Radio-attenuating metallic material

A bismuth-tin alloy addresses the drawbacks of traditional radiation shielding materials by offering lightweight, cost-effective, and easily moldable radiation protection.

FR3161912B3Active Publication Date: 2026-04-10LEMER PAX
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Patent Information

Authority / Receiving Office
FR · FR
Patent Type
Utility models
Current Assignee / Owner
Filing Date
2024-05-06
Publication Date
2026-04-10

AI Technical Summary

Technical Problem

Existing radiation protection materials like lead and tungsten face issues such as toxicity, high cost, environmental concerns, and difficulty in shaping, necessitating complex handling and maintenance.

Method used

A bismuth-tin alloy with a minimum 50% bismuth content, optionally with antimony, copper, and silver, providing excellent radio attenuation and moldability, replacing traditional materials.

Benefits of technology

The bismuth-tin alloy offers effective radiation shielding with reduced weight and cost, simpler handling, and improved manufacturability compared to lead and tungsten.

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Abstract

The present invention relates to a radio-attenuating metallic material for the production of a protective screen or shield against ionizing radiation such as X-rays, gamma rays, or beta rays. This radio-attenuating material is characterized in that it consists of an alloy of at least bismuth and tin, with bismuth present in a proportion of at least 50% by weight in the final metallic material. Preferably, the radio-attenuating material comprises: - between 52 and 70% by weight of bismuth in the final material, and - between 30 and 48% by weight of tin in the final material.
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Description

Title of the invention: Radio-attenuating metallic material Technical field of the invention

[0001] The present invention relates to the general field of protection against ionizing radiation.

[0002] It relates more particularly to a new radio-attenuating metallic material, for the production of protective screens, or protective shells, against ionizing radiation such as X-rays, gamma rays or beta rays. State of the art

[0003] The metallic materials generally used in the field of radiation protection are lead and tungsten.

[0004] Lead is widely used, in particular because of its low cost, its ease of implementation by molding, and its good radio-attenuation qualities.

[0005] But its use is increasingly regulated, due to its toxicity and the environmental or ecological problems it poses.

[0006] The handling of this metal presents health risks, and it is very often necessary to associate it with a coating such as paint or a plastic shell, which significantly complicates the manufacture and also the maintenance of the armor.

[0007] Tungsten is used in a limited way, as a replacement for lead.

[0008] However, it is an expensive, heavy material and its shaping must be done by machining because it cannot be easily molded.

[0009] The aim of the present invention is to propose a new radio-attenuating material that overcomes the aforementioned drawbacks of structures known to date. Presentation of the invention

[0010] For this purpose, the present invention proposes a radio-attenuating metallic material, for the production of a protective screen, or a protective shell, against ionizing radiation such as X-rays, gamma rays or beta rays, which material consists of an alloy of at least bismuth (Bi) and tin (Sn), the bismuth being present in a proportion of at least 50% by weight in the final metallic material.

[0011] Such a material ensures very good radio attenuation.

[0012] Its mechanical properties are advantageous; in particular, it is conformable by molding. Its production cost is low, and it is lighter than tungsten with equivalent protection.

[0013] Preferably, tin is present in a proportion of at least 30% (and even more preferably at least 40%) by weight in the final material.

[0014] The material according to the invention may include small proportions of other metals such as antimony and / or copper and / or silver, so as to adapt the mechanical properties of the final material, in particular according to the intended application.

[0015] The proportions of these other metals can be, for each one, on the order of a few percent maximum by weight in the final material.

[0016] For example, the proportion by weight in the final material of each other metal can be between 0.1 and 5%, preferably between 0.1 and 3%, and even more preferably between 0.1 and 2%.

[0017] Preferably, all of these other metals together constitute less than 5% by weight of the final metallic material.

[0018] The radio-attenuating material may comprise at least antimony and / or copper and / or gallium.

[0019] Antimony and / or copper and / or gallium together occupy less than 5% by weight of the final metallic material.

[0020] In an interesting embodiment, the radioprotective material according to the invention comprises:

[0021] - between 52 and 70% by weight of bismuth in the final material, and

[0022] - between 30 and 48% by weight of tin in the final material.

[0023] In a preferred embodiment, the material comprises:

[0024] - between 55 and 60% by weight of bismuth in the final material, and

[0025] - between 40 and 45% by weight of tin in the final material.

[0026] In general, this material is particularly suitable for use as a radio-attenuating material in the fields of imaging and therapy in nuclear medicine, and also in the field of radiology.

[0027] Such a material can for example be used for the production of a container for receiving a radioactive product or a container for receiving a container of radioactive product (for example to produce a syringe protector intended to contain a radioisotope, or to produce an armored transport case).

[0028] Such a container adapted for receiving a radioactive product or a container of radioactive product, is then at least partially made of radioprotective material according to the invention.

[0029] It can also be used for the production of screens adapted to form a barrier against ionizing radiation and in particular X-rays, gamma or beta rays.

[0030] Such a screen adapted to form a barrier against ionizing radiation and in particular X-rays, is then at least partially made of radioprotective material according to the invention.

[0031] Applications can also be envisaged in the field of shielding X-ray tubes, or gamma camera collimators. Example

[0032] The radio-attenuating metallic material may comprise: 58% by weight of bismuth, and 42% by weight of tin.

[0033] The Bi-Sn alloy is produced by heating a mixture of bismuth and tin beyond their melting point.

[0034] The molten and homogenized liquid alloy is poured into a mold, for example a steel mold, to obtain the molded material in the desired shape.

[0035] The desired product can be obtained by direct casting into the mold (for example a mold in the shape of a syringe protector).

[0036] A rough casting can also be made with a view to finishing by machining, cutting and / or stamping.

[0037] Where appropriate, extrusion techniques may also be used to shape the finished product.

[0038] The density of the material obtained is approximately 8.58. (compared to that of tungsten, which is 17.56) Results

[0039] A syringe protector made of the radio-attenuating material described above (58% bismuth and 42% tin) provides a radio-attenuation similar / comparable to that of a syringe protector made of tungsten, having the same structure and the same wall thickness, while being twice as light.

Claims

Demands

1. Radio-attenuating metallic material, for the production of a protective screen, or a protective shell, against ionizing radiation such as X-rays, gamma rays or beta rays, characterized in that it consists of an alloy of at least bismuth and tin, the bismuth being present in a proportion of at least 50% by weight in the final metallic material.

2. Radio-attenuating material according to claim 1, characterized in that it comprises tin in a proportion of at least 30% by weight in the final material.

3. Radio-attenuating material according to claim 2, characterized in that it comprises tin in a proportion of at least 40% by weight in the final material.

4. Radio-attenuating material according to any one of claims 1 to 3, characterized in that it comprises at least antimony and / or copper and / or gallium.

5. Radio-attenuating material according to claim 4, characterized in that antimony and / or copper and / or gallium together occupy less than 5% by weight of the final metallic material.

6. Radio-attenuating material according to any one of claims 1 to 5, characterized in that it comprises: - between 52 and 70% by weight of bismuth in the final material, and - between 30 and 48% by weight of tin in the final material.

7. Radio-attenuating material according to claim 6, characterized in that it comprises: - between 55 and 60% by weight of bismuth in the final material, and - between 40 and 45% by weight of tin in the final material.

8. A container made of radio-attenuating material suitable for receiving a radioactive product or a container for a radioactive product, which container is at least partially made of radio-protective material according to any one of claims 1 to 7.

9. A screen made of radio-attenuating material adapted to form a barrier against ionizing radiation and in particular X-rays, which screen is at least partially made of radioprotective material according to any one of claims 1 to 7.