Atomic Layer Deposition for High-k Dielectric Density

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Solution Overview

Problem

Current methods for forming dielectric layers in semiconductor manufacturing, particularly at the 40 nm and 28 nm process nodes, are insufficient to meet performance and manufacturing specifications due to challenges in achieving the required density and reducing leakage.

Innovation Solution

The use of atomic layer deposition (ALD) to form high-k dielectric layers, such as zirconium oxide and hafnium oxide, with specific precursor materials and process conditions to create a composite dielectric layer that enhances density and reduces leakage, involving a first deposition process with self-limiting reactions and a second process with faster cycle times to improve efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If current methods are used to form dielectric layers at 40 nm and 28 nm process nodes, then manufacturing simplicity is maintained, but density and leakage performance specifications cannot be met

Engineering Contradiction:
Improvedielectric layer densityVSAvoiddeposition process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The dielectric layer formation is divided into multiple sequential deposition cycles, each depositing a thin monolayer through self-limiting surface reactions. This segmentation allows precise control over the final dielectric layer density and composition, meeting the stringent requirements for 40 nm and 28 nm process nodes while managing complexity through systematic process design

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The deposition process utilizes controlled changes in precursor materials, reaction conditions, and cycle parameters to optimize dielectric layer properties. By adjusting parameters such as precursor flow rates, reaction temperatures, and purge times, the method achieves high-density dielectric layers with reduced leakage while maintaining manufacturability

Inventive Principle:
Principle #35Parameter changes

2Productivity

If faster deposition cycle times are used, then manufacturing productivity increases, but dielectric layer density and quality may deteriorate

Engineering Contradiction:
Improvedeposition cycle timeVSAvoiddielectric layer quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The deposition process employs periodic cycles of precursor introduction, reaction, and purge steps. Each cycle is optimized to complete within a specific time window, allowing faster overall deposition while maintaining dielectric layer quality through the self-limiting nature of the surface reactions that ensure complete monolayer formation before the next cycle begins

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The self-limiting surface reactions automatically regulate the deposition rate and monolayer completion without requiring complex real-time monitoring or adjustment. This self-regulating mechanism enables faster cycle times while ensuring consistent dielectric layer quality, as the reaction naturally stops when the surface is saturated, preventing over-deposition

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in improved density, reduced leakage, and increased data retention, enabling better performance and manufacturing efficiency for semiconductor devices, particularly in capacitors and transistors.

Implementation Method 1

introducing a first precursor to a deposition chamber for a first time and introducing a first purge gas to the deposition chamber for a second time after the introducing the first precursor

Methodology Applied
Scientific EffectSelf-limiting surface reaction: Adsorption

Implementation Method 2

The use of atomic layer deposition (ALD) to form high-k dielectric layers, such as zirconium oxide and hafnium oxide, with specific precursor materials and process conditions

Methodology Applied
Scientific EffectAtomic layer deposition: Chemical Vapour Deposition

Data Source

PatentUS9818885B2Deposited material and method of formation
Publication Date: 2017.11.14 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US9818885B2 patent drawing
  • US9818885B2 patent drawing
  • US9818885B2 patent drawing

AI summary

A system and method for manufacturing a semiconductor device is provided. An embodiment comprises forming a deposited layer using an atomic layer deposition (ALD) process. The ALD process may utilize a first precursor for a first time period, a first purge for a second time period longer than the first time period, a second precursor for a third time period longer than the first time period, and a second purge for a fourth time period longer than the third time period.