Electroluminescent (EL) devices

a technology of electroluminescent devices and electroluminescent coatings, which is applied in the direction of discharge tube luminescnet screens, other domestic articles, natural mineral layered products, etc., can solve the problems of poor fluorescent properties of materials, performance levels of current available devices may still be below expectations, and performance characteristics still possess many disadvantages

Inactive Publication Date: 2000-05-02
LG DISPLAY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these devices require excitation voltages on the order of 100 volts or greater.
However, these materials are believed to possess poor fluorescent properties and there is no indication that the materials can be used as light emitting materials.
While recent progress in organic EL research has elevated the potential of organic EL devices for widespread applications, the perfo

Method used

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  • Electroluminescent (EL) devices
  • Electroluminescent (EL) devices

Examples

Experimental program
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Effect test

example i

Synthesis of 4,4'-Bis-[2-(4,6-diphenyl-1,3,5-triazinyl)]1-1,1'-biphenyl:

In a 100 milliliter round bottom flask there was added 4,4-biphenyldicarbonyl chloride (5.14 grams), 1,2-dichlorobenzene (15.0 milliliters), thionyl chloride (2.0 milliliters), and aluminum chloride (5.5 grams with stirring, benzonitrile (7.6 grams) was added slowly, and the resulting reaction mixture was heated under argon to about 150.degree. C. for 0.5 hours. The temperature of the reaction mixture was reduced to 120.degree. C., then ammonium chloride (3.5 grams) was added in one portion. The reaction mixture was stirred at this temperature for an additional 20 hours. The reaction flask was removed from the heater and cooled to room temperature, about 25.degree. C. throughout. The resulting mixture was poured into 600 milliliters of methanol and stirred for 20 minutes. The precipitates were collected by filtration and dried in a vacuum oven to afford 2.7 grams of crude product which was further purified by su...

example ii

Synthesis of 4,4'-Bis-[2-(4,6-di-p-tolyl-1,3,5-triazinyl)]1-1,1'-biphenyl:

In a 250 milliliter round bottom flask there was added 4,4'-biphenyidicarbonyl chloride (8.215 grams), 1,2-dichlorobenzene (65 milliliters), thionyl chloride (1.0 milliliter), and aluminum chloride (7.3 grams). With stirring, p-tolunitrile (13.5 grams) was added slowly, and the resulting reaction mixture was heated under argon to about 150.degree. C. for 0.5 hours. The temperature of the reaction mixture was reduced to 120.degree. C., then ammonium chloride (7.13 grams) was added in one portion. The reaction mixture was stirred at this temperature for an additional 20 hours. The reaction flask was removed from the heater and cooled to room temperature. The mixture was poured into 600 milliliters of methanol and stirred for 20 minutes. The precipitates were collected by filtration and dried in a vacuum oven to afford 3.49 grams of crude product which was further purified by sublimation. The pure about 99.5 tria...

example iii

Synthesis of 4,4'-Bis-[2-(4,6-di-m-tolyl-1,3,5-triazinyl)]-1,1'-biphenyl:

In a 200 milliliter round bottom flask there was added 4,4'-biphenyidicarbonyl chloride (8.0 grams), 1,2-dichlorobenzene (65.0 milliliters), thionyl chloride (1.6 milliliters), and aluminum chloride (7.6 grams). With stirring, m-tolunitrile (13.4 grams) was added slowly, and the resulting reaction mixture was heated under argon to about 150.degree. C. for 0.5 hours. The temperature of the reaction mixture was reduced to 120.degree. C., then ammonium chloride (6.1 grams) was added in one portion. The reaction mixture was stirred at this temperature for additional 20 hours. The reaction flask was removed from the heater and cooled to room temperature. The resulting mixture was poured into 100 milliliters of methanol and stirred for 20 minutes. The precipitates were collected by filtration and dried in a vacuum oven to afford 2.568 grams of crude product which was further purified by sublimation. The pure 99.25 pe...

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Abstract

An electroluminescent device comprised of an anode, a hole transporting layer, a light emitting layer, and a cathode, wherein said light emitting layer contains a component of the formula wherein Ar1, Ar2, Ar3, and Ar4 are each independently aryl or optionally aliphatic; R1 and R2 are independently selected from the group consisting of hydrogen, aliphatic, halogen, and cyano; L is a suitable linking group; and n is a number of from 0 to about 3.

Description

This invention is directed to organic electroluminescent (EL) devices, and more specifically, to organic EL devices with a number of excellent performance characteristics. Organic EL devices are desired that are capable of providing uniform luminescence, saturated color in the blue, green and red regions of the visible spectrum, and low driving voltages. The organic EL devices of the present invention enable in embodiments the aforementioned characteristics and which devices contain organic luminescent materials or light emitting components comprised of fluorescent triazine compounds, and which devices can be selected for use in flat-panel emissive display technologies, including TV screens, computer screens, and the like.PRIOR ARTA simple organic EL device can be comprised of a layer of an organic luminescent material conductively sandwiched between an anode, typically comprised of a transparent conductor, such as indium tin oxide, and a cathode, typically a low work function metal...

Claims

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Application Information

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IPC IPC(8): C07D251/24C07D251/00H01L51/05H01L51/30H01L51/50H01L51/00
CPCC07D251/24H01L51/0067H01L51/0052H01L51/0055H01L51/0058Y10S428/917H01L51/007H01L51/0081H01L51/5012H01L2251/308H01L51/0068H10K85/623H10K85/626H10K85/655H10K85/6565H10K85/615H10K85/654H10K85/324H10K50/11H10K2102/103
Inventor HU, NAN-XINGESTEGHAMATIAN, MOHAMMADQI, YUPOPOVIC, ZORAN D.ONG, BENG S.HOR, AH-MEE
Owner LG DISPLAY CO LTD
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