Al-Mn-Sc Alloy Composition for Crack-Resistant AM Strength

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Solution Overview

Problem

Current high-performance aluminium alloys for additive manufacturing (AM) and rapid solidification processes lack sufficient strength and thermal stability, with existing alloys exhibiting low tensile and yield strengths, and requiring costly solution treatments, while being susceptible to solidification cracks and corrosion.

Innovation Solution

Development of an Al-Mn-Sc based alloy with 2.01-15.0 wt% manganese and 0.3-2.0 wt% scandium, which can be directly age hardened to achieve superior mechanical properties and thermal stability without the need for solution treatment, utilizing high cooling rates to form thermally stable nano-sized precipitates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If near-eutectic Al-Si based alloys are used for additive manufacturing, then good castability and weldability are achieved, but tensile strength and yield strength remain below 400 MPa and 300 MPa respectively

Engineering Contradiction:
Improvecastability and weldabilityVSAvoidtensile strength and yield strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The invention changes the compositional parameters by replacing Si-based alloying with Mn and Sc additions, specifically using 2.01-15.0 wt% Mn and 0.3-2.0 wt% Sc to achieve both manufacturability and high strength through a different chemical system

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite alloy system combining Al-Mn-Sc with specific compositional ranges that integrate the beneficial properties of Mn (strength) and Sc (thermal stability and precipitation hardening) to achieve superior mechanical properties while maintaining ease of manufacture

Inventive Principle:
Principle #40Composite materials

2Strength

If high strength aluminium alloys are used for additive manufacturing, then tensile strength above 400 MPa and yield strength above 300 MPa are achieved, but solidification crack susceptibility increases

Engineering Contradiction:
Improvetensile strength and yield strengthVSAvoidsolidification crack susceptibility
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The invention changes the compositional parameters by limiting Cu, Mg, and Zn content while optimizing Mn and Sc ratios, thereby reducing solidification range and hot tearing susceptibility while maintaining high strength through alternative strengthening mechanisms

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the potential harm of high strength alloying into benefit by using Sc to control solidification behavior and reduce crack susceptibility, while Mn provides strength through a different mechanism that does not expand the solidification range

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Device complexity

If conventional aluminium alloys are used for additive manufacturing, then manufacturing process is simple, but components require solution treatment after fabrication to achieve required properties

Engineering Contradiction:
Improvemanufacturing process complexityVSAvoidlead time for solution treatment
Core Design Contradiction:
Device complexityVSLoss of time

Solution Approach 1:

The invention performs preliminary action by incorporating Sc and Mn in specific ratios during alloy fabrication, which pre-configures the alloy to achieve required properties through direct age hardening without requiring subsequent solution treatment, thereby reducing lead time and process complexity

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention extracts the solution treatment step from the manufacturing process by designing an alloy composition that achieves required properties through direct age hardening alone, eliminating the need for the separate solution treatment operation

Inventive Principle:
Principle #2Taking out (Extraction)

4Adaptability or versatility

If aluminium alloys are used for elevated temperature applications, then potential to replace titanium alloys is achieved, but thermal stability and strength at temperatures above 150°C are insufficient

Engineering Contradiction:
Improveapplicability for elevated temperature applicationsVSAvoidstrength and thermal stability at elevated temperatures
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The invention changes the compositional parameters by adding Sc (0.3-2.0 wt%) which forms thermally stable precipitates, and optimizing Mn content (2.01-15.0 wt%) to provide solid solution strengthening that maintains strength at elevated temperatures above 150°C

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite alloy system combining Al-Mn-Sc with specific compositional ranges that integrate the beneficial properties of Mn (solid solution strengthening) and Sc (thermal stable precipitates) to achieve both adaptability for elevated temperature applications and sufficient strength

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Al-Mn-Sc alloy demonstrates high strength and thermal stability, comparable to 7xxx series alloys, with enhanced corrosion resistance and weldability, allowing for the production of structural components that maintain properties at elevated temperatures without the need for complex heat treatments.

Implementation Method 1

The AM processes use a laser beam, an electron beam or an electric arc as the energy source, with the source precisely controlled by either a CNC driven system or galvanometer based mirror scanning system. Through melting and solidifying of materials, successive layers can be built up in turn

Methodology Applied
Scientific EffectRapid solidification: Freezing

Implementation Method 2

utilizing high cooling rates to form thermally stable nano-sized precipitates

Methodology Applied
Scientific EffectPrecipitation hardening: Precipitation

Data Source

PatentUS11976343B2High strength aluminium alloy for rapid solidification manufacturing processes
Publication Date: 2024.05.07 MONASH UNIV
  • US11976343B2 patent drawing
  • US11976343B2 patent drawing
  • US11976343B2 patent drawing

AI summary

An aluminium based alloy, and a method for production of components by additive manufacturing (AM) or other rapid solidification process with the alloy, is based on the alloy having a composition with from 2.01 wt % to 15.0 wt % manganese, from 0.3 wt % to 2.0 wt % scandium, with a balance apart from minor alloy elements and incidental impurities of aluminium.