Aluminum-Copper Bonding via Controlled Si Phase

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Solution Overview

Problem

The formation of Kirkendall voids at the bonding interface between aluminum members with a high Si content and copper members during solid-phase diffusion bonding leads to increased heat resistance and deteriorated heat dissipation characteristics in power module substrates.

Innovation Solution

By controlling the Si concentration in the aluminum alloy between 1 mass% to 25 mass% and ensuring the Si phase at the bonding surface has an equivalent circle diameter of 1 µm to 8 µm, the method promotes fine Si phases, reducing Cu diffusion and suppressing Kirkendall void formation, while using electrical heating and pressure to facilitate solid-phase diffusion bonding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If solid-phase diffusion bonding is performed between aluminum member with high Si content and copper member, then bonding strength is improved, but Kirkendall voids form at bonding interface causing heat resistance increase

Engineering Contradiction:
Improvebonding strengthVSAvoidheat dissipation characteristics
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent changes the physical state parameters of Si phase from coarse to fine dispersion, and controls the size parameter (equivalent circle diameter) to 1-8 µm. This parameter change in Si phase morphology prevents excessive Cu diffusion while maintaining bonding strength, thereby resolving the contradiction between bonding strength and heat dissipation characteristics.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If Ni plating film is formed on surface of circuit layer and metal layer, then bonding reliability is improved, but manufacturing complexity and cost increase due to masking process

Engineering Contradiction:
Improvebonding reliabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts and removes the Ni plating step and masking process from the manufacturing sequence. Instead of forming Ni plating film, the invention directly bonds aluminum member to copper member through solid-phase diffusion bonding with controlled Si phase, thereby eliminating the complex masking process while maintaining bonding reliability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces fine Si phase (1-8 µm equivalent circle diameter) as an intermediary layer between aluminum member and copper member. This Si phase mediator prevents excessive Cu diffusion and Kirkendall void formation, replacing the need for Ni plating film while simplifying the manufacturing process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If Ag underlying layer is formed through plating to improve bondability, then bonding is improved, but manufacturing labor and cost increase

Engineering Contradiction:
ImprovebondabilityVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent removes the Ag underlying layer formation step from the manufacturing process. By directly using aluminum member with controlled fine Si phase (1-8 µm equivalent circle diameter) for solid-phase diffusion bonding, the invention eliminates the need for Ag plating, thereby improving manufacturing efficiency while maintaining bondability.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively suppresses Kirkendall voids, enhances bonding reliability, reduces heat resistance, and improves heat dissipation characteristics in power module substrates with complex structures, including those with flow passages.

Implementation Method 1

the aluminum member and the copper member are heated and pressurized to facilitate solid-phase diffusion bonding

Methodology Applied
Scientific EffectSolid-phase diffusion bonding: Diffusion Welding

Implementation Method 2

electrical heating and pressure to facilitate solid-phase diffusion bonding

Methodology Applied
Scientific EffectElectrical heating: Joule Heating

Data Source

PatentEP3269491B1Manufacturing method for junction, manufacturing method for substrate for power module with heat sink, and manufacturing method for heat sink
Publication Date: 2019.11.27 MITSUBISHI MATERIALS CORP
  • EP3269491B1 patent drawingFigure 1
  • EP3269491B1 patent drawingFigure 2
  • EP3269491B1 patent drawingFigure 3

AI summary

A method of manufacturing a bonded body is provided in which a copper member (13B) formed from copper or a copper alloy, and an aluminum member (31) formed from an aluminum alloy in which a Si concentration is set in a range of 1 mass% to 25 mass% are bonded to each other. In the aluminum member before the bonding, D90 of an equivalent circle diameter of a Si phase at a bonding surface with the copper member is set in a range of 1 µm to 8 µm, and the aluminum member and the copper member are subjected to solid-phase diffusion bonding.