Agar-Xanthan Gel Composition for High Salt Stability

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Solution Overview

Problem

Existing gel compositions for savory food products face challenges such as instability at high salt concentrations, rapid gel formation during cooling, and difficulty in melting when reheated, which affects texture and usability in concentrated food products like sauces and soups.

Innovation Solution

A heat-reversible gel composition comprising 30-70% water, 10-25% salt, and 0.15-12% gelling agents, primarily agar and xanthan, with optional additional agents like starch or carrageenan, which forms an elastic gel that melts easily when reheated to temperatures above 90°C and dissolves quickly in boiling water, maintaining stability and preventing syneresis.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If combinations of xanthan and galactomannans are used as gelling agents, then gel strength is improved, but the gel loses strength as salt content is increased

Engineering Contradiction:
Improvegel strengthVSAvoidstability at high salt concentrations
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters by replacing galactomannans with agar, a hydrocolloid with different molecular structure and salt tolerance properties. Agar maintains stable gel strength across a wide range of salt concentrations (0-5% NaCl), resolving the contradiction between gel strength and salt stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite gelling system combining agar (0.1-2%) and xanthan gum (0.05-1%) that leverages the salt-stabilizing properties of agar with the thickening and texture-enhancing properties of xanthan, achieving both strong gel formation and stability at high salt concentrations

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If conventional gelling agents are used, then gel formation occurs during cooling, but this leads to undesired texture for consumption

Engineering Contradiction:
Improvegel formation during coolingVSAvoidtexture during consumption
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The patent utilizes the reversible thermal phase transition properties of agar, which remains in a liquid state above its melting point (85-95°C) and forms a gel below its gelling point (32-40°C). This allows the product to maintain a pourable liquid texture during consumption while forming a stable gel structure during storage at refrigeration temperatures

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent optimizes the gelling agent concentration parameters (agar 0.1-2%, xanthan 0.05-1%) to control the kinetics of gel formation, creating a system that gels slowly at refrigeration temperatures rather than rapidly during cooling, thereby maintaining desirable texture during consumption

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If gelatin and starch are used as gelling agents, then gel formation is achieved, but a very high dosage is needed and gelatin is not suitable for vegetarian diets

Engineering Contradiction:
Improvegel formation capabilityVSAvoiddosage of gelling agent
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent changes the chemical composition by replacing gelatin and starch with a vegetarian-compatible agar-xanthan system. Agar forms strong gels at very low concentrations (0.1-2%), significantly reducing the required dosage compared to gelatin-starch combinations while maintaining vegetarian suitability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite system of agar and xanthan where agar provides the primary gelling function at low doses and xanthan enhances the gel structure and stability, achieving effective gel formation with minimal total gelling agent dosage while meeting vegetarian dietary requirements

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The agar-xanthan gel composition provides a stable, elastic texture that withstands high salt levels, prevents rapid gel formation during consumption, and ensures easy melting and dissolving, enhancing processing and storage stability, while maintaining a smooth mouthfeel and preventing lingering coatings.

Implementation Method 1

Agar has specific physical characteristics. It will melt when heated to 85 °C and will form a gel structure below 40 °C

Methodology Applied
Scientific EffectGelation: Gel

Implementation Method 2

It will melt when heated to 85 °C and will form a gel structure below 40 °C

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 3

A heat-reversible gel composition comprising both agar and xanthan as gelling agents for preparing savoury gelled food products

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP2729021B1Gel composition
Publication Date: 2016.04.13 NESTEC SA

AI summary

A composition in the form of a gel for preparing a food product, the composition comprising water, flavourings, salt and gelling agents, where the gelling agents comprise at least agar and xanthan.