides, such as lithium cobalt oxide, lithium magnesium oxide, or lithium tin oxide, as examples, or phosphates, such as LiFePO4, as an example.

A layer of the mixture that contains polymer and conductive particles is applied over a first surface, when the mixture has a first viscosity that allows the conductive particles to rearrange within the layer. An electric field is applied over the layer, so that a number of the conductive particles are aligned with the field and thereafter the viscosity of the layer is changed to a second, higher viscosity, in order to mechanically stabilise the layer. This leads to a stable layer with enhanced and anisotropic conductivity.