SCR (selective catalytic reduction) flue gas denitration catalyst regeneration method

A denitration catalyst and catalyst technology, which can be used in catalyst regeneration/reactivation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve problems such as serious pollution and environmental pollution, and achieve the effect of cheap promotion and use

Inactive Publication Date: 2012-09-12
NANJING UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Both patents are based on the regeneration of vanadium-titanium catalysts. V2O5 is a highly toxic substance. Not only will it cause serious pollution during production and use, but the regenerated vanadium-titanium catalysts will still continue to pollute the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] 1. Preparation of cleaning solution, weigh 0.05 Kg (0.01%) of TX-10 emulsifier, weigh 49.95 Kg (99.9%) of oxalic acid with an acid molar concentration of 1.5 mol / L, and perform ultrasonic treatment for 10 minutes to make it mix Evenly, it is prepared into 50 Kg cleaning solution.

[0038] 2. Preparation of active replenishing liquid

[0039] The first step: Weigh JFC type accelerator 0.05 Kg (0.1%), diffusion agent sodium dinaphthyl methane disulfonate 2.5Kg (5%), zirconium nitrate 2.5 Kg (5%), copper nitrate 2.5 Kg (5% ), deionized water 8 Kg (16%), stirring speed is 100 rev / min, mechanical stirring 120 minutes, make it mix homogeneously;

[0040] Step 2: Weigh 15 Kg (30%) of tetrabutyl titanate, 15 Kg (30%) of absolute ethanol, and 4.45 Kg (8.9%) of deionized water. Stirring speed is 1000 rev / min, mechanical stirring for 10 minutes to make it mix evenly;

[0041] Step 3: Add liquid A to liquid B, stir at a speed of 500 rpm, mechanically stir for 90 minutes, and pre...

Embodiment 2

[0055] 1. Preparation of cleaning solution, weigh 5 Kg (10%) of OP-10 emulsifier, weigh 45 Kg (90%) of nitric acid with an acid molar concentration of 3 mol / L, and perform ultrasonic treatment for 35 minutes to make it mix Evenly, prepare 50Kg cleaning solution.

[0056] 2. Preparation of active replenishing liquid

[0057] The first step: take by weighing JFC-1 type accelerator 5 Kg (10%), diffusion agent sodium dinaphthyl methane disulfonate 0.05 Kg (0.1%), nickel nitrate 2.5 Kg (5%), lanthanum nitrate 5 Kg ( 10%), molybdenum nitrate 5 Kg (10%), zirconium sulfate 5 Kg (10%), ferric nitrate 2.5 Kg (5%), deionized water 22 Kg (44%), stirring speed is 1000 rpm, mechanical Stir for 10 minutes to make it evenly mixed;

[0058] Step 2: Weigh 0.5 Kg (1%) of tetrabutyl titanate, 0.5 Kg (1%) of absolute ethanol, and 1.95 Kg (3.9%) of deionized water. The stirring speed is 100 rpm, and the mechanical stirring is carried out for 120 minutes to make it evenly mixed;

[0059] Step 3:...

Embodiment 3

[0070] 1. Preparation of cleaning solution, weigh 5 Kg (10%) of OP-10 emulsifier, weigh 45 Kg (90%) of sulfuric acid with an acid molar concentration of 0.018mol / L, and perform ultrasonic treatment for 60 minutes to mix Evenly, prepare 50Kg cleaning solution.

[0071] 2. Preparation of active replenishing liquid

[0072] The first step: weigh JFC-2 type accelerator 2.5 Kg (5%), diffusion agent sodium dinaphthyl methane disulfonate 5Kg (10%), molybdenum sulfate 5Kg (10%), copper sulfate 5Kg (10%) , cerium sulfate 2.5Kg (5%), deionized water 20Kg (40%), stirring speed is 500 revs / min, mechanical stirring 60 minutes, make it mix homogeneously;

[0073] Step 2: Weigh 2.5Kg (5%) of tetrabutyl titanate, 2.5Kg (5%) of absolute ethanol, and 5Kg (10%) of deionized water. Stirring speed is 1000 rpm, mechanical stirring for 60 minutes, mixing evenly;

[0074] Step 3: Add liquid A to liquid B, stir at a speed of 1000 rpm, mechanically stir for 60 minutes, and prepare 50kg of active rep...

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PUM

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Abstract

The invention relates to a catalyst regeneration method, and especially relates to an SCR flue gas denitration catalyst regeneration method. The method concretely comprises the following steps: purging a catalyst to be regenerated; putting the catalyst into a cleaning pool, cleaning with a cleaning solution, and drying; dipping the cleaned catalyst into an activity supplement solution to carry out activity supplement, and drying; and roasting and cooling the dried catalyst to obtain a generated denitration catalyst. The method of the invention has the following beneficial effects: catalyst carriers are not destroyed during cleaning; the catalyst can be cleaned, active substances can be supplemented, and active components of the regenerated catalyst are environmentally-friendly, so the regenerated catalyst does not generate pollution in the use process; and the denitration activity of the regenerated catalyst reaches above 90%. The method is very important for regeneration and reuse of dead toxic vanadium-titanium catalysts, and use promotion of self-developed novel environmentally-friendly and cheap titanium-based denitration catalysts.

Description

technical field [0001] The invention relates to a catalyst regeneration method, in particular to a catalyst regeneration method for SCR flue gas denitrification. Background technique [0002] Denitrification refers to the removal of nitrogen oxides (NOx). my country's NOx emissions in 2010 were as high as 22.73 million tons, making it the world's largest emitter. NOx is the main cause of acid rain, and the loss caused by acid rain pollution in my country exceeds 300 billion yuan every year. Among many denitrification methods, selective catalytic reduction (SCR) has a high denitrification rate (>90%), mature technology, and no harmful products. It has become the main method of NOx treatment at home and abroad (accounting for 96%). In the SCR system, the catalyst is the core, usually accounting for 30%-50% of the initial investment. Since the flue gas contains K, Na, As and other oxides and fly ash, it is easy to poison and block the catalyst, which will cause the cata...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J38/68B01J38/60B01J38/62B01D53/90B01D53/56
Inventor 祝社民杨波沈树宝
Owner NANJING UNIV OF TECH
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